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131.
The Nantianwan mafic intrusion in the Panxi region, SW China, part of the ~260?Ma Emeishan large igneous province, consists of the olivine gabbro and gabbronorite units, separated by a transitional zone. Olivine gabbros contain olivine with Fo values ranging from 83 to 87, indicating crystallization from a moderately evolved magma. They have 0.2 to 0.9?wt?% sulfide with highly variable PGE (17?C151?ppb) and variable Cu/Pd ratios (1,500?C32,500). Modeling results indicate that they were derived from picritic magmas with high initial PGE concentrations. Olivine gabbros have negative ??Nd(t) values (?1.3 to ?0.1) and positive ??Os(t) values (5?C15), consistent with low degrees of crustal contamination. Gabbronorites include sulfide-bearing and sulfide-poor varieties, and both have olivine with Fo values ranging from 74 to 79, indicating crystallization from a more evolved magma than that for olivine gabbros. Sulfide-bearing gabbronorites contain 1.9?C4.1?wt?% sulfide and 37?C160?ppb PGE and high Cu/Pd ratios (54,000?C624,000). Sulfide-poor gabbronorites have 0.1?C0.6?wt?% sulfide and 0.2?C15?ppb PGE and very high Cu/Pd ratios (16,900?C2,370,000). Both sulfide-bearing and sulfide-poor gabbronorites have ??Nd(t) values (?0.9 to ?2.1) similar to those for olivine gabbros, but their ??Os(t) values (17?C262) are much higher and more variable than those of the olivine gabbros. Selective assimilation of crustal sulfides from the country rocks is thus considered to have resulted in more radiogenic 187Os of the gabbronorites. Processes such as magma differentiation, crustal contamination and sulfide saturation at different stages in magma chambers may have intervened during formation of the intrusion. Parental magmas were derived from picritic magmas that had fractionated olivine under S-undersaturated conditions before entering a deep-seated staging magma chamber, where the parental magmas crystallized olivine, assimilated minor crustal rocks and reached sulfide saturation, forming an olivine- and sulfide-laden crystal mush in the lower part and evolved magmas in the upper part of the chamber. The evolved magmas were forced out of the staging chamber and became S-undersaturated due to a pressure drop during ascent to a shallow magma chamber. The magmas re-attained sulfide saturation by assimilating external S from S-rich country rocks. They may have entered the shallow magma chamber as several pulses so that several gabbronorite layers each with sulfide segregated to the base and a sulfide-poor upper part. The olivine gabbro unit formed from a new and more primitive magma that entrained olivine crystals and sulfide droplets from the lower part of the staging chamber. A transitional zone formed along the boundary with the gabbronorite unit due to chemical interaction between the two rock units.  相似文献   
132.
133.
On December 4th 2007, a 3-Mm3 landslide occurred along the northwestern shore of Chehalis Lake. The initiation zone is located at the intersection of the main valley slope and the northern sidewall of a prominent gully. The slope failure caused a displacement wave that ran up to 38 m on the opposite shore of the lake. The landslide is temporally associated with a rain-on-snow meteorological event which is thought to have triggered it. This paper describes the Chehalis Lake landslide and presents a comparison of discontinuity orientation datasets obtained using three techniques: field measurements, terrestrial photogrammetric 3D models and an airborne LiDAR digital elevation model to describe the orientation and characteristics of the five discontinuity sets present. The discontinuity orientation data are used to perform kinematic, surface wedge limit equilibrium and three-dimensional distinct element analyses. The kinematic and surface wedge analyses suggest that the location of the slope failure (intersection of the valley slope and a gully wall) has facilitated the development of the unstable rock mass which initiated as a planar sliding failure. Results from the three-dimensional distinct element analyses suggest that the presence, orientation and high persistence of a discontinuity set dipping obliquely to the slope were critical to the development of the landslide and led to a failure mechanism dominated by planar sliding. The three-dimensional distinct element modelling also suggests that the presence of a steeply dipping discontinuity set striking perpendicular to the slope and associated with a fault exerted a significant control on the volume and extent of the failed rock mass but not on the overall stability of the slope.  相似文献   
134.
This application-oriented paper presents comparison of various broadband frequency based structural damage localization indices using experimental data from a full-scale structure known as the I-40 Bridge. First, three ‘damage-sensitive’ response parameters determined in the time and/or spectral domain, modal domain and wavelet domain are presented for damage localization in the context of a ‘non-model-based’ damage identification approach. Secondly, experimental modal data (namely natural frequencies, mode shapes and modal damping) obtained from this full-scale bridge subjected to various damage conditions is employed for assessment of the robustness of these methods on ‘real-world’ applications. Consequently, the results obtained are compared with those obtained from existing resonance frequency based damage identification methods. The results obtained demonstrate the improved capability of the broadband methods to localize damage in a full-scale structure despite sparse modal information and limited measurement grid points.  相似文献   
135.
The study of climate impacts on Living Marine Resources (LMRs) has increased rapidly in recent years with the availability of climate model simulations contributed to the assessment reports of the Intergovernmental Panel on Climate Change (IPCC). Collaboration between climate and LMR scientists and shared understanding of critical challenges for such applications are essential for developing robust projections of climate impacts on LMRs. This paper assesses present approaches for generating projections of climate impacts on LMRs using IPCC-class climate models, recommends practices that should be followed for these applications, and identifies priority developments that could improve current projections. Understanding of the climate system and its representation within climate models has progressed to a point where many climate model outputs can now be used effectively to make LMR projections. However, uncertainty in climate model projections (particularly biases and inter-model spread at regional to local scales), coarse climate model resolution, and the uncertainty and potential complexity of the mechanisms underlying the response of LMRs to climate limit the robustness and precision of LMR projections. A variety of techniques including the analysis of multi-model ensembles, bias corrections, and statistical and dynamical downscaling can ameliorate some limitations, though the assumptions underlying these approaches and the sensitivity of results to their application must be assessed for each application. Developments in LMR science that could improve current projections of climate impacts on LMRs include improved understanding of the multi-scale mechanisms that link climate and LMRs and better representations of these mechanisms within more holistic LMR models. These developments require a strong baseline of field and laboratory observations including long time series and measurements over the broad range of spatial and temporal scales over which LMRs and climate interact. Priority developments for IPCC-class climate models include improved model accuracy (particularly at regional and local scales), inter-annual to decadal-scale predictions, and the continued development of earth system models capable of simulating the evolution of both the physical climate system and biosphere. Efforts to address these issues should occur in parallel and be informed by the continued application of existing climate and LMR models.  相似文献   
136.
Mangrove ecosystems play an important, but understudied, role in the cycling of carbon in tropical and subtropical coastal ocean environments. In the present study, we examined the diel dynamics of seawater carbon dioxide (CO2) and dissolved oxygen (DO) for a mangrove-dominated marine ecosystem (Mangrove Bay) and an adjacent intracoastal waterway (Ferry Reach) on the island of Bermuda. Spatial and temporal trends in seawater carbonate chemistry and associated variables were assessed from direct measurements of dissolved inorganic carbon, total alkalinity, dissolved oxygen (DO), temperature, and salinity. Diel pCO2 variability was interpolated across hourly wind speed measurements to determine variability in daily CO2 fluxes for the month of October 2007 in Bermuda. From these observations, we estimated rates of net sea to air CO2 exchange for these two coastal ecosystems at 59.8 ± 17.3 in Mangrove Bay and 5.5 ± 1.3 mmol m−2 d−1 in Ferry Reach. These results highlight the potential for large differences in carbonate system functioning and sea-air CO2 flux in adjacent coastal environments. In addition, observation of large diel variability in CO2 system parameters (e.g., mean pCO2: 390–2,841 μatm; mean pHT: 8.05–7.34) underscores the need for careful consideration of diel cycles in long-term sampling regimes and flux estimates.  相似文献   
137.
Quantification of landscape-based vegetation structural variation and pattern is a significant goal for a variety of ecological, monitoring and biodiversity studies. Vegetation structural metrics, derived from airborne laser scanning (ALS or aerial light detection and ranging—LiDAR) and QuickBird satellite imagery, were used to establish the degree of plot-based vegetation variation at a hillslope scale. Topographic position is an indicator of energy and water availability, and was quantified using DEM-based insolation and topographic wetness, respectively, stratifying areas into hot-warm-cold and wet-moist-dry topographic classes. A range of vegetation metrics—maximum and modal canopy height, crown cover, foliage cover, NDVI and semivariance—were compared among randomly selected plots from each topographic class. NDVI increases with increasing landscape wetness, whereas ALS-derived foliage cover decreases with increasing insolation. Foliage cover is well correlated with crown cover (R 2 =0.65), and since foliage cover is readily calculable for whole-of-landscape application, it will provide valuable and complementary information to NDVI. Between-plot heterogeneity increases with increasing wetness and decreasing insolation, indicating that more sampling is required in these locations to capture the full range of landscape-based variability. Pattern analysis in landscape ecology is one of the fundamental requirements of landscape ecology, and the methods described here offer statistically significant, quantifiable and repeatable means to realise that goal at a fine spatial grain.  相似文献   
138.
Carbonate reactions are common in mineral deposits due to CO2-rich mineralising fluids. This study presents the first in-depth, integrated analysis of microstructure and microchemistry of fluid-mediated carbonate reaction textures at hydrothermal conditions. In doing so, we describe the mechanisms by which carbonate phases replace one another, and the implications for the evolution of geochemistry, rock microstructures and porosity. The sample from the 1.95 Moz Junction gold deposit, Western Australia, contains calcite derived from carbonation of a metamorphic amphibole—plagioclase assemblage that has further altered to siderite and dolomite. The calcite is porous and contains iron-rich calcite blebs interpreted to have resulted from fluid-mediated replacement of compositionally heterogeneous amphiboles. The siderite is polycrystalline but nucleates topotactically on the calcite. As a result, the boundaries between adjacent grains are low-angle boundaries (<10°), which are geometrically similar to those formed by crystal–plastic deformation and recovery. Growth zoning within individual siderite grains shows that the low-angle boundaries are growth features and not due to deformation. Low-angle boundaries develop due to the propagation of defects at grain faces and zone boundaries and by impingement of grains that nucleated with small misorientations relative to each other during grain growth. The cores of siderite grains are aligned with the twin planes in the parent calcite crystal showing that the reactant Fe entered the crystal along the twin boundaries. Dolomite grains, many of which appear to in-fill space generated by the siderite replacement, also show alignment of cores along the calcite twin planes, suggesting that they did not grow into space but replaced the calcite. Where dolomite is seen directly replacing calcite, it nucleates on the Fe-rich calcite due to the increased compatibility of the Fe-bearing calcite lattice relative to the pure calcite. Both reactions are interpreted as fluid-mediated replacement reactions which use the crystallography and elemental chemistry of the calcite. Experiments of fluid-mediated replacement reactions show that they proceed much faster than diffusion-based reactions. This is important when considering the rates of reactions relative to fluid flow in mineralising systems.  相似文献   
139.
This study presents new ages for the northwest section of the Laurentide Ice Sheet (LIS) glacial chronology from material recovered from two retrogressive thaw slumps exposed in the Richardson Mountains, Northwest Territories, Canada. One study site, located at the maximum glacial limit of the LIS in the Richardson Mountains, had calcite concretions recovered from aufeis buried by glacial till that were dated by U/Th disequilibrium to 18,500 cal yr BP. The second site, located on the Peel Plateau to the east yielded a fossil horse (Equus) mandible that was radiocarbon dated to ca. 19,700 cal yr BP. These ages indicate that the Peel Plateau on the eastern flanks of the Richardson Mountains was glaciated only after 18,500 cal yr BP, which is later than previous models for the global last glacial maximum (LGM). As the LIS retreated the Peel Plateau around 15,000 cal yr BP, following the age of the Tutsieta phase, we conclude that the presence of the northwestern margin of the LIS at its maximum limit was a very short event in the western Canadian Arctic.  相似文献   
140.
Acidification of surface seawater owing to anthropogenic activities has raised serious concerns on its consequences for marine calcifying organisms and ecosystems. To acquire knowledge concerning the future consequences of ocean acidification (OA), researchers have relied on incubation experiments with organisms exposed to future seawater conditions, numerical models, evidence from the geological record, and recently, observations from aquatic environments exposed to naturally high CO2 and low pH, e.g., owing to volcanic CO2 vents, upwelling, and groundwater input. In the present study, we briefly evaluate the distribution of dissolved CO2–carbonic acid parameters at (1) two locations in the Pacific and the Atlantic Ocean as a function of depth, (2) a mangrove environment in Bermuda, (3) a seasonally stratified body of water in a semi-enclosed sound in Bermuda, and (4) in temporarily isolated tide pools in Southern California. We demonstrate that current in situ conditions of seawater pCO2, pH, and CaCO3 saturation state (Ω) in these environments are similar or even exceed the anticipated changes to these parameters in the open ocean over the next century as a result of OA. The observed differences between the Pacific and Atlantic Oceans with respect to seawater CO2–carbonic acid chemistry, preservation of CaCO3 minerals, and the occurrence and distribution of deep-sea marine calcifiers, support the hypothesized negative effects of OA on the production and preservation of CaCO3 in surface seawater. Clues provided from shallow near-shore environments in Bermuda and Southern California support these predictions, but also highlight that many marine calcifiers already experience relatively high seawater pCO2 and low pH conditions.  相似文献   
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