Geochemical characteristics of lavas from Broken Ridge, the Naturaliste Plateau and southernmost Kerguelen Plateau: Cretaceous plateau volcanism in the southeast Indian Ocean   总被引：3，自引：0，他引：3  

J. J. Mahoney  W. B. Jones  F. A. Frey  V. J. M. Salters  D. G. Pyle  H. L. Davies 《Chemical Geology》1995,120(3-4):315-345

Lavas from several major bathymetric highs in the eastern Indian Ocean that are likely to have formed as Early to Middle Cretaceous manifestations of the Kerguelen hotspot are predominantly tholeiitic; so too are glass shards from Eocene to Paleocene volcanic ash layers on Broken Ridge, which are believed to have come from eruptions on the Ninetyeast Ridge. The early dominance of tholeiitic compositions contrasts with the more recent intraplate, alkalic volcanism of the Kerguelen Archipelago. Isotopic and incompatible-element ratios of the plateau lavas are distinct from those of Indian mid-ocean ridge basalts; their Nd, Sr, ²⁰⁷Pb/²⁰⁴Pb and isotopic ratios overlap with but cover a much wider range than measured for more recent oceanic products of the Kerguelen hotspot (including the Ninetyeast Ridge) or, indeed, oceanic lavas from any other hotspot in the world. Samples from the Naturaliste Plateau and ODP Site 738 on the southern tip of the Kerguelen Plateau are particularly noteworthy, with ε_Nd(T) = − 13 to −7, (⁸⁷Sr/⁸⁶Sr)_T=0.7090 to 0.7130 and high ²⁰⁷Pb/²⁰⁴Pb relative to ²⁰⁶Pb/²⁰⁴Pb. In addition, the low-ε_Nd(T) Naturaliste Plateau samples are elevated in SiO₂ (> 54 wt%). In contrast to “DUPAL” oceanic islands such as the Kerguelen Archipelago, Pitcairn and Tristan da Cunha, the plateau lavas with extreme isotopic characteristics also have relative depletions in Nb and Ta (e.g., Th/Ta, La Nb > primitive mantle values); the lowest ε_Nd(T) and highest Th/Ta and La Nb values occur at sites located closest to rifted continental margins. Accepting a Kerguelen plume origin for the plateau lavas, these characteristics probably reflect the shallow-level incorporation of continental lithosphere in either the head of the early Kerguelen plume or in plume-derived magmas, and suggest that the influence of such material diminished after the period of plateau construction. Contamination of asthenosphere with the type of material affecting Naturaliste Plateau and Site 738 magmatism appears unlikely to be the cause of low-²⁰⁶Pb/⁰⁴Pb Indian mid-ocean ridge basalts. Finally, because isotopic data for the plateaus do not cluster or form converging arrays in isotope-ratio plots, they provide no evidence for either a quickly evolving, positive ε_Nd, relatively high-²⁰⁶Pb/²⁰⁴Pb plume composition, or a plume source dominated by mantle with ε_Nd of −3 to 0.  相似文献   

Origins of the mafic and ultramafic rocks in the Ronda peridotite     

C.J. Suen  F.A. Frey 《Earth and Planetary Science Letters》1987,85(1-3)

The Ronda peridotite massif in southern Spain originated from the upper mantle, evidently as a rapidly rising diapir. Major and trace element abundance trends of the peridotites reflect their origin as residues from partial melting of garnet lherzolite. About 5% of the massif consists of mafic rocks, mainly pyroxenites and gabbros. They occur as concordant layers amidst the peridotites, and these layers do not cross-cut each other. However, major and trace element data show that the mafic layers do not have the geochemical characteristics of primary melts. We conclude that crystal/liquid fractionation occurred at high pressures ( > 19 kbar) as melts migrated through magma conduits towards the cooler exterior portion of the diapir. This process generated a sequence of “cumulates” (mainly clinopyroxene + orthopyroxene + spinel and clinopyroxene + garnet) along the walls of the conduits which are now represented by the mafic layers.  相似文献   

Geochemical evolution of Kohala Volcano,Hawaii     

Marvin A. Lanphere  Frederick A. Frey 《Contributions to Mineralogy and Petrology》1987,95(1):100-113

Kohala Volcano, the oldest of five shield volcanoes comprising the island of Hawaii, consists of a basalt shield dominated by tholeiitic basalt, Pololu Volcanics, overlain by alkalic lavas, Hawi Volcanics. In the upper Pololu Volcanics the lavas become more enriched in incompatible elements, and there is a transition from tholeiitic to alkalic basalt. In contrast, the Hawi volcanics consist of hawaiites, mugearites, and trachytes. ⁸⁷Sr/⁸⁶Sr ratios of 14 Pololu basalts and 5 Hawi lavas range from 0.70366 to 0.70392 and 0.70350 to 0.70355, respectively. This small but distinct difference in Sr isotopic composition of different lava types, especially the lower ⁸⁷Sr/⁸⁶Sr in the younger lavas with higher Rb/Sr, has been found at other Hawaiian volcanoes. Our data do not confirm previous data indicating Sr isotopic homogeneity among lavas from Kohala Volcano. Also some abundance trends, such as MgO-P₂O₅, are not consistent with a simple genetic relationship between Pololu and Hawi lavas. We conclude that all Kohala lavas were not produced by equilibrium partial melting of a compositionally homogeneous source.  相似文献   

Petrology and geochemistry of basalts from the American-Antarctic Ridge,Southern Ocean: implications for the westward influence of the Bouvet mantle plume     

Anton P. le Roex  Henry J. B. Dick  Arch M. Reid  Fred A. Frey  Anthony J. Erlank  Stan R. Hart 《Contributions to Mineralogy and Petrology》1985,90(4):367-380

Ridge segments and fracture zones from the American-Antarctic Ridge have been systematically dredge sampled from 4° W to 18° W. Petrographic studies of the dredged basalts show that the dominant basalt variety is olivine-plagioclase basalt, although olivine-plagioclase-clinopyroxene basalt is relatively common at some localities. Selected samples have been analysed for major and trace elements, rare earth elements and Sr and Nd isotopes. These data show that the majority of samples are slightly evolved (Mg#=69-35) N-type MORB, although a small group of samples from a number of localities have enriched geochemical characteristics (T- and P-type MORB).These different types of MORB are readily distinguished in terms of their incompatible trace element and isotopic characteristics: N-type MORB have high Zr/Nb (17–78), Y/Nb (4.6–23) and ¹⁴³Nd/¹⁴⁴Nd (0.51303–0.51308) ratios, low Zr/Y (2.2–4.2) and ⁸⁷Sr/⁸⁶Sr (0.70263–0.70295) ratios and have (La/Sm)_N<1.0; T-type MORB have lower than chondritic Zr/Nb ratios (8.8–15.5), relatively low Y/Nb (1.9–4.3) and ¹⁴³Nd/¹⁴⁴Nd (0.51296–0.51288) ratios and relatively high Zr/Y (3.1–4.7), ⁸⁷Sr/⁸⁶Sr (0.70307–0.70334) and (La/Sm)_N (1.1–1.5) ratios; the single sample of P-type MORB has low Zr/Nb (6.3), Y/Nb (0.9) and ¹⁴³Nd/¹⁴⁴Nd (0.51287) ratios and high Zr/Y (7.1), ⁸⁷Sr/⁸⁶Sr (0.70351) and (La/Sm)_N (2.4) ratios. The geochemical characteristics of this sample are essentially identical to those of the Bouvet Island lavas.Geochemically enriched MORB are less abundant on the American-Antarctic Ridge than on the Southwest Indian Ridge but their geochemical characteristics are identical. The compositions of T- and P-type MORB are consistent with a regional mixing model involving normal depleted mantle and Bouvet plume type magma. On a local scale the composition of T-type MORB is consistent with derivation from depleted mantle which contains 4% veins of P-type melt.We propose a model for the evolution of the American-Antarctic Ridge lavas in which N-type MORB is derived from mantle with negligible to low vein/mantle ratios, T-type MORB is derived from domains with moderate and variable vein/mantle ratios and P-type MORB from regions with very high vein/mantle ratios where vein material comprises the major portion of the melt. The sparse occurrence of enriched lavas and by implication enriched mantle beneath the American-Antarctic Ridge, some distance (500–1,200 km) from the Bouvet plume location, is interpreted to be the result of lateral dispersion of enriched mantle domains by asthenospheric flow away from the Bouvet mantle plume towards the American-Antarctic Ridge.  相似文献   

The Ronda high temperature peridotite: Geochemistry and petrogenesis   总被引：2，自引：0，他引：2  

Frederick A Frey  C John Suen  Harlan W Stockman 《Geochimica et cosmochimica acta》1985,49(11):2469-2491

The Ronda peridotite in southern Spain is a large (~300 km²) exposure of upper mantle which provides direct information about mantle processes on a scale much larger than that provided by mantle xenoliths in basalt. Ronda peridotites range from harzburgite to lherzolite, and vary considerably in major element content, e.g., Al₂O₃ from 0.9 to 4.8%, and trace element abundances, e.g., Sr, Zr and La abundances vary by factors of 20 to 40. These compositional variations are systematic and correlate with (pyroxene + garnet)/olivine ratios and olivine compositions. The data are consistent with formation of residual peridotites by variable degrees of melting (~0 to 30%) of a compositionally homogeneous peridotite. None of the peridotites have geochemical characteristics of residues formed by extensive (?5%) fractional melting and the data can be explained by equilibrium (batch) melting, possibly with incomplete melt segregation in some samples. Based on compositional differences between Ronda peridotites, the segregated melts were picritic (12–22% MgO) with relative rare earth element abundances similar to mid-ocean ridge basalt (MORB). Prior to the melting event the Ronda peridotite body was a suitable source for MORB. The compositional characteristics of Ronda peridotites are consistent with diapiric rise of a fertile mantle peridotite with relatively small degrees of melting near the diapir-wall rock interface yielding residues of garnet iherzolite, and larger degrees of melting in the diapir interior yielding residues of garnet-free peridotite. Subsequently these residual rocks were recrystallized at sub-solidus conditions (Obata, 1980), and emplaced in the crust by thrusting (Lundeen, 1978).  相似文献   

Trace element abundances in megacrysts and their host basalts: Constraints on partition coefficients and megacryst genesis   总被引：1，自引：0，他引：1  

Anthony J. Irving  Fred A. Frey 《Geochimica et cosmochimica acta》1984,48(6):1201-1221

In an effort to obtain information about mineral/melt trace element partitioning during the high pressure petrogenesis of basic rocks, we determined rare earth and other trace element abundances in megacrysts of clinopyroxene, orthopyroxene, amphibole, mica, anorthoclase, apatite and zircon, and in their host basalts. In general, the ranges of mineral/melt partition coefficients established from experimental partitioning studies and phenocryst/matrix measurements overlap with the ranges of megacryst/host abundance ratios. Our data for Hf, Sc, Ta and Th partitioning represent some of the only estimates available. Consideration of phase equilibria, major element partitioning and isotopic ratios indicate that most of the pyroxene and amphibole megacrysts may have been in equilibrium with their host magmas at high pressures (mostly 10–25 kb). In contrast, it is unlikely that mica, anorthoclase, apatite and zircon megacrysts formed in equilibrium with their host basalts; instead, we conclude that they were precipitated from more evolved magmas and have been mixed into their present host magmas. Consequently, the trace element abundance ratios for megacryst/host should not be interpreted as partition coefficients, but only as guides for understanding trace element partitioning during high pressure petrogenesis. With this caveat, we conclude that the megacryst/ host trace element abundance data indicate that mineral/melt partition coefficients in basaltic systems during high pressure fractionation are not drastically different from partition coefficients valid for low pressure fractionation.  相似文献   

Geochemistry of diverse basalt types from Loihi Seamount,Hawaii: petrogenetic implications     

Frederick A. Frey  David A. Clague 《Earth and Planetary Science Letters》1983

The wide variety of basalt types, tholeiitic to basanite, dredged from Loihi Seamount have minor and trace element abundances that are characteristic of subaerial Hawaiian basalts, thereby confirming that Loihi Seamount is a manifestation of the Hawaiian “hot spot”. Within the Loihi sample suite there are well-defined positive correlations among abundances of highly incompatible elements (P, K, Rb, Ba, Nb, light REE and Ta) and moderately incompatible elements (Sr, Ti, Zr and Hf) and between MgO, Ni and Cr. However, within the Loihi suite abundance ratios of geochemically similar elements (Zr/Hf, Nb/Ta and La/Ce) vary by factors of 1.2–1.5 and abundance ratios of highly incompatible elements such as P/Ce, P/Th, K/Rb, Ba/Th and La/Nb vary by factors of 1.2–2.5. These abundance ratios are not readily changed by different degrees of fractionation and melting. Therefore, we conclude that these samples are not genetically related by different degrees of melting of a compositionally homogeneous source.On the basis of K/P, K/Ti, P/Ce, Zr/Nb, Th/P and La/Sm abundance ratios, the twelve samples studied in detail can be divided into six geochemical groups. Samples within each group are similar in ⁸⁷Sr/⁸⁶Sr [1], and intra-group compositional variations may reflect low-pressure fractionation and different degrees of melting. In addition, crossing chondrite-normalized REE patterns within the alkalic basalt groups reflect equilibration of the magmas with garnet. In ratio-ratio plots involving abundance ratios of highly incompatible elements, e.g., La/P, Nb/P, K/P, Rb/P, Ba/P and Th/P, the geochemical groups define linear arrays suggestive of mixing. However, these data combined with the isotopic data are not consistent with two-component mixing.  相似文献   

Modelling phase–assemblage diagrams for magnesian metapelites in the system K2O–FeO–MgO–Al2O3–SiO2–H2O: geodynamic consequences for the Monte Rosa nappe, Western Alps     

R. Le Bayon  C. de Capitani  M. Frey 《Contributions to Mineralogy and Petrology》2006,151(4):395-412

Magnesian metamorphic rocks with metapelitic mineral assemblage and composition are of great interest in metamorphic petrology for their ability to constrain P–T conditions in terranes where metamorphism is not easily visible. Phase–assemblage diagrams for natural and model magnesian metapelites in the system KFMASH are presented to document how phase relationships respond to water activity, bulk composition, pressure and temperature. The phase assemblages displayed on these phase diagrams are consistent with natural mineral assemblages occurring in magnesian metapelites. It is shown that the equilibrium assemblages at high pressure conditions are very sensitive to a(H₂O). Specifically, the appearance of the characteristic HP assemblage chloritoid–talc–phengite–quartz (with excess H₂O) in the magnesian metapelites of the Monte Rosa nappe (Western Alps) is due to the reduction of a(H₂O). Furthermore, the mineral assemblages are determined by the whole-rock FeO/(FeO+MgO) ratio and effective Al content X _A as well as P and T. The predicted mineral associations for the low- and high-X _A model bulk compositions of magnesian metapelites at high pressure are not dependent on the X _A variations as they show a similar sequence of mineral assemblages. Above 20 kbar, the prograde sequence of assemblages associated with phengite (with excess SiO₂ and H₂O) for low- and high-X _A bulk compositions of magnesian metapelites is: carpholite–chlorite → chlorite–chloritoid → chloritoid–talc → chloritoid–talc–kyanite → talc–garnet–kyanite → garnet–kyanite ± biotite. At low to medium P–T conditions, a low-X _A stabilises the phengite-bearing assemblages associated with chlorite, chlorite + K-feldspar and chlorite + biotite while a high-X _A results in the chlorite–phengite bearing assemblages associated with pyrophyllite, andalusite, kyanite and carpholite. A high-X _A magnesian metapelite with nearly iron-free content stabilises the talc–kyanite–phengite assemblage at moderate to high P–T conditions. Taking into account the effective bulk composition and a(H₂O) involved in the metamorphic history, the phase–assemblage diagrams presented here may be applied to all magnesian metapelites that have compositions within the system KFMASH and therefore may contribute to gaining insights into the metamorphic evolution of terranes. As an example, the magnesian metapelites of the Monte Rosa nappe have been investigated, and an exhumation path with P–T conditions for the western roof of the Monte Rosa nappe has been derived for the first time. The exhumation shows first a near-isothermal decompression from the Alpine eclogite peak conditions around 24 kbar and 505°C down to approximately 8 kbar and 475°C followed by a second decompression with concomitant cooling.M. Frey: deceased  相似文献   

Optimal design of supplemental viscous dampers for linear framed structures     

Oren Lavan  Robert Levy 《地震工程与结构动力学》2006,35(3):337-356

A methodology for the optimal design of supplemental viscous dampers for framed structures is presented. It addresses the problem of minimizing the added damping subject to a constraint on the maximal interstorey angular drift for an ensemble of realistic ground motion records while assuming linear behaviour of the damped structure. The solution is achieved by actually solving an equivalent optimization problem of minimizing the added damping subject to a constraint on a maximal weighted integral on the squared angular drift. The computational effort is appreciably reduced by first using one ‘active’ ground motion record. If the resulting optimal design fails to satisfy the constraints for other ground motions from the original ensemble, additional ground motions (loading conditions) are added one by one to the ‘active’ set until the optimum is reached. An efficient selecting process which is presented herein will usually require one or two records to attain an optimum design. Examples of optimal designs of supplemental dampers are presented for a 2‐storey shear frame and a 10‐storey industrial frame. The 2‐storey shear frame is required to withstand one given ground motion whereas the 10‐storey frame is required to withstand an ensemble of twenty ground motions. The resulting viscously damped structures have envelope values of interstorey drifts equal or less than the target drifts. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Past,present and future of saline lakes: research for global sustainable development     

郑绵平 《中国海洋湖沼学报》2015,33(6):1349-1353

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