Effects of pH and temperature on dimerization rate of glycine: Evaluation of favorable environmental conditions for chemical evolution of life     

Kasumi Sakata  Norio Kitadai 《Geochimica et cosmochimica acta》2010,74(23):6841-6851

To evaluate favorable environmental conditions for the chemical evolution of life, we studied the effects of pH and temperature on the dimerization rate of glycine (Gly: NH₂-CH₂-COOH), one of the simplest amino acids. Gly dimerizes to form glycylglycine (GlyGly), and GlyGly further reacts to form diketopiperazine (DKP). Gly solutions with pH ranging from 3.1 to 10.9 were heated for 1-14 days at 140 °C, and changes in concentrations of Gly, GlyGly, and DKP were evaluated. At pH 9.8, the experiments were conducted at 120, 140, 160, and 180 °C. The dimerization rate of Gly was nearly constant at pH 3-7 and increased with increasing pH from 7 to 9.8 and then decreased with further increases in pH. To elucidate the reason for this pH dependency, we evaluated the role of the three dissociation states of Gly (cationic state: Gly⁺, zwitterionic state: Gly^±, and anionic state: Gly⁻). For pH >6, the dominant forms are Gly^± and Gly⁻, and the molar fraction of Gly^± decreases and that of Gly⁻ increases with increasing pH. The dimerization rate was determined for each dissociation state. The reaction between Gly^± and Gly⁻ was found to be the fastest; the rate constant of the reaction between Gly^± and Gly⁻ was 10 times the size of that between Gly⁻ and Gly⁻ and 98 times that between Gly^± and Gly^±. The dimerization rate became greatest at pH 9.8 because the molar fractions of Gly^± and Gly⁻ are approximately equal at this pH. The dimerization rate increased with temperature, and an activation energy of 88 kJ mol⁻¹ was obtained. Based on these results and previous reports on the stability of amino acids under hydrothermal conditions, we determined that Gly dimerizes most efficiently under alkaline pH (∼9.8) at about 150 °C.  相似文献   

基于格网数据的洪水灾害风险评估方法——以日本新川洪灾为例   总被引：13，自引：1，他引：12  

张超万庆  张继权NorioOkada 励惠国 《地球信息科学学报》2003,5(4):69-73

本文对日本格网统计数据的历史、体系以及结构进行了介绍 ,并应用地理信息技术给出了各级格网的自动生成方法。同时以 2 0 0 0年日本新川洪水灾害为案例 ,建立了二维洪水演进水动力学模型 ,并采用地理信息系统与水动力学模型结合的方法对新川破堤洪水泛滥进行了模拟 ,同时对洪泛区灾害损失进行了评估 ,得到的结果为进一步评估洪水灾害风险以及确定合理的洪灾保险费率奠定了基础 ,对于格网统计数据在城市规划以及城市减灾等领域的应用也有一定的借鉴意义。  相似文献   

Wind Fields over Funka Bay and Their Effect on Water Circulation in the Bay     

Jun Inoue  Masayuki Kawashima  Kay I. Ohshima  Yasushi Fujiyoshi  Ken-ichi Maruyama 《Journal of Oceanography》2000,56(5):507-515

Horizontal wind fields over Funka Bay during cold air outbreaks were simulated using a 3-D meso-scale atmospheric model. The simulated wind fields over the bay have a positive curl in the north and a negative curl in the south. These wind fields were used to simulate the current in Funka Bay using a barotropic ocean model. The simulated current pattern was composed of two vortices—one with anti-clockwise vorticity in the north and the other with clockwise vorticity in the south—and was in the opposite direction to that simulated by the uniform wind fields. This is because the wind stress curl effect on the vorticity production in Funka Bay opposes and overwhelms the bathymetry torque effect during cold air outbreaks. These results show that the non-uniformity of the wind fields caused by the land topography around a shallow lake or bay cannot be neglected in simulating its currents.  相似文献   

Comparison of AGASA data with CORSIKA simulation     

M. Nagano  D. Heck  K. Shinozaki  N. Inoue  J. Knapp 《Astroparticle Physics》2000,13(4):209-294

An interpretation of Akeno giant air shower array (AGASA) data by comparing the experimental results with the simulated ones by cosmic ray simulation for KASCADE (CORSIKA) has been made. General features of the electromagnetic component and low energy muons observed by AGASA can be well reproduced by CORSIKA. The form of the lateral distribution of charged particles agrees well with the experimental one between a few hundred metres and 2000 m from the core, irrespective of the hadronic interaction model studied and the primary composition (proton or iron). It does not depend on the primary energy between 10^17.5 and 10²⁰ eV as the experiment shows. If we evaluate the particle density measured by scintillators of 5 cm thickness at 600 m from the core S₀(600), suffix 0 denotes the vertically incident shower) by taking into account the similar conditions as in the experiment, the conversion relation from S₀(600) to the primary energy is expressed as E (eV)=2.15×10¹⁷S₀(600)^1.015 within 10% uncertainty among the models and composition used, which suggests the present AGASA conversion factor is the lower limit. Although the form of the muon lateral distribution fits well to the experiment within 1000 m from the core, the absolute values change with hadronic interaction model and primary composition. The slope of the ρ_μ(600) (muon density above 1 GeV at 600 m from the core) vs. S₀(600) relation in experiment is flatter than that in simulation of any hadronic model and primary composition. As the experimental slope is constant from 10¹⁵ to 10¹⁹ eV, we need to study this relation in a wide primary energy range to infer the rate of change of chemical composition with energy.  相似文献   

ASCA Observations of X-ray Emission from Ultra-luminous Infrared Galaxies     

Takao Nakagawa  Tsuneo Kii  Ryuichi Fujimoto  Toshiyuki Miyazaki  Hajime Inoue  Yasushi Ogasaka  Ryohei Kawabe 《Astrophysics and Space Science》1999,266(1-2):43-48

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Vertical profiles of nitrous oxide and dissolved oxygen in marine sediments     

Toshihiro Usui  Isao Koike  Norio Ogura   《Marine Chemistry》1998,59(3-4)

The whole core squeezing method was used to simultaneously obtain profiles of nitrous oxide (N₂O), nitrogenous nutrients, and dissolved oxygen in sediments of Koaziro Bay, Japan (coastal water), the East China Sea (marginal sea), and the central Pacific Ocean (open ocean). In the spring of Koaziro Bay, subsurface peaks of interstitial N₂O (0.5–3.5 cm depth) were observed, at which concentrations were higher than in the overlying water. This was also true for nitrate (NO₃⁻) and nitrite (NO₂⁻) profiles, suggesting that the transport of oxic overlying water to the depth through faunal burrows induced in situ N₂O production depending on nitrification. In the summer of Koaziro Bay, sediment concentrations of N₂O, NO₃⁻ and NO₂⁻ were lower than in the overlying water. In most East China Sea sediments, both N₂O and NO₃⁻ decreased sharply in the top 0.5–2 cm oxic layer (oxygen: 15–130 μM), which may have indicated N₂O and NO₃⁻ consumption by denitrification at anoxic microsites. N₂O peaks at subsurface depth (0.5–6.5 cm) implied in situ production of N₂O and/or its supply from the overlying water through faunal burrows. However, the occurrence of the latter process was not confirmed by the profiles of other constituents. In the central Pacific Ocean, the accumulation of N₂O and NO₃⁻ in the sediments likely resulted from nitrification. Nitrous oxide fluxes from the sediments, calculated using its gradient at the sediment–water interface and the molecular diffusion coefficient, were −45 to 6.9 nmolN m⁻² h⁻¹ in Koaziro Bay in the spring, −29 to −21 nmolN m⁻² h⁻¹ in the summer, −46 to 37 nmolN m⁻² h⁻¹ in the East China Sea, 0.17 to 0.23 nmolN m⁻² h⁻¹ in the equatorial Pacific, and <±0.2 nmolN m⁻² h⁻¹ in the subtropical North Pacific, respectively.  相似文献   

Effective location of active control devices for building vibrations caused by periodic excitation acting on intermediate storey     

Liping Xing  Eizaburo Tachibana  Yutaka Inoue 《地震工程与结构动力学》2000,29(2):177-193

In order to investigate ways of reducing vibrations of building structures subjected to excitation acting on intermediate storey, active vibration controls are conducted with active control devices installed on different floors of the structure, and the effective location of control devices is also investigated. In this paper, we propose a new ‘Discrete‐Optimizing Control Method’ for vibration control. The control forces are determined analytically which makes the ‘discrete‐index function’ minimum. Through numerical simulation, the Discrete‐Optimizing Control Method is proved to be an effective control method. The response reduction effects are best when the control devices are concentrated on the adjacent three floors of the vibration source. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

Assessing land-use and carbon stock in slash-and-burn ecosystems in tropical mountain of Laos based on time-series satellite images     

Yoshio Inoue  Yoshiyuki Kiyono  Hidetoshi Asai  Yukihito Ochiai  Jiaguo Qi  Albert Olioso  Tatsuhiko Shiraiwa  Takeshi Horie  Kazuki Saito  Linkham Dounagsavanh 《International Journal of Applied Earth Observation and Geoinformation》2010

In the tropical mountains of Southeast Asia, slash-and-burn (S/B) agriculture is a widely practiced and important food production system. The ecosystem carbon stock in this land-use is linked not only to the carbon exchange with the atmosphere but also with food and resource security. The objective of this study was to provide quantitative information on the land-use and ecosystem carbon stock in the region as well as to infer the impacts of alternative land-use and ecosystem management scenarios on the carbon sequestration potential at a regional scale. The study area was selected in a typical slash-and-burn region in the northern part of Laos. The chrono-sequential changes of land-use such as the relative areas of community age and cropping (C) + fallow (F) patterns were derived from the analysis of time-series satellite images. The chrono-sequential analysis showed that a consistent increase of S/B area during the past three decades and a rapid increase after 1990. Approximately 37% of the whole area was with the community age of 1–5 years, whereas 10% for 6–10 years in 2004. The ecosystem carbon stock at a regional scale was estimated by synthesizing the land-use patterns and semi-empirical carbon stock model derived from in situ measurements where the community age was used as a clue to the linkage. The ecosystem carbon stock in the region was strongly affected by the land-use patterns; the temporal average of carbon stock in 1C + 10F cycles, for example, was greater by 33 MgC ha⁻¹ compared to that in 1C + 2F land-use pattern. The amount of carbon lost from the regional ecosystems during 1990–2004 periods was estimated to be 42 MgC ha⁻¹. The study approach proved to be useful especially in such regions with low data-availability and accessibility. This study revealed the dynamic change of land-use and ecosystem carbon stock in the tropical mountain of Laos as affected by land-use. Results suggest the significant potential of carbon sequestration through changing land-use and ecosystem management scenarios. These quantitative estimates would be useful to better understand and manage the land-use and ecosystem carbon stock towards higher sustainability and food security in similar ecosystems.  相似文献   

Dynamic non-linear analysis of reinforced concrete shear wall by finite element method with explicit analytical procedure     

Norio Inoue  Kejian Yang  Akenori Shibata 《地震工程与结构动力学》1997,26(9):967-986

A numerical procedure for a dynamic non-linear finite element analysis is proposed here to analyse three-dimensional reinforced concrete shear wall structures subjected to earthquake motions. A shear wall is modelled as a quasi-three dimensional structure which is composed of plane elements considering the in-plane stiffness of orthogonal flange panels. The proposed constitutive model is based on the non-linearity of reinforcement and concrete in which the tension stiffening in tension and the degradation of stiffness and strength in compression of concrete after cracking are considered. The acceleration-pulse method, which is a kind of explicit analytical procedure, is employed to solve the non-linear dynamic equations, where the dynamic equation can be solved without stiffness matrix and so the iterative procedure is not necessary for descending portion of stress–strain relationship caused by cracking and softening after compressive strength in concrete. The damping effect is considered by assuming equivalent viscous damping which can give good cyclic behaviours of inertia force vs. displacement relationships. This analytical method was applied to a test specimen of a reinforced concrete shear wall with a H-shaped section which was vibrated up to failure by using a large-scale shaking table with high -performance in Japan. The test was performed as one of the dynamic model tests for evaluation of seismic behaviour of nuclear reactor buildings. The calculations were performed sequentially from the elastic range to failure. The comparison with the test results shows that this approach has good accuracy. © 1997 by John Wiley & Sons Ltd  相似文献