Emulating exhalative chemistry: synthesis and structural characterization of ilinskite,Na[Cu5O2](SeO3)2Cl3, and its K-analogue     

Vadim M. Kovrugin  Oleg I. Siidra  Marie Colmont  Olivier Mentré  Sergey V. Krivovichev 《Mineralogy and Petrology》2015,109(4):421-430

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Permian granites in the Pyrenees: the Aya pluton (Basque Country)     

Yoann Denèle  Jean‐Louis Paquette  Philippe Olivier  Pierre Barbey 《地学学报》2012,24(2):105-113

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Sulfur Mass Fractions in Thirty-Seven Geological Reference Materials by Titration,XRF and Elemental Analyser     

Olivier Alard  Ananuer Halimulati  Lauren Gorojovsky  Peter Wieland 《Geostandards and Geoanalytical Research》2023,47(2):437-456

Although sulfur is a relatively abundant element, measurement results with small uncertainties remain challenging to achieve, especially at S mass fractions below 100 μg g^-1. We report > 1700 measurement results of S for thirty-seven geological reference materials including igneous, metamorphic and sedimentary rocks, and one soil. Measurement results were obtained in two laboratories (Macquarie GeoAnalytical and Géosciences Montpellier) over a long period of time ≈ 25 years (1997–2022), using several measurement procedures: X-ray fluorescence, high temperature iodo titration and elemental analysers equipped with thermal conductivity and/or infra-red detectors. Sulfur mass fractions for these diverse geological reference materials range between 5.5 and 11,395 μg g^-1. While the comprehensive data set reported here should contribute significantly to a better characterisation of the S mass fractions of widely used geological reference materials, computed uncertainties, data distribution and comparison to published values still indicate heterogeneous distribution of S carrier(s) and analytical bias.  相似文献   

A Novel Technique for Measuring the Solar Radius from Eclipse Light Curves – Results for 2010, 2012, 2013, and 2015     

Philippe Lamy  Jean-Yves Prado  Olivier Floyd  Patrick Rocher  Guillaume Faury  Serge Koutchmy 《Solar physics》2015,290(10):2617-2648

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Fission track and fault kinematics analyses for new insight into the Late Cenozoic tectonic regime changes in West-Central Sulawesi (Indonesia)   总被引：1，自引：0，他引：1  

Olivier Bellier  Michel Sbrier  Diane Seward  Thierry Beaudouin  Michel Villeneuve  Eka Putranto 《Tectonophysics》2006,413(3-4):201-220

A 3-D density model for the Cretan and Libyan Seas and Crete was developed by gravity modelling constrained by five 2-D seismic lines. Velocity values of these cross-sections were used to obtain the initial densities using the Nafe–Drake and Birch empirical functions for the sediments, the crust and the upper mantle. The crust outside the Cretan Arc is 18 to 24 km thick, including 10 to 14 km thick sediments. The crust below central Crete at its thickest section, has values between 32 and 34 km, consisting of continental crust of the Aegean microplate, which is thickened by the subducted oceanic plate below the Cretan Arc. The oceanic lithosphere is decoupled from the continental along a NW–SE striking front between eastern Crete and the Island of Kythera south of Peloponnese. It plunges steeply below the southern Aegean Sea and is probably associated with the present volcanic activity of the southern Aegean Sea in agreement with published seismological observations of intermediate seismicity. Low density and velocity upper mantle below the Cretan Sea with ρ  3.25 × 10³ kg/m³ and V_p velocity of compressional waves around 7.7 km/s, which are also in agreement with observed high heat flow density values, point out at the mobilization of the upper mantle material here. Outside the Hellenic Arc the upper mantle density and velocity are ρ ≥ 3.32 × 10³ kg/m³ and V_p = 8.0 km/s, respectively. The crust below the Cretan Sea is thin continental of 15 to 20 km thickness, including 3 to 4 km of sediments. Thick accumulations of sediments, located to the SSW and SSE of Crete, are separated by a block of continental crust extended for more than 100 km south of Central Crete. These deep sedimentary basins are located on the oceanic crust backstopped by the continental crust of the Aegean microplate. The stretched continental margin of Africa, north of Cyrenaica, and the abruptly terminated continental Aegean microplate south of Crete are separated by oceanic lithosphere of only 60 to 80 km width at their closest proximity. To the east and west, the areas are floored by oceanic lithosphere, which rapidly widens towards the Herodotus Abyssal plain and the deep Ionian Basin of the central Mediterranean Sea. Crustal shortening between the continental margins of the Aegean microplate and Cyrenaica of North Africa influence the deformation of the sediments of the Mediterranean Ridge that has been divided in an internal and external zone. The continental margin of Cyrenaica extends for more than 80 km to the north of the African coast in form of a huge ramp, while that of the Aegean microplate is abruptly truncated by very steep fractures towards the Mediterranean Ridge. Changes in the deformation style of the sediments express differences of the tectonic processes that control them. That is, subduction to the northeast and crustal subsidence to the south of Crete. Strike-slip movement between Crete and Libya is required by seismological observations.  相似文献   

Time-dependent response of a zonally averaged ocean–atmosphere–sea ice model to Milankovitch forcing     

Andrés Antico  Olivier Marchal  Lawrence A. Mysak 《Climate Dynamics》2010,34(6):763-779

An ocean–atmosphere–sea ice model is developed to explore the time-dependent response of climate to Milankovitch forcing for the time interval 5–3 Myr BP. The ocean component is a zonally averaged model of the circulation in five basins (Arctic, Atlantic, Indian, Pacific, and Southern Oceans). The atmospheric component is a one-dimensional (latitudinal) energy balance model, and the sea-ice component is a thermodynamic model. Two numerical experiments are conducted. The first experiment does not include sea ice and the Arctic Ocean; the second experiment does. Results from the two experiments are used to investigate (1) the response of annual mean surface air and ocean temperatures to Milankovitch forcing, and (2) the role of sea ice in this response. In both experiments, the response of air temperature is dominated by obliquity cycles at most latitudes. On the other hand, the response of ocean temperature varies with latitude and depth. Deep water formed between 45°N and 65°N in the Atlantic Ocean mainly responds to precession. In contrast, deep water formed south of 60°S responds to obliquity when sea ice is not included. Sea ice acts as a time-integrator of summer insolation changes such that annual mean sea-ice conditions mainly respond to obliquity. Thus, in the presence of sea ice, air temperature changes over the sea ice are amplified, and temperature changes in deep water of southern origin are suppressed since water below sea ice is kept near the freezing point.  相似文献   

Along-strike variations of P–T conditions in accretionary wedges and syn-orogenic extension,the HP–LT Phyllite–Quartzite Nappe in Crete and the Peloponnese     

Laurent Jolivet  Fabien Trotet  Patrick Monié  Olivier Vidal  Bruno Goffé  Loïc Labrousse  Philippe Agard  Bad'r Ghorbal 《Tectonophysics》2010,480(1-4):133-148

Syn-orogenic detachments in accretionary wedges make the exhumation of high-pressure and low-temperature metamorphic rocks possible with little erosion. The velocity of exhumation within the subduction channel or the accretionary complex, and thus the shape of P–T paths, depend upon the kinematic boundary conditions. A component of slab retreat tends to open the channel and facilitates the exhumation. We document the effect of slab retreat on the shape of P–T paths using the example of the Phyllite–Quartzite Nappe that has been exhumed below the Cretan syn-orogenic detachment during the Miocene in Crete and the Peloponnese. Data show a clear tendency toward colder conditions at peak pressure and during exhumation where the intensity of slab retreat is larger. This spatial evolution of P–T gradient is accompanied with an evolution from a partly coaxial regime below the Peloponnese section of the detachment toward a clearly non-coaxial regime in Crete.  相似文献   

Bioturbation, short-lived radioisotopes, and the tracer-dependence of biodiffusion coefficients     

Pascal Lecroart  Olivier Maire  Sabine Schmidt  Pierre Anschutz 《Geochimica et cosmochimica acta》2010,74(21):6049-6063

Bioturbation refers to the mixing of sediment particles resulting from benthic faunal activity. It is the dominant particle mixing process in most marine sediments and exerts an important control on diagenetic processes. In models, bioturbation is usually treated as a diffusive process where the biodiffusion coefficient (D_b) characterizes the biological mixing intensity. Biodiffusion coefficients are classically computed by fitting a diffusive model to vertical profiles of particle-bound radioisotopes. One peculiar observation is tracer-dependence: D_b values from short-lived tracers tend to be larger than those obtained from long-lived tracers from the same site. Recent theoretical work, based on random walk theory and Lattice Automaton Bioturbation Simulations (LABS), has suggested that this tracer-dependence is simply a model artifact and has concluded that the biodiffusion model is not applicable to the short observational time scales associated with short-lived radioisotopes. Here we have compiled a global dataset of D_b values obtained from different radiotracers to assess tracer-dependence from a data perspective. Tracer-dependence is significant in low-mixing environments like slope and deep-sea sediments, but is not present in intensely mixed coastal areas. Tracer-dependence is absent when the number of mixing events is larger than 20, or the potential length scale is greater than 0.5 cm. Roughly this comes down to tracer-derived D_b values greater than 2 cm² yr⁻¹. This condition is met for 68%, 50%, and 8% of published D_b values obtained from coastal, continental slope, and abyssal environments, respectively. These results show that short-lived radioisotopes are suitable to quantify biodiffusion mixing in sedimentary environments featuring intense bioturbation.  相似文献   

A search for ethane on Pluto and Triton     

Francesca E. DeMeo  Christophe Dumas  Silvia Protopapa  Thomas R. Geballe  Frédéric Merlin 《Icarus》2010,208(1):412-424

We present here a search for solid ethane, C₂H₆, on the surfaces of Pluto and Triton, based on near-infrared spectral observations in the H and K bands (1.4-2.45 μm) using the Very Large Telescope (VLT) and the United Kingdom Infrared Telescope (UKIRT). We model each surface using a radiative transfer model based on Hapke theory (Hapke, B. [1993]. Theory of Reflectance and Emittance Spectroscopy. Cambridge University Press, Cambridge, UK) with three basic models: without ethane, with pure ethane, and with ethane diluted in nitrogen. On Pluto we detect weak features near 2.27, 2.405, 2.457, and 2.461 μm that match the strongest features of pure ethane. An additional feature seen at 2.317 μm is shifted to longer wavelengths than ethane by at least 0.002 μm. The strength of the features seen in the models suggests that pure ethane is limited to no more than a few percent of the surface of Pluto. On Triton, features in the H band could potentially be explained by ethane diluted in N₂, however, the lack of corresponding features in the K band makes this unlikely (also noted by Quirico et al. (Quirico, E., Doute, S., Schmitt, B., de Bergh, C., Cruikshank, D.P., Owen, T.C., Geballe, T.R., Roush, T.L. [1999]. Icarus 139, 159-178)). While Cruikshank et al. (Cruikshank, D.P., Mason, R.E., Dalle Ore, C.M., Bernstein, M.P., Quirico, E., Mastrapa, R.M., Emery, J.P., Owen, T.C. [2006]. Bull. Am. Astron. Soc. 38, 518) find that the 2.406-μm feature on Triton could not be completely due to ¹³CO, our models show that it could not be accounted for entirely by ethane either. The multiple origin of this feature complicates constraints on the contribution of ethane for both bodies.  相似文献   

Boulders and ponds on the Asteroid 433 Eros     

Andrew J. Dombard  Olivier S. Barnouin  Louise M. Prockter  Peter C. Thomas 《Icarus》2010,210(2):713-721

There are ∼300 features on the Asteroid 433 Eros that morphologically resemble ponds (flat-floored and sharply embaying the bounding depression in which they sit). Because boulders on Eros are apparently eroding in place and because ponds with associated boulders tend to be larger than ponds without blocks, we propose that ponds form from thermally disaggregated and seismically flattened boulder material, under the assumption that repeated day/night cycling causes material fatigue that leads to erosion of the boulders. Results from a simple boulder emplacement/thermal erosion model with boulders emplaced in a few discrete events (i.e., large impacts) match well the observed size distribution. Under this scenario, the subtle color differences of ponds (somewhat bluer than the rest of the surface) might be due to some combination of less space-weathered material and density stratification of silicate-rich chondrules and more metal-rich matrix from a disaggregated boulder. Volume estimates of ponds derived from NEAR Laser Rangefinder profiles are consistent with what can be supplied by boulders. Ponds are also observed to be concentrated in regions of low slope and high elevation, which suggests the presence of a less mobile regolith and thus a contrast in the resistance to seismic shaking between the pond material and the material that makes up the bounding depression. Future tests include shake-table experiments and temperature cycling (fatigue) of ordinary chondrites to test the thermal erosion mechanism.  相似文献