We measured specific activities of the long‐lived cosmogenic radionuclides 60Fe in 28 iron meteorites and 53Mn in 41 iron meteorites. Accelerator mass spectrometry was applied at the 14 MV Heavy Ion Accelerator Facility at ANU Canberra for all samples except for two which were measured at the Maier‐Leibnitz Laboratory, Munich. For the large iron meteorite Twannberg (IIG), we measured six samples for 53Mn. This work doubles the number of existing individual 60Fe data and quadruples the number of iron meteorites studied for 60Fe. We also significantly extended the entire 53Mn database for iron meteorites. The 53Mn data for the iron meteorite Twannberg vary by more than a factor of 30, indicating a significant shielding dependency. In addition, we performed new model calculations for the production of 60Fe and 53Mn in iron meteorites. While the new model is based on the same particle spectra as the earlier model, we no longer use experimental cross sections but instead use cross sections that were calculated using the latest version of the nuclear model code INCL. The new model predictions differ substantially from results obtained with the previous model. Predictions for the 60Fe activity concentrations are about a factor of 2 higher, for 53Mn, they are ~30% lower, compared to the earlier model, which gives now a better agreement with the experimental data. 相似文献
Substantial isotopic fractionations are associated with many microbial sulfur metabolisms and measurements of the bulk δ34S isotopic composition of sulfur species (predominantly sulfates and/or sulfides) have been a key component in developing our understanding of both modern and ancient biogeochemical cycling. However, the interpretations of bulk δ34S measurements are often non-unique, making reconstructions of paleoenvironmental conditions or microbial ecology challenging. In particular, the link between the μm-scale microbial activity that generates isotopic signatures and their eventual preservation as a bulk rock value in the geologic record has remained elusive, in large part because of the difficulty of extracting sufficient material at small scales. Here we investigate the potential for small-scale (∼100 μm-1 cm) δ34S variability to provide additional constraints for environmental and/or ecological reconstructions. We have investigated the impact of sulfate concentrations (0.2, 1, and 80 mM SO4) on the δ34S composition of hydrogen sulfide produced over the diurnal (day/night) cycle in cyanobacterial mats from Guerrero Negro, Baja California Sur, Mexico. Sulfide was captured as silver sulfide on the surface of a 2.5 cm metallic silver disk partially submerged beneath the mat surface. Subsequent analyses were conducted on a Cameca 7f-GEO secondary ion mass spectrometer (SIMS) to record spatial δ34S variability within the mats under different environmental conditions. Isotope measurements were made in a 2-dimensional grid for each incubation, documenting both lateral and vertical isotopic variation within the mats. Typical grids consisted of ∼400-800 individual measurements covering a lateral distance of ∼1 mm and a vertical depth of ∼5-15 mm. There is a large isotopic enrichment (∼10-20‰) in the uppermost mm of sulfide in those mats where [SO4] was non-limiting (field and lab incubations at 80 mM). This is attributed to rapid recycling of sulfur (elevated sulfate reduction rates and extensive sulfide oxidation) at and above the chemocline. This isotopic gradient is observed in both day and night enrichments and suggests that, despite the close physical association between cyanobacteria and select sulfate-reducing bacteria, photosynthetic forcing has no substantive impact on δ34S in these cyanobacterial mats. Perhaps equally surprising, large, spatially-coherent δ34S oscillations (∼20-30‰ over 1 mm) occurred at depths up to ∼1.5 cm below the mat surface. These gradients must arise in situ from differential microbial metabolic activity and fractionation during sulfide production at depth. Sulfate concentrations were the dominant control on the spatial variability of sulfide δ34S. Decreased sulfate concentrations diminished both vertical and lateral δ34S variability, suggesting that small-scale variations of δ34S can be diagnostic for reconstructing past sulfate concentrations, even when original sulfate δ34S is unknown. 相似文献
Natural Hazards - In this study we estimate how flooded areas evolve on measures of social vulnerability over both the long and short term in Calgary, Canada. The first part of our analysis... 相似文献
It has recently been realized that the Arctic undergoes drastic changes, probably resulting from global change induced processes. This acts on the cycling of matter and on biogenic elements in the Arctic Ocean having feedback mechanisms with the global climate, for example by interacting with atmospheric trace gas concentration. A contemporary budget for biogenic elements as well as suspended matter for the Arctic Ocean as a baseline for comparison with effects of further global change is, thus, needed. Available budgets are based on the late Holocene sedimentary record and are therefore quiet different from the present which has already been affected by the intense anthropogenic activity of the last centuries.
We calculated a contemporary suspended matter and organic carbon budget for the Kara Sea utilizing the numerous available data from the recent literature as well as our own data from Russian-German SIRRO (Siberian River Run-off) expeditions. For calculation of the budgets we used a multi-box model to simplify the Kara Sea shelf and estuary system: input was assumed to comprise riverine and eolian input as well as coastal erosion, output was assumed to consist of sedimentation and export to the Arctic Ocean. Exchange with the adjacent seas was considered in our budget, and primary production as well as recycling of organic material was taken into account. According to our calculations, about 18.5 × 106 t yr− 1 of sediments and 0.37 × 106 t yr− 1 of organic carbon are buried in the estuaries, whereas 20.9 × 106 t yr− 1 sediment and 0.31 × 106 t yr− 1 organic carbon are buried on the shelf. Most sources and sinks of our organic carbon budget of the Kara Sea are in the same order of magnitude, making it a region very sensitive to further changes. 相似文献
Stable nitrogen isotopic ratios were measured in sinking particles and surface sediments from the South China Sea (SCS) in order to study recent nitrogen sources and degradation. Average δ15N values of 16 sediment traps deployed at seven locations in the northern, central and southern SCS were uniformly low, ranging between 2.7 and 4.5‰ with a winter minimum in the northern and central SCS. Enhanced nitrogen contents and δ15N values were noted in samples affected by swimmers, comprising between 5 and 20% of total nitrogen fluxes. Nitrate sources were subsurface waters from the western Pacific, which were isotopically depleted due to the remineralization of nitrogen from nitrogen fixation in surface waters. Nitrogen fixation in the SCS contributed up to 20% to the settling particles. In the southern SCS, resuspended matter close to the shelf added to the sinking particulates. The long-term trap record from the central SCS revealed decreasing δ15N values during the 1990s, which correspond with findings from the North Pacific Subtropical Gyre and may be attributable to increased nitrogen fixation due to global warming-related stratification. This trend may be restricted to the 1990s but could also persist due to the projection of more frequent occurrence of El Niño conditions.The δ15N increase from swimmer-free trap averages of 2.7–3.6‰ to values of 5–6‰ in underlying deep-sea sediments was in the same range as in other deep ocean areas. Similar to results from the northern Indian Ocean, this increase could be related to isotopic enrichment during amino acid degradation. The lowest sedimentary δ15N values characterize the Pinatubo ash layer deposited off Luzon in an event of mass sedimentation in 1991. The fast deposition of organic matter drawn from the surface waters with the ash in the form of vertical density currents evidently preserved the planktonic δ15N signal. 相似文献