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121.
Manfred Burianek Johannes Birkenstock Philipp Mair Volker Kahlenberg Olaf Medenbach Robert D. Shannon Reinhard X. Fischer 《Physics and Chemistry of Minerals》2016,43(7):527-534
Single crystals of B2O3 are needed for the precise determination of the refractive indices used to calculate the electronic polarizability α of 3-coordinated boron. The α(B) values in turn are used to predict mean refractive indices of borate minerals. Since the contribution of boron to the total polarizability of a mineral is very low, the synthetic compound B2O3 represents an ideal model system because of its high molar content of boron. Millimeter-sized crystals were synthesized at 1 GPa in a piston-cylinder apparatus. The samples were heated above the liquidus (800 °C), subsequently cooled at 15 °C/h to 500 °C and finally quenched. The refractive indices were determined by the immersion method using a microrefractometer spindle stage. The refractive indices n o = 1.653 (3) and n e = 1.632 (3) correspond to a total polarizability for B2O3 of α = 4.877 Å3. These values were used to determine the electronic polarizability of boron of α(B) = 0.16 Å3. Although the surface of the B2O3 crystals was coated with a hydrous film immediately after being exposed to air, its bulk crystallinity is retained for a period of at least 2 months. 相似文献
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Nicole Kowalski Olaf Dellwig Melanie Beck Maik Grunwald Sibylle Fischer Maike Piepho Thomas Riedel Holger Freund Hans-Jürgen Brumsack Michael E. Böttcher 《Ocean Dynamics》2009,59(2):333-350
Tidal and seasonal behaviour of the redox-sensitive trace metals Mn, Fe, Mo, U, and V have been investigated in the open-water
column and shallow pore waters of the backbarrier tidal flats of the island of Spiekeroog (Southern North Sea) in 2002 and
2007. The purpose was to study the response of trace metal cycles on algae blooms, which are assumed to cause significant
changes in the redox state of the entire ecosystem. Trace metal data were complemented by measurements of nutrients and enumeration
of algae cells in 2007. Generally, Mn and V show a tidal cyclicity in the water column with maximum values during low tide
which is most pronounced in summer due to elevated microbial activity in the sediments. Mo and U behave almost conservatively
throughout the year with slightly increasing levels towards high tide. Exceptions are observed for both metals after summer
algae blooms. Thus, the seasonal behaviour of the trace metals appear to be significantly influenced by productivity in the
water column as the occurrence of algae blooms is associated with an intense release of organic matter (e.g. transparent exopolymer
particles, TEP) thereby forming larger organic-rich aggregates. Along with elevated temperatures in summer, the deposition
of such aggregates favours microbial activity within the surface sediments and release of DOC, nutrients and trace metals
(Mn, Mo and V) during the degradation of the aggregates. Additionally, pronounced reducing conditions lead to the reduction
of Mn(IV)-oxides and Fe(III)-(oxihydr)oxides, thereby releasing formerly scavenged compounds as V and phosphate. Therefore,
pore-water profiles show significant enrichments in trace metals especially from July to September. Finally, the trace metals
are released to the open water column via draining pore waters (esp. Mo, Mn, and V) and/or fixed in the sediment as sulphides
(Fe, Mo) and bound to organic matter (U). Non-conservative behaviour of Mo in oxygenated seawater, first observed in the investigation
area by Dellwig et al. (Geochim Cosmochim Acta 71:2745–2761, 2007a), was shown to be a recurrent phenomenon which is closely coupled to bacterial activity after the breakdown of algae blooms.
In addition to the postulated fixation of Mo in oxygen-depleted micro-zones of the aggregates or by freshly formed organic
matter, a direct removal of Mo from the water column by reduced sediment surfaces may also play an important role. 相似文献
126.
Andrea Lübben Olaf Dellwig Sandra Koch Melanie Beck Thomas H. Badewien Sibylle Fischer Rainer Reuter 《Ocean Dynamics》2009,59(2):263-275
The spatial and temporal distributions of chromophoric dissolved organic matter (CDOM) and dissolved organic carbon (DOC)
was studied in the East-Frisian Wadden Sea (Southern North Sea) during several cruises between 2002 and 2005. The spatial
distribution of CDOM in the German Bight shows a strong gradient towards the coast. Tidal and seasonal variations of dissolved
organic matter (DOM) identify freshwater discharge via flood-gates at the coastline and pore water efflux from tidal flat
sediments as the most important CDOM sources within the backbarrier area of the Island of Spiekeroog. However, the amount
and pattern of CDOM and DOC is strongly affected by various parameters, e.g. changes in the amount of terrestrial run-off,
precipitation, evaporation, biological activity and photooxidation. A decoupling of CDOM and DOC, especially during periods
of pronounced biological activity (algae blooms and microbial activity), is observed in spring and especially in summer. Mixing
of the endmembers freshwater, pore water, and open sea water results in the formation of a coastal transition zone. Whilst
an almost conservative behaviour during mixing is observed in winter, summer data point towards non-conservative mixing. 相似文献
127.
David Thistle Lisa A. Levin Andrew J Gooday Olaf Pfannkuche P John D. Lambshead 《Deep Sea Research Part I: Oceanographic Research Papers》1999,46(12):185
Although much of the deep sea is physically tranquil, some regions experience near-bottom flows that rework the surficial sediment. During periods of physical reworking, animals in the reworked layer risk being suspended, which can have both positive and negative effects. Reworking can also change the sediment in ecologically important ways, so the fauna of reworked sites should differ from that of quiescent locations. We combined data from two reworked, bathyal sites on the summit of Fieberling Guyot (32°27.631′N, 127°49.489′W; 32°27.581′N, 127°47.839′W) and compared the results with those of more tranquil sites. We tested for differences in the following parameters, which seemed likely to be sensitive to the direct or indirect effects of reworking: (1) the vertical distribution of the meiofauna in the sea bed, (2) the relative abundance of surface-living harpacticoids, (3) the proportion of the fauna consisting of interstitial harpacticoids, (4) the ratio of harpacticoids to nematodes. We found that the vertical distributions of harpacticoid copepods, ostracods, and kinorhynchs were deeper on Fieberling. In addition, the relative abundance of surface-living harpacticoids was less, the proportion of interstitial harpacticoids was greater, and the ratio of harpacticoids to nematodes was greater on Fieberling. These differences between Fieberling and the comparison sites suggest that physical reworking affects deep-sea meiofauna and indicate the nature of some of the effects. 相似文献
128.
Jochen Vogl Martin Rosner Simone A. Kasemann Rebecca Kraft Anette Meixner Janine Noordmann Savelas Rabb Olaf Rienitz Jan A. Schuessler Michael Tatzel Robert D. Vocke 《Geostandards and Geoanalytical Research》2020,44(3):439-457
The continuous improvement of analytical procedures using multi‐collector technologies in ICP‐mass spectrometry has led to an increased demand for isotope standards with improved homogeneity and reduced measurement uncertainty. For magnesium, this has led to a variety of available standards with different quality levels ranging from artefact standards to isotope reference materials certified for absolute isotope ratios. This required an intercalibration of all standards and reference materials, which we present in this interlaboratory comparison study. The materials Cambridge1, DSM3, ERM‐AE143, ERM‐AE144, ERM‐AE145, IRMM‐009 and NIST SRM 980 were cross‐calibrated with expanded measurement uncertainties (95% confidence level) of less than 0.030‰ for the δ25/24Mg values and less than 0.037‰ for the δ26/24Mg values. Thus, comparability of all magnesium isotope delta (δ) measurements based on these standards and reference materials is established. Further, ERM‐AE143 anchors all magnesium δ‐scales to absolute isotope ratios and therefore establishes SI traceability, here traceability to the SI base unit mole. This applies especially to the DSM3 scale, which is proposed to be maintained. With ERM‐AE144 and ERM‐AE145, which are product and educt of a sublimation–condensation process, for the first time a set of isotope reference materials is available with a published value for the apparent triple isotope fractionation exponent θapp, the fractionation relationship ln α(25/24Mg)/ln α(26/24Mg). 相似文献
129.
Michael E. Böttcher Herta S. Effenberger Peer-Lennart Gehlken Georg H. Grathoff Burkhard C. Schmidt Patrizia Geprägs Rainer Bahlo Olaf Dellwig Thomas Leipe Vera Winde André Deutschmann Alexander Stark David Gallego-Torres Francisca Martinez-Ruiz 《Chemie der Erde / Geochemistry》2012,72(1):85-89
Following a tentative evidence for the occurrence of low-temperature barium manganese(II) carbonates in brackish sediments of the Baltic Sea, a stoichiometric double carbonate, BaMn[CO3]2, was synthesized from aqueous solutions at ambient temperature for the first time. Here we report the results of a multi-method approach, including scanning electron microscopy (SEM–EDX) investigations, the chemical composition, and, in particular, the diagnostic powder X-ray diffraction pattern, as well as diagnostic parts of the FT infrared absorption and Raman spectra for future identification of this new carbonate in low-temperature environments, like brackish sediments. 相似文献
130.