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41.
42.
A statistically relevant correlation between the reaction rate coefficient, k
OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E
i,v, reveals two classes of compounds: aromatics where –log(k
OH/cm3s-1)3/2E
i,v(eV)–2 and aliphatics where –log(k
OH/cm3s-1)4/5E
i,v(eV)+3. The prediction of the rate coefficient, k
OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×105 cm3, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated. 相似文献
43.
The lysosomal membrane destabilization and the metallothionein content in the digestive gland cells of mussels (Mytilus galloprovincialis Lam.), collected along the east coast of the North Adriatic (Istrian and Kvarnerine coast, Croatia), were examined over a period of four years (1996–1999). The lysosomal membrane stability, as a biomarker of general stress, showed that the membrane labilization period in mussels from polluted, urban- and industrial-related areas was significantly decreased (p<0.05) when compared to mussels from control, clean sea water sites. In the harbour of Rijeka, the most contaminated site, the lysosomal membrane stability was reduced by more than 70% compared to the control. This method also proved to be a useful biomarker for detection of additional stress caused by short-term hypoxia that occurred once during this study inside the polluted and periodically quite eutrophic Pula Harbour. The concentration of metallothioneins in the mussel digestive gland, as a specific biomarker of exposure to heavy metals, did not reveal significant differences (p<0.05) between sites covered by this study. 相似文献
44.
45.
The present paper examines magmatic structures in the Jizera and Liberec granites of the Krkonoše–Jizera Plutonic Complex, Bohemian Massif. The magmatic structures are here interpreted to preserve direct field evidence for highly localized magma flow and other processes in crystal-rich mushes, and to capture the evolution of physical processes in an ancient granitic magma chamber. We propose that after chamber-wide mixing and hybridization, as suggested by recent petrological studies, laminar magma flow became highly localized to weaker channel-like domains within the higher-strength crystal framework. Mafic schlieren formed at flow rims, and their formation presumably involved gravitational settling and velocity gradient flow sorting coupled with interstitial melt escape. Local thermal or compositional convection may have resulted in the formation of vertical schlieren tubes and ladder dikes whereas subhorizontal tubes or channels formed during flow driven by lateral gradients in magma pressure. After the cessation or deceleration of channel flow, gravity-driven processes (settling of crystals and enclaves, gravitational differentiation, development of downward dripping instabilities), accompanied by compaction, filter pressing and melt segregation, dominated in the crystal mush within the flow channels. Subsequently, magmatic folds developed in schlieren layers and the magma chamber recorded complex, late magmatic strains at high magma crystallinities. Late-stage magma pulsing into localized submagmatic cracks represents the latest events of magmatic history of the chamber prior to its final crystallization. We emphasize that the most favorable environments for the formation and preservation of magmatic structures, such as those hosted in the Jizera and Liberec granites, are slowly cooling crystal-rich mushes. Therefore, where preserved in plutons, these structures may lend strong support for a “mush model” of magmatic systems. 相似文献
46.
A. V. Shavrina N. S. Polosukhina J. Zverko V. Khalak V. V. Tsymbal J. Žižňovský 《Astronomy Reports》2001,45(10):784-796
The spectra of two roAp stars have been analyzed as part of a project to study lithium in magnetic Ap stars. Variability of the Li I 6708 Å resonance doublet and rare-earth lines was detected, which can be explained using an oblique rotator model with the lithium spots located at the magnetic poles. Synthetic spectra obtained at different rotational phases have yielded the first data on the atmospheric chemical compositions of these spotted stars. Using refined atomic data and the most complete line lists has enabled a detailed study of the spectra near the Li I 6708 Å line and computation of the Li I line profile taking into account the spotted distribution of the lithium over the stellar surfaces. The positions of two lithium spots and lithium abundances for each of the spots have been determined. 相似文献
47.
P. M. Nikolić S. Ðurić D. M. Todorović D. Vasiljević-Radović V. Blagojević P. Mihajlović J. Elazar K. T. Radulović A. I. Bojičić D. Urošević 《Physics and Chemistry of Minerals》2001,28(1):44-51
Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D T≈0.16 × 10?5 m2 s?1), the coefficient of diffusion (D between 0.15×10?2 0.16×10?2 m2 s?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s g≈65.5 m s?1 and s b≈66.4 m s?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×1018 cm?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed. 相似文献
48.
Djuro Radinović 《Pure and Applied Geophysics》1972,93(1):159-176
Summary A numerical model for the quantitative precipitation forecasting has been formulated. In this model precipitation is computed as a function of the vertical velocity and humidity distribution in the atmosphere. The orographic influence on the vertical velocity was taken into consideration. Further, the relation between vertical velocity and static stability of the atmosphere has been considered and, as an important factor in the condensation process, was introduced into the equation of the model. This numerical model for the precipitation forecasting has been applied in the North Adriactic Sea region, which is characterized by a strong vertical gradient of the specific humidity and pronounced orographic influence. The results achieved show that this model could successfully be used as an objective method in the routine forecasting of the amount of precipitation. 相似文献
49.
Lj. Barić 《Mineralogy and Petrology》1969,13(3-4):233-249
Zusammenfassung In der Umgebung der Stadt Prilep in Mazedonien kommen an mehreren Stellen in einer hochmetamorphen, aus Glimmerschiefern und Amphiboliten bestehenden Zone Calcit- und Dolomitmarmore vor. In den letzterwähnten wurden bisher Dolomit, Calcit, Korund, Diaspor, -Zoisit, Rutil, Fluorit, Achroit, Pyrit, Muskovit, Illit, Margarit und Chlorit (vonErdmannnsdörfer auch Kossmatit) festgestellt. Diese Paragenese ist regionalmetamorph entstanden.
Mit 1 Abbildung 相似文献
Dolomite-marble in the surroundings of the town prilep, macedonia, and its minerals
Summary Calcite- and dolomite-marbles occur in a highly metamorphic series together with micaschists and amphibolites at several localities in the surroundings of Prilep, Macedonia. In the dolomite-marbles, dolomite, calcite, corundum, diaspore, -zoisite, rutile, fluorite, achroite pyrite, muscovite, illite, margarite, chlorite, and kossmatite (the last only byErdmannsdörffer) have been found. The paragenesis is of regional metamorphic origin.
Mit 1 Abbildung 相似文献
50.
Milan Stojković Jasna Plavšić Stevan Prohaska Dragutin Pavlović Jovan Despotović 《水文科学杂志》2020,65(3):387-400
ABSTRACTClimate change projections of precipitation and temperature suggest that Serbia could be one of the most affected regions in southeastern Europe. To prepare adaptation measures, the impact of climate changes on water resources needs to be assessed. Pilot research is carried out for the Lim River basin, in southeastern Europe, to predict monthly flows under different climate scenarios. For estimation of future water availability, an alternative approach of developing a deterministic-stochastic time series model is chosen. The proposed two-stage time series model consists of several components: trend, long-term periodicity, seasonality and the stochastic component. The latter is based on a transfer function model with two input variables, precipitation and temperature, as climatic drivers. The Nash-Sutcliffe model efficiency for the observed period 1950–2012 is 0.829. The model is applied for the long-term hydrological prediction under the representative concentration pathway (RCP) emissions scenarios for the future time frame 2013–2070. 相似文献