Confined fluids and their role in pressure solution     

Alessandro Anzalone  James Boles  George Greene  Kevin Young  Jacob Israelachvili  Norma Alcantar   《Chemical Geology》2006,230(3-4):220-231

The process of pressure solution is defined as the dissolution of materials under high stress at grain-to-grain contacts and precipitation at interfaces under low stress. The kinetics of this process are still poorly understood mainly because of the large timescales involved. In this research, the Surface Forces Apparatus (SFA) technique was coupled with an optical interference technique for in situ visualization of the nanoscale deformations and thickness changes. The SFA was used to measure the forces (or pressures) and distances between two solid surfaces pressed together with a thin film between them. Using the SFA, combined with geological observations, we are studying the short-range colloidal forces between surfaces of mica and silica at the nanoscale such as van der Waals, electrostatic, and hydration forces.

This study involves two cases, the symmetric case of mica in contact with mica and the asymmetric case of a quartz surface in contact with mica. Our results reveal highly subtle effects depending on the nature and concentration of the counterions present in the solution either of Na⁺, Ca²⁺, or mixtures of these ions, as well as on the pH. For the symmetric case, the equilibrium interactions of force F or pressure P versus fluid film thickness T have been measured between the mica surfaces across aqueous films in the thickness range from T = 25 Å down to contact separations around T = 0 Å, and depend on the solution conditions and applied lithostatic pressure. Measurements have also been made of the rates of diffusion of ions through such ultra-thin films and on the precipitation and growth of ionic crystallite layers on the surfaces. Our results show that the diffusion coefficient of hydrated sodium is two orders of magnitude lower than the diffusion of water into mica–mica cleavage and a factor of 40 lower than the coefficient of sodium ions in bulk water.

For the asymmetric case, the dissolution of the quartz surface was observed to be dependent on the interfacial fluid composition and pH, the externally applied ‘lithostatic’ pressure, and the type of crystalline structure exposed to the mica surface. Our experiments also show that there is an initial stage after fresh solution is added in which the spacing between the surfaces increases, however, the thickness started decreasing steadily after approximately 4 h of exposure independently of the crystallinity of the quartz surface. For a particular set of conditions, the process eventually slows down and reaches equilibrium after some time, but a further increase in pressure restarts the dissolution process. This is also true for the addition of fresh interfacial solution during the experiment after a period of thickness fluctuation. These results are consistent with the observation that pressure solution of quartz is greatly enhanced with the presence of mica.  相似文献   

Sorption of silica by clay minerals     

Raymond Siever  Norma Woodford 《Geochimica et cosmochimica acta》1973,37(8):1851-1880

Clay minerals were reacted with silica-spiked solutions of unbuffered distilled water; water buffered at pH 5.5, 8 and 10; alkali chloride solutions; natural and artificial sea water to assess the influence of pH, silica and cation activities. The data are plotted as silica produced by dissolution or sorption of silica by clay surface as a function of initial silica concentration at a given pH and solution composition. This allows the determination of the dissolved silica value at which the clay mineral surface neither dissolves nor sorbs silica. The values of the various activities in different solutions are used to infer the phase equilibria between solution, clay mineral and the surface phase produced either by dissolution or sorption. Most intensively investigated were sorption reactions of kaolinite in sea water and other ionic solutions to form silica-rich, cation-rich surface phases in cationic solutions and silica-rich phases in cation-free solutions.Inferred equilibrium constants imply that silicate reconstitution is doubtful as a mechanism for partial control of silica and cation composition of sea water but is reasonable in silica-rich interstitial waters.  相似文献   

A comparison of surface and underground array measurements of ambient noise recorded in Naples (Italy)     

Rosalba Maresca  Norma Damiano  Lucia Nardone  Mauro A. Di Vito  Francesca Bianco 《Journal of Seismology》2014,18(3):385-400

In this study, we describe two experiments of seismic noise measurements carried out in Naples, Italy. The site allowed measurements to be obtained both at the surface and in a tunnel that is 120-m-deep. The main goal was to compare the seismic response evaluated at the surface to the in-tunnel response, through spectral, polarization, and resonance directivity analyses. In the 1 to 20 Hz frequency band, the noise level was up to 15 dB higher at the surface than in the tunnel. The polarization properties and horizontal-to-vertical spectral ratios appear not to be influenced by the tunnel geometry or by the topography. Some preferential alignments were observed in the polarization azimuths computed at the surface, which are likely to be due to local sources, rather than morphological features. The absence of directivity effects and the low noise levels in the tunnel make this site suitable for installing seismic stations. We also studied how the subsoil structure affects the seismic motion at the surface. The dispersive properties of the Rayleigh waves were investigated using the spatial autocorrelation method. A joint inversion of the dispersion data and the horizontal-to-vertical spectral ratios provided the subsurface Vs profile. The derived model has a low velocity contrast at depth, such as to generate moderate and broad H/V spectral ratio peak amplitude. The normalized spectral ratio appears more appropriate to identify the soil-resonance frequencies.  相似文献   

Effect of composition,structure, and spin state on the thermal conductivity of the Earth's lower mantle     

A.F. Goncharov  V.V. Struzhkin  J.A. Montoya  S. Kharlamova  R. Kundargi  J. Siebert  J. Badro  D. Antonangeli  F.J. Ryerson  W. Mao 《Physics of the Earth and Planetary Interiors》2010,180(3-4):148-153

The change in electronic structure of iron at high pressures to spin-paired states in ferropericlase, silicate perovskite, and post-perovskite may have a profound influence on the thermal conductivity of the lower mantle. Here, we present optical absorption data for lower mantle minerals to assess the effect of composition (including iron oxidation state), structure, and iron spin state on radiative heat transfer. We confirm that the presence of ferric iron in ferropericlase strongly affects the optical properties, while the effect of the spin-pairing transition may be more secondary. We also show that post-perovskite exhibits larger optical absorption in the near infrared and visible spectral ranges than perovskite which may have a profound effect on the dynamics the lowermost mantle. We present preliminary results from measurements of the phonon thermal conductivity of perovskite at 125 GPa using a pulsed laser heating technique. The available data suggest a larger value than what previously estimated, although the uncertainty is large.  相似文献   

Variability of the Atlantic meridional overturning circulation in the last millennium and two IPCC scenarios     

Pablo Ortega  Marisa Montoya  Fidel González-Rouco  Juliette Mignot  Stephanie Legutke 《Climate Dynamics》2012,38(9-10):1925-1947

The variability of the Atlantic meridional overturning circulation (AMOC) is investigated in several climate simulations with the ECHO-G atmosphere-ocean general circulation model, including two forced integrations of the last millennium, one millennial-long control run, and two future scenario simulations of the twenty-first century. This constitutes a new framework in which the AMOC response to future climate change conditions is addressed in the context of both its past evolution and its natural variability. The main mechanisms responsible for the AMOC variability at interannual and multidecadal time scales are described. At high frequencies, the AMOC is directly responding to local changes in the Ekman transport, associated with three modes of climate variability: El Ni?o-Southern Oscillation (ENSO), the North Atlantic Oscillation (NAO), and the East Atlantic (EA) pattern. At low frequencies, the AMOC is largely controlled by convection activity south of Greenland. Again, the atmosphere is found to play a leading role in these variations. Positive anomalies of convection are preceded in 1?year by intensified zonal winds, associated in the forced runs to a positive NAO-like pattern. Finally, the sensitivity of the AMOC to three different forcing factors is investigated. The major impact is associated with increasing greenhouse gases, given their strong and persistent radiative forcing. Starting in the Industrial Era and continuing in the future scenarios, the AMOC experiences a final decrease of up to 40% with respect to the preindustrial average. Also, a weak but significant AMOC strengthening is found in response to the major volcanic eruptions, which produce colder and saltier surface conditions over the main convection regions. In contrast, no meaningful impact of the solar forcing on the AMOC is observed. Indeed, solar irradiance only affects convection in the Nordic Seas, with a marginal contribution to the AMOC variability in the ECHO-G runs.  相似文献   

Comparison of the last interglacial climate simulated by a coupled global model of intermediate complexity and an AOGCM     

C. Kubatzki  M. Montoya  S. Rahmstorf  A. Ganopolski  M. Claussen 《Climate Dynamics》2000,16(10-11):799-814

The climate at the Last Interglacial Maximum (125 000 years before present) is investigated with the atmosphere-ocean general circulation model ECHAM-1/LSG and with the climate system model of intermediate complexity CLIMBER-2. Comparison of the results of the two models reveals broad agreement in most large-scale features, but also some discrepancies. The fast turnaround time of CLIMBER-2 permits one to perform a number of sensitivity experiments to (1) investigate the possible reasons for these differences, in particular the impact of different freshwater fluxes to the ocean, (2) analyze the sensitivity of the results to changes in the definition of the modern reference run concerning CO₂ levels (preindustrial versus “present”), and (3) estimate the role of vegetation in the changed climate. Interactive vegetation turns out to be capable of modifying the initial climate signals significantly, leading especially to warmer winters in large parts of the Northern Hemisphere, as indicated by various paleodata. Differences due to changes in the atmospheric CO₂ content and due to interactive vegetation are shown to be at least of the same order of magnitude as differences between the two completely different models, demonstrating the importance of careful experimental design.  相似文献   

Detailed Analysis of Solar Data Related to Historical Extreme Geomagnetic Storms: 1868 – 2010     

Laure Lefèvre  Susanne Vennerstrøm  Mateja Dumbović  Bojan Vršnak  Davor Sudar  Rainer Arlt  Frédéric Clette  Norma Crosby 《Solar physics》2016,291(5):1483-1531

  相似文献   

K. Scherer, H. Fichtner, B. Heber, U. Mall (eds.), Space Weather: The Physics Behind a Slogan, Lecture Notes in Physics     

Norma B. Crosby 《Surveys in Geophysics》2006,27(4):489-490

  相似文献   

Do Pharmaceuticals, Pathogens, and Other Organic Waste Water Compounds Persist When Waste Water Is Used for Recharge?   总被引：3，自引：0，他引：3  

Gail E. Cordy  Norma L. Duran  Herman Bouwer  Robert C. Rice  Edward T. Furlong  Steven D. Zaugg  Michael T. Meyer  Larry B. Barber  Dana W. Kolpin 《Ground Water Monitoring & Remediation》2004,24(2):58-69

  相似文献   

Dissolution kinetics and the weathering of mafic minerals     

Raymond Siever  Norma Woodford 《Geochimica et cosmochimica acta》1979,43(5):717-724

Fayalite, hypersthene, basalt, and obsidian were dissolved in buffered solutions (25°C; pH 4.5 and 5.5) under air, N₂ or O₂ atmospheres, in order to follow the kinetics of dissolution. Each dissolved more rapidly at lower pH values, dissolving most rapidly in the initial few days, followed by slower dissolution for periods up to six months. Dissolution was more rapid when air was excluded. In oxygen atmospheres an Fe(OH)₃ precipitate armors mineral surfaces, thus inhibiting further dissolution, and further affects the solution by scavenging dissolved silica and cations. Dissolution reactions include initial exchange between cations and H⁺, incongruent dissolution of silicate structures, oxidation of Fe²⁺ in solution, precipitation of Fe(OH)₃, and scavenging of dissolved silica and cations by Fe(OH)₃. Dissolution kinetics may explain weathering of mafic rocks and minerals at the Earth's surface, the formation of Fe-oxide coatings on mineral grains, weathering of submarine mafic rocks and intrastratal solution of mafic minerals in buried sandstones. Early Precambrian weathering would have been more rapid before the appearance of large amounts of oxygen in the atmosphere, and continental denudation rates may have been higher than at present because of this effect and the predominance of mafic igneous rocks at an early stage of continent formation and growth.  相似文献