δB, Sr, Mg and B in a modern Porites coral: the relationship between calcification site pH and skeletal chemistry     

Nicola Allison  Adrian A. Finch 《Geochimica et cosmochimica acta》2010,74(6):1790-6360

Sr/Ca, B/Ca, Mg/Ca and δ¹¹B were determined at high spatial resolution across ∼1 year of a modern Hawaiian Porites lobata coral by secondary ion mass spectrometry (SIMS). We observe significant variations in B/Ca, Mg/Ca, Sr/Ca and δ¹¹B over short skeletal distances (nominally equivalent to periods of <20 days). This heterogeneity probably reflects variations in the composition of the extracellular calcifying fluid (ECF) from which the skeleton precipitates. Calcification site pH (total scale) was estimated from skeletal δ¹¹B and ranged from 8.3 to 8.8 (± ∼0.1) with a mean of ∼8.6. Sr/Ca and B/Ca heterogeneity is not simply correlated with calcification site pH, as might be expected if Ca-ATPase activity increases the pH and decreases the Sr/Ca and B(OH)₄⁻/CO₃²⁻ ratios of the ECF. We produced a simple model of the ECF composition and the skeleton deposited from it, over a range of calcium transport and carbonate scenarios, which can account for these observed geochemical variations. The relationship between the pH and Sr/Ca of the ECF is dependent on the concentration of DIC at the calcification site. At higher DIC concentrations the ECF has a high capacity to buffer the [H⁺] changes induced by Ca-ATPase pumping. Conversely, at low DIC concentrations, this buffering capacity is reduced and ECF pH changes more rapidly in response to Ca-ATPase pumping. The absence of a simple correlation between ECF pH and skeletal Sr/Ca implies that calcification occurred under a range of DIC concentrations, reflecting variations in the respiration and photosynthesis of the coral and symbiotic zooxanthellate in the overlying coral tissues. Our observations have important implications for the use of coral skeletons as indicators of palaeo-ocean pH.  相似文献   

Alpine tectono‐metamorphic history of the continental units from Vardar zone: the Kopaonik Metamorphic Complex (Dinaric‐Hellenic belt,Serbia)     

Mario Zelic  Nicola Levi  Alessandro Malasoma  Michele Marroni  Luca Pandolfi  Branislav Trivic 《Geological Journal》2010,45(1):59-77

The easternmost zone of the Dinaric‐Hellenic belt is represented by the Vardar Zone, in which the Kopaonik Metamorphic Complex (KMC) is regarded as the lowermost unit. This complex is topped by the unmetamorphosed Brzece unit and is intruded by the Oligocene Kopaonik Intrusive complex. The KMC is characterized by a stratigraphy that includes metapelites and meta‐carbonates of Late Triassic age, associated with metabasites. It is characterized by a complex deformation history that comprises four phases: D1 to D4. The D1 phase structures occur only as relict structures, whereas the D2 phase structures are represented by isoclinal F2 folds, associated with a well‐developed S2 foliation. The estimated P‐T conditions for the D1 and D2 metamorphism are consistent with the upper greenschist facies. The D3 phase is characterized by west‐verging thrusts associated with upright folds. In contrast, the D4 phase is characterized by open folds (F4) associated with low‐angle normal faults. The D1 and D2 deformation phases developed during the shortening related to continental collision, whereas the subsequent D3 and D4 phases can be related to the progressive exhumation of the KMC. The D4 phase probably developed during extensional tectonics during and after emplacement of the Kopaonik Intrusive Complex. The data show that the continental units belonging to the Vardar zone had a long‐lived deformation history that was more complex that previously thought. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Monitoring, prediction, and early warning using ground-based radar interferometry   总被引：11，自引：8，他引：3  

Nicola Casagli  Filippo Catani  Chiara Del Ventisette  Guido Luzi 《Landslides》2010,7(3):291-301

In order to define adequate prevention measures and to manage landslide emergencies, real-time monitoring is required. This paper presents two different applications of the remote sensing technique: the ground-based synthetic aperture radar interferometry, here proposed as a monitoring and early warning support for slope instability. Data acquisitions carried out through a ground-based synthetic aperture radar interferometer, operating in K_u band, installed in front of the observed slopes, are discussed. Two case studies, based on the use of the same apparatus (formerly developed by the Joint Research Center of the European Commission and by Ellegi-LiSALab srl), are reported: the first one concerns the monitoring of a large landslide, named Ruinon (Valfurva, Italy). The second one deals with the monitoring of the NW unstable slope in the Stromboli island aimed to implementing an early warning system. Acquired interferometric data are processed to provide displacements and velocity maps of the monitored area. The monitoring services ongoing on the Ruinon landslide and on Stromboli demonstrate the capability of this technique to operate in different operative settings (i.e., different phenomena and geological framework) and for different aims (monitoring for prevention, early warning, and emergency assessment). This methodology has also been proved by national and regional authorities of civil protection in order to provide a real-time monitoring for emergency management.  相似文献   

Assessing parameter identifiability for multiple performance criteria to constrain model parameters     

Björn Guse  Jens Kiesel  Matthias Pfannerstill  Nicola Fohrer 《水文科学杂志》2020,65(7):1158-1172

ABSTRACT

Reliable simulations of hydrological models require that model parameters are precisely identified. In constraining model parameters to small ranges, high parameter identifiability is achieved. In this study, it is investigated how precisely model parameters can be constrained in relation to a set of contrasting performance criteria. For this, model simulations with identical parameter samplings are carried out with a hydrological model (SWAT) applied to three contrasting catchments in Germany (lowland, mid-range mountains, alpine regions). Ten performance criteria including statistical metrics and signature measures are calculated for each model simulation. Based on the parameter identifiability that is computed separately for each performance criterion, model parameters are constrained to smaller ranges individually for each catchment. An iterative repetition of model simulations with successively constrained parameter ranges leads to more precise parameter identifiability and improves model performance. Based on these results, a more consistent handling of model parameters is achieved for model calibration.  相似文献   

Spectroscopic evidence on organically-bound iron in natural and synthetic complexes with humic substances     

Nicola Senesi 《Geochimica et cosmochimica acta》1981,45(2):269-272

On the basis of a lack of Mössbauer evidence and of a vague interpretation of some i.r. absorptions, Dicksonet al. (1979) conclude that no iron directly bound to humic materials persists after the usually accepted extraction and separation procedures. Many statements in the paper by Dicksonet al. (1979) appear to be contradictory with this conclusion.In this comment the author has tried to demonstrate that Mössbauer spectroscopy alone cannot give an answer to the problem, but needs further spectroscopic and chemical evidence. Mössbauer data, overinterpreted by Dicksonet al. (1979). have been critically discussed, in comparison with similar data previously obtained by various authors. Large spectroscopic—mainly Mössbauer, ESR and i.r.—evidence have been given in order to demonstrate the already well ascertained existence of organically bound iron in natural and synthetic complexes with humic substances.  相似文献   

A method of determining optimum scales for averaging the earth's topography in quantitative studies of atmospheric cyclo- and anti-cyclogenesis     

Godev  Nicola 《Boundary-Layer Meteorology》1977,12(2):231-242

A method for optimum modelling of the earth's topography, corresponding to differing meteorological phenomena, is presented.The optimum averaging scale for mountains in terms of orographic cyclo- and anti-cyclogenesis is shown to be of the order of 150 km. The use of larger or smaller averaging scales decreases the correlation between the degree of cyclo- and anti-cyclogenesis and the parameters which describe the orography.A quantitative relation between orographic cyclo- and anti-cyclogenesis and the form of orography determined by the Laplacian ² Z ₀ of the terrain function Z ₀ = Z ₀(x, y) is presented.  相似文献   

On the cyclogenetic nature of the earth's orographic form     

Dr. Nicola Godev 《Meteorology and Atmospheric Physics》1970,19(1):299-310

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Environmental impact of the MV CITA on the foreshore of Porth Hellick, Isles of Scilly     

Smith NA 《Marine pollution bulletin》2004,49(11-12):1105-1108

The grounding of the container feeder vessel MV CITA on Newfoundland Rocks, Isles of Scilly, had an effect on the surrounding biota and benthic environment. Included in the CITA's cargo were five 40 ft containers holding pallets of polyester film used in the production of audio and visual recording tapes. The wreckage presented a minor but potentially chronic source of pollution through the delayed release of polythene film, which was left on the seabed as it was considered insufficiently valuable to warrant salvage. The polythene disintegrated and was washed upon the foreshore of Porth Hellick in minute shreds. The adjacent foreshore and two control sites within the islands were analysed using a 5-strand line and vegetation survey with 10 random quadrats within each line to determine the environmental impact of the polythene.  相似文献   

Post-collisional rapid exhumation and erosion during continental sedimentation: the example of the late Variscan Salvan-Dorénaz basin (Western Alps)     

Nicola?Capuzzo  Robert?Handler  Franz?Neubauer  Andreas?WetzelEmail author 《International Journal of Earth Sciences》2003,92(3):364-379

The Salvan-Dorénaz intramontane basin formed between ca. 308–293 Ma as an asymmetric graben along crustal-scale transtensional fracture zones within the Aiguilles-Rouges crystalline massif (Western Alps) and represents a feature of the post-collisional evolution of the Variscan orogens. It contains 1.5–1.7 km of continental clastic deposits which were eroded from granitic, volcanic, and metamorphic rocks. Textural and compositional immaturity of the sandstones, and the numerous lithic fragments with low chemical and physical stability suggest only short-range transport. ⁴⁰Ar/³⁹Ar analyses of detrital muscovite are interpreted to represent cooling of the crystalline basement below the respective closure temperatures. Ages from detrital muscovite range between ca. 280–330 Ma. ⁴⁰Ar/³⁹Ar white mica plateau ages from granitic boulders range between 301–312 Ma and suggest rapid cooling. The very short time interval recorded between the ⁴⁰Ar/³⁹Ar cooling ages and the stratigraphic age of the host sediment suggests that considerable portions of the upper crust were removed prior to the formation of the basin. Late Variscan granitic boulders document surface exposure and erosion of Late Carboniferous granites during early stages of the infilling of the basin. Therefore, unroofing of basement units, magmatic activity, and formation of the fault bounded Salvan-Dorénaz basin were acting concomitantly, and are highly suggestive of extensional tectonics. When compared with other orogens, this situation seems specific to the Variscan, especially the exclusively young ages of detrital material, however, modern analogous may exist.Electronic Supplementary Material Supplementary material is available for this article if you access the article at . A link in the frame on the left on that page takes you directly to the supplementary material.  相似文献   

Facies and basin architecture of the Late Carboniferous Salvan-Dorénaz continental basin (Western Alps, Switzerland/France)     

Nicola Capuzzo  Andreas Wetzel 《Sedimentology》2004,51(4):675-697

The Salvan‐Dorénaz Basin formed during the Late Palaeozoic within the Aiguilles‐Rouges crystalline basement (Western Alps) as an asymmetric, intramontane graben elongated in a NE–SW direction and bounded by active faults. At least 1700 m of fluvial, alluvial fan and volcanic deposits provide evidence for a strong tectonic influence on deposition with long‐term, average subsidence rates of > 0·2 mm yr^?1. The early basin fill was associated with coarse‐grained alluvial fans that were dominated by braided channels (unit I). These issued from the south‐western margin of the basin. The fans then retreated to a marginal position and were overlain by muddy floodplain deposits of an anastomosed fluvial system (unit II) that drained towards the NE. Deposition of thick muds resulted from a reduction in the axial fluvial gradient caused by accelerated tectonic subsidence. Overlying sand‐rich meandering river deposits (unit III) document a reversal in the drainage direction from the NE to the SW caused by synsedimentary tectonism, reflecting large‐scale topographic reorganization in this part of the Variscides with subsidence now preferentially in the W and SW and uplift in the E and NE. Coarse‐grained alluvial fan deposits (unit IV) repeatedly prograded into, and retreated from, the basin as documented by coarsening‐upward cycles tens of metres thick reflecting smaller scale tectonic cycles. Volcanism was active throughout the evolution of the basin, and U/Pb isotopic dating of the volcanic deposits restricts the time of basin development to the Late Carboniferous (308–295 Ma). ⁴⁰Ar/³⁹Ar ages of detrital white mica indicate rapid tectonic movements and exhumation of the nearby basement. In unit I, youngest ages are close to that of the host sediment, but the age spectrum is wide. In unit II, high subsidence and/or sedimentation rates coincide with very narrow age spectra, indicating small, homogeneous catchment areas. In unit III, age spectra became wider again and indicate growing catchment areas.  相似文献