Relating the reproductive toxicity of five ingested metals in calanoid copepods with sulfur affinity   总被引：6，自引：0，他引：6  

Hook SE  Fisher NS 《Marine environmental research》2002,53(2):161-174

The sublethal toxicity of dietary Ag, Cd, Hg, Mn, and Zn to marine copepods, measured as depressed egg production, was evaluated as a function of ambient metal concentrations and metal concentrations in copepod tissues. All metals were toxic following 4-h feedings on metal-contaminated phytoplankton food, but there was a four order of magnitude difference between the inhibitory concentration in copepod tissues of the most toxic (2.4 nmol g(-1) dry wt. for Hg) and least toxic (13.4 micromol g(-1) dry wt. for Mn) metals. Metal concentrations in copepods that elicited a toxic response were about 3 times higher than background concentrations for Ag and 9 times higher for Hg, about 2 times higher for Cd, two orders of magnitude higher for Mn, and only 5% higher for Zn. Copepods exposed to lower concentrations of Zn for longer periods (1 week), resulting in tissue Zn concentrations similar to those in the short-term exposures, were not affected, suggesting that copepods were capable of adjusting to slowly increasing Zn by sequestration of this metal. Toxic metal concentrations in copepod tissues were directly proportional (r2 = 0.85) to the affinity of the metals for sulfur, as indicated by the solubility products of the metal sulfides. This relationship, together with protein analysis of eggs, published recently, suggests that metals affect egg production by binding to enzymes involved with vitellogenesis.  相似文献   

Multispecies analysis in Balsfjord, northern Norway: solution and sensitivity analysis of a simple ecosystem model     

Bax  Nicholas; Eliassen  Jens-Eric 《ICES Journal of Marine Science》1990,47(2):175-204

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Comparison of atmospheric forcing in four sub-arctic seas     

Muyin Wang  Nicholas A. Bond  James E. Overland 《Deep Sea Research Part II: Topical Studies in Oceanography》2007,54(23-26):2543

A comparative analysis was conducted on climate variability in four sub-arctic seas: the Sea of Okhotsk, the Bering Sea shelf, the Labrador Sea, and the Barents Sea. Based on data from the NCEP/NCAR reanalysis, the focus was on air–sea interactions, which influence ice cover, ocean currents, mixing, and stratification on sub-seasonal to decadal time scales. The seasonal cycles of the area-weighted averages of sea-level pressure (SLP), surface air temperature (SAT) and heat fluxes show remarkable similarity among the four sub-arctic seas. With respect to variation in climate, all four seas experience changes of comparable magnitude on interannual to interdecadal time scales, but with different timing. Since 2000 warm SAT anomalies were found during most of the year in three of the four sub-arctic seas, with the exception of the Sea of Okhotsk. A seesaw (out of phase) pattern in winter SAT anomalies between the Labrador and the Barents Sea in the Atlantic sector is observed during the past 50 years before 2000; a similar type of co-variability between the Sea of Okhotsk and the Bering Sea shelf in the Pacific is only evident since 1970s. Recent positive anomalies of net heat flux are more prominent in winter and spring in the Pacific sectors, and in summer in the Atlantic sectors. There is a reduced magnitude in wind mixing in the Sea of Okhotsk since 1980, in the Barents Sea since 2000, and in early spring/late winter in the Bering Sea shelf since 1995. Reduced sea-ice areas are seen over three out of four (except the Sea of Okhotsk) sub-arctic seas in recent decades, particularly after 2000 based on combined in situ and satellite observations (HadISST). This analysis provides context for the pan-regional synthesis of the linkages between climate and marine ecosystems.  相似文献   

Photochemical modeling of Titan's atmosphere     

Toublanc D  Parisot JP  Brillet J  Gautier D  Raulin F  McKay CP 《Icarus》1995,113(1):2-26

We have developed a new photochemical model of Titan's atmosphere which includes all the important compounds and reactions in spherical geometry from the surface to 1240 km. Compared to the previous model of Yung et al. (1984, Astrophys. J. Suppl. 55, 465-506), the most significant recent change in the reactions used is the updated methane photodissociation scheme (Mordaunt et al. 1993, J. Chem. Phys. 98(3), 2054-2065). Moreover, the transfer of the solar radiation in the atmosphere and the photolysis rates have been calculated by using a Monte Carlo code. Finally, the eddy diffusion coefficient profile is adjusted in order to fit the mean vertical distribution of HCN retrieved from millimeter groundbased observations of Tanguy et al. (1990, Icarus, 85, 43-57) using new values for the boundary flux of atomic nitrogen (Strobel et al. 1992, Icarus 100, 512-526). We have run the model in both steady-state and diurnal modes, with 62 speices involved in 249 reactions. There is little difference between diurnal and steady-state results. Overall our results are in a closer agreement with the abundances inferred from the Voyager infrared measurements at the equator than the Yung et al. results. We find that the catalytic scheme for H recombination invoked by Yung et al. only slightly improves the model results and we conclude that this scheme is not essential to fit observations.  相似文献   

Episodic ocean-induced CO2 greenhouse on Mars: implications for fluvial valley formation     

Gulick VC  Tyler D  McKay CP  Haberle RM 《Icarus》1997,130(1):68-86

Pulses of CO2 injected into the martian atmosphere more recently than 4 Ga can place the atmosphere into a stable, higher pressure, warmer greenhouse state. One to two bar pulses of CO2 added to the atmosphere during the past several billion years are sufficient to raise global mean temperatures above 240 or 250 K for tens to hundreds of millions of years, even when accounting for CO2 condensation. Over time, the added CO2 is lost to carbonates, the atmosphere collapses and returns to its buffered state. A substantial amount of water could be transported during the greenhouse periods from the surface of a frozen body of water created by outflow channel discharges to higher elevations, despite global temperatures well below freezing. This water, precipitated as snow, could ultimately form fluvial valleys if deposition sites are associated with localized heat sources, such as magmatic intrusions or volcanoes. Thus, if outflow channel discharges were accompanied by the release of sufficient quantities of CO2, a limited hydrological cycle could have resulted that would have been capable of producing geomorphic change sufficient for fluvial erosion and valley formation. Glacial or periglacial landforms would also be a consequence of such a mechanism.  相似文献   

Formation and occurrence of organic hydroperoxides in the troposphere: Laboratory and field observations     

C. Nicholas Hewitt  Gregory L. Kok 《Journal of Atmospheric Chemistry》1991,12(2):181-194

The formation and occurrence of hydroperoxides in the troposphere have been studied by laboratory experiments and by preliminary field measurements. Nine alkenes were reacted individually with ozone in a reaction chamber in the presence of excess water, and the amounts of hydrogen peroxide and of nine organic hydroperoxides produced in the gas and aerosol phases and deposited on the chamber walls determined by HPLC. The reactions of ethene, propene, 1-butene and isoprene gave hydroxymethyl hydroperoxide as the major product with no hydrogen peroxide observed. In the case of - and -pinene, 2-carene and limonene the major product was hydrogen peroxide. Cis-2-butene produced hydrogen peroxide and methyl hydroperoxide. Preliminary measurements of hydrogen peroxide and five organic hydroperoxides in ambient air were made at Niwot Ridge, Colorado from 24 July–4 August 1989. The gas-phase species were preconcentrated by cryotrapping with subsequent HPLC separation. The gas-phase concentrations of H₂O₂ ranged from 0.5–2 ppbv with the lowest concentrations being measured at night and the highest under conditions of strong photochemical activity. The maximum concentrations of hydroxymethyl hydroperoxide approximated those of H₂O₂. Methyl hydroperoxide concentrations ranged from <50 to 800 pptv and three other organic hydroperoxides were detected at concentrations below 200 pptv. High volume aerosol samples yielded H₂O₂ and methyl hydroperoxide concentrations <10 ng m^-3 while H₂O₂ and six organic species were detected in rainwater at concentrations in the range <0.01–50 M.  相似文献   

Corrigendum to “Sedimentology, stratigraphy, and glacier dynamics, western Scottish Highlands” [Quaternary Research 68 (2007) 79–95]     

Nicholas R. Golledge   《Quaternary Research》2007,68(3):456-457

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Constrained Smoothing of Noisy Data Using Splines in?Tension     

Nicholas A. Teanby 《Mathematical Geology》2007,39(4):419-434

A method of fitting a smooth cubic spline curve through noisy data points is presented. Overshoots of the spline curve between data points were prevented by applying tension to the fit using a quadratic spring approximation, which allowed a linear inverse theory approach to be adopted. Error-bars in the measured data were mapped through the inversion process to give the covariance of the fitted curve. This is an improvement over previous methods, which largely neglect the effect of data errors on the fit. Another improvement is to impose fixed constraints on the fit by simultaneously applying the method of Lagrange multipliers. The effect of these constraints on the covariance of the fitted curve is quantified using results from linear algebra. Example applications to synthetic data and a record of magnetic inclination from Hawaii are given.  相似文献   

Sedimentology, stratigraphy, and glacier dynamics, western Scottish Highlands     

Nicholas R. Golledge 《Quaternary Research》2007,68(1):79-95

Glacial sediments of the western Scottish Highlands are comprehensively described and characterized here for the first time, enabling the first glacial stratigraphy for the area to be proposed. This classification is based on the results of extensive geological mapping and field investigation of sedimentary sequences and their structures, X-ray diffraction and particle size distribution analyses, and comparison with deposits formed in contemporary glaciated environments. These new data are subsequently appraised in terms of their implications for late Pleistocene glacier evolution and dynamics. Together, the data suggest that much of the landscape is palimpsest, and can be attributed to the Weichselian (Late Devensian) glaciation. Subsequent glacier advance during the Younger Dryas did little to modify the area, suggesting that ice flow was dominated by sliding on a meltwater-lubricated rigid bed, with deformation of basal sediments playing a more limited role. Final deglaciation was marked by a significant increase in basal meltwater flux, reflecting the warming climate and increasing precipitation. These new palaeoglaciological and palaeoenvironmental insights advance our understanding of former glacier dynamics in the western Scottish Highlands, improve our knowledge of Pleistocene landscape evolution of this area, and enable comparisons to be made with sedimentary sequences elsewhere.  相似文献   

Catchment-scale (dis)connectivity in sediment flux in the upper Hunter catchment, New South Wales, Australia   总被引：3，自引：1，他引：3  

Kirstie A. Fryirs  Gary J. Brierley  Nicholas J. Preston  John Spencer 《Geomorphology》2007,84(3-4):297

(Dis)connectivity within and between landscape compartments affects the extent and rate of transfer of energy and matter through catchments. Various landforms may impede sediment conveyance in a river system, whether laterally to the channel (termed buffers) or longitudinally along the channel itself (termed barriers). A generic approach to analysis of landscape (dis)connectivity using slope threshold analysis in GIS, tied to air photograph interpretation and field mapping of buffers and barriers, is tested in the upper Hunter catchment, Australia. Under simulated conditions, effective catchment area, which is a measure of the proportion of a catchment that has the potential to contribute sediment to the channel network, varies from 73% to just 3% of the total catchment area for differing subcatchments in the upper Hunter. This variability can be explained by the spatial distribution and assemblage of buffers and barriers in each subcatchment. Multiple forms of disconnectivity are evident in some subcatchments, such that when one buffer or barrier is breached, other features still impede sediment transfer within the system. The importance of the position of buffers and barriers within any given subcatchment is emphasised. Spatial variability in valley width exerts a critical control on catchment connectivity, with more efficient sediment conveyance in narrow valleys relative to wider valleys characterised by piedmonts, terraces, fans and extensive floodplains in which conveyance is impeded. This variability reflects the landscape history and geological setting of each subcatchment. The framework developed in this paper can be used to assess the impact of natural or human-induced buffers and barriers on catchment-scale sediment flux in any landscape setting, providing a physical template atop which other biogeochemical fluxes could be examined.  相似文献