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51.
The major and trace elements and Sr–Nd–Pb isotopes of the host rocks and the mafic microgranular enclaves (MME) gathered from the Dölek and Sariçiçek plutons, Eastern Turkey, were studied to understand the underlying petrogenesis and geodynamic setting. The plutons were emplaced at  43 Ma at shallow depths ( 5 to 9 km) as estimated from Al-in hornblende geobarometry. The host rocks consist of a variety of rock types ranging from diorite to granite (SiO2 = 56.98–72.67 wt.%; Mg# = 36.8–50.0) populated by MMEs of gabbroic diorite to monzodiorite in composition (SiO2 = 53.21–60.94 wt.%; Mg# = 44.4–53.5). All the rocks show a high-K calc-alkaline differentiation trend. Chondrite-normalized REE patterns are moderately fractionated and relatively flat [(La/Yb)N = 5.11 to 8.51]. They display small negative Eu anomalies (Eu/Eu = 0.62 to 0.88), with enrichment of LILE and depletion of HFSE. Initial Nd–Sr isotopic compositions for the host rocks are εNd(43 Ma) = − 0.6 to 0.8 and mostly ISr = 0.70482–0.70548. The Nd model ages (TDM) vary from 0.84 to 0.99 Ga. The Pb isotopic ratios are (206Pb/204Pb) = 18.60–18.65, (207Pb/204Pb) = 15.61–15.66 and (208Pb/204Pb) = 38.69–38.85. Compared with the host rocks, the MMEs are relatively homogeneous in isotopic composition, with ISr ranging from 0.70485 to 0.70517, εNd(43 Ma) − 0.1 to 0.8 and with Pb isotopic ratios of (206Pb/204Pb) = 18.58–18.64, (207Pb/204Pb) = 15.60–15.66 and (208Pb/204Pb) = 38.64–38.77. The MMEs have TDM ranging from 0.86 to 1.36 Ga. The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data, in conjunction with the geodynamic evidence, suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, probably triggered by the upwelling of the asthenophere, and interacted with a crustal melt that originated from the dehydration melting of the mafic lower crust at deep crustal levels. Modeling based on the Sr–Nd isotope data indicates that  77–83% of the subcontinental lithospheric mantle involved in the genesis. Consequently, the interaction process played an important role in the genesis of the hybrid granitoid bodies, which subsequently underwent a fractional crystallization process along with minor amounts of crustal assimilation, en route to the upper crustal levels generating a wide variety of rock types ranging from diorite to granite in an extensional regime.  相似文献   
52.
Karstic limestone formations in the Mediterranean basin are potential water resources that can meet a significant portion of groundwater demand. Therefore, it is necessary to thoroughly study the hydrogeology and hydrogeochemistry of karstic mountain regions. This paper presents a detailed hydrogeological and hydrogeochemical characterization of the Nif Mountain karstic aquifer system in western Turkey, an important recharge source for the densely populated surrounding area. Based on the geological and hydrogeological studies, four major aquifers were identified in the study area including the allochthonous limestone in Bornova flysch, conglomerate-sandstone and clayey-limestone in Neogene series, and the Quaternary alluvium. Physicochemical characteristics of groundwater were measured in situ, and samples were collected at 59 locations comprised of springs and wells. Samples were analyzed for major ions, isotopic composition, arsenic, boron and heavy metals among other trace elements. It was found that the hydrogeological structure is complex with many springs having a wide range of discharge rates. High-discharge springs originate from allochthonous limestone units, whereas low-discharge springs are formed at the contacts with claystone and limestone units. Using stable isotope analysis data, a δ18O-deuterium relationship was obtained that lies between the Mediterranean meteoric and mean global lines. Tritium analyses showed that low-discharge springs originating from contact zones had longer circulation times compared to the high-discharge karstic springs. Furthermore, hydrogeochemical data revealed that groundwater quality significantly deteriorated as water moved from the mountain to the plains. Heavy metal, arsenic and boron concentrations were generally within drinking-water quality standards with a few exceptions occurring in residential and industrial areas located at the foothills of the mountain. Elevated arsenic concentrations were related to local geologic formations, which are likely to contain oxidized sulfite minerals in claystones. It is concluded that Nif Mountain overall has a significant potential to provide high-quality water with a safe yield of at least 50 million m3/year, which corresponds to about 28% of the mean annual inflow to the Tahtali reservoir, a major water resource for the city of Izmir. An erratum to this article can be found at  相似文献   
53.
There are many influences on precipitation chemistry and its variation. The transport paths of air masses before rainfall provide useful knowledge for evaluating and understanding the results of the analysis of the chemical compositions of precipitation. As a consequence, it is important to determine the variation of the chemical composition of rainwater by back trajectory analysis for estimating the source of the emissions. In this study, the rainwater samples were collected using specially designed collectors between November 1997 and June 1998 in the urban and forest areas of Istanbul. The rainwater samples were analyzed for major ion concentrations and pH. The volume‐weighed mean pH values were 5.8. The rainwater samples were classified to determine the source region of pollutants in rainwater using synoptic maps. In general, the results of the analysis on the chemical concentrations of precipitation during the measurement period showed that most of ions reached Istanbul from the directions of W‐SW, NW‐W, and NE‐N, respectively.  相似文献   
54.
Quaternary Erzincan Volcanics (QEVs) from the Erzincan Basin consist of mega- and pheno-cryst-bearing high-K calc-alkaline dome lavas. Fourteen nearly phenocrystic domes, with a range of basaltic-andesite, andesite, dacite and rhyolite compositions, were emplaced in the North Anatolian Fault Zone. The emplacement ages yielded by the unspiked K–Ar technique range from 102 to 140 ka. The andesitic domes (each less than 3 km in diameter) contain amphibole megacrysts. Amphibole compositions show a linear variation from ferro-edenite, edenite to pargasite from rhyolite to andesite. Pargasitic amphibole megacrysts scattered into the groundmass are very similar in composition to the microlites. All plagioclases are 53 mol%. Oscillation types are An32−50 whose variations range from 10 to 16 mol% An and have 10–150 μm in thickness. Pre-eruptive conditions, calculated from mega- and pheno-cryst composition, using pyroxene and two oxide thermometers and the Al-in-hornblende barometer, ranged from 918 to 837 °C and 6.6 to 4.3 kbar for andesitic magma, 824–755 °C and 4.6–4.2 kbar for dacitic magma to 803–692 °C and 4.3–3.9 kbar for rhyolitic magma, which correspond to a depth of >10 km for storage region of the crust. The fO2 values vary from −14.25 to −15.35 log units which are plotted just below nickel–nickel oxide (NNO) buffers. The systematic decrease in thermobarometric results from andesite to rhyolite is consistent with a single magma reservoir moving upward through the crust followed by fractional crystallization. Textural and compositional relationships of mega- and pheno-crystic phases suggest that magma mixing, fluid input to the reservoir and fractional crystallization processes, with a small amount crustal contamination play key role in evolution of the QEVs.  相似文献   
55.
Combination of flotation and magnetic separation methods is widely used for enrichment of feldspar ores by purifying from dark-colored gangue minerals such as iron and titanium. In this study, the removal of dark-colored minerals from feldspar ore (Aydin Cine region of Turkey) was studied using a dry magnetic separator. The effect of several parameters such as feed particle size, blade angle, and roll speed on the removal efficiency was investigated in detail. In addition, the gangue contents of the magnetic and non-magnetic products were determined by a digital image processing (DIP) method in terms of using color differences between the feldspar sample and gangue minerals. The results obtained from this study clearly indicated that the dry magnetic separation method can be successfully applied in enrichment of feldspar. Meanwhile, the particle size of the sample showed no significant influence on the separation recovery. According to the results obtained from the digital image processing process, the sample with 0.04% cross sectional area of dark-colored minerals can be obtained at roll speed of 100 rpm and 130° of blade angle using the original particle size of 500×106 μm. Additionally, most importantly, these results showed that digital image processing method can be used to determine gangue content (dark-colored minerals) of the magnetic separation products compared to conventional methods as a simple, a reliable, and a repeatable method.  相似文献   
56.
We present new, whole-rock major and trace element chemistry, including rare earth elements (REE), platinum-group elements (PGE), and Re–Os isotope data from the upper mantle peridotites of a Cretaceous Neo-Tethyan ophiolite in the Mu?la area in SW Turkey. We also report extensive mineral chemistry data for these peridotites in order to better constrain their petrogenesis and tectonic environment of formation. The Mu?la peridotites consist mainly of cpx-harzburgite, depleted harzburgite, and dunite. Cpx-harzburgites are characterized by their higher average CaO (2.27 wt.%), Al2O3 (2.07 wt.%), REE (53 ppb), and 187Os/188Os(i) ratios varying between 0.12497 and 0.12858. They contain Al-rich pyroxene with lower Cr content of coexisting spinel (Cr# = 13–22). In contrast, the depleted harzburgites and dunites are characterized by their lower average CaO (0.58 wt.%), Al2O3 (0.42 wt.%), and REE (1.24 ppb) values. Their clinopyroxenes are Al-poor and coexist with high-Cr spinel (Cr# = 33–83). The 187Os/188Os(i) ratios are in the range of 0.12078–0.12588 and are more unradiogenic compared to those of the cpx-harzburgites.Mineral chemistry and whole rock trace and PGE data indicate that formation of the Mu?la peridotites cannot be explained by a single stage melting event; at least two-stages of melting and refertilization processes are needed to explain their geochemical characteristics. Trace element compositions of the cpx-harzburgites can be modeled by up to ~ 10–16% closed-system dynamic melting of a primitive mantle source, whereas those of the depleted harzburgites and dunites can be reproduced by ~ 10–16% open-system melting of an already depleted (~ 16%) mantle. These models indicate that the cpx-harzburgites are the products of first-stage melting and low-degrees of melt–rock interaction that occurred in a mid-ocean ridge (MOR) environment. However, the depleted harzburgites and dunites are the product of second-stage melting and related refertilization which took place in a supra subduction zone (SSZ) environment. The Re–Os isotope systematics of the Mu?la peridotites gives model age clusters of ~ 250 Ma, ~ 400 Ma and ~ 750 Ma that may record major tectonic events associated with the geodynamic evolution of the Neo-Tethyan, Rheic, and Proto-Tethyan oceans, respectively. Furthermore, > 1000 Ma model ages can be interpreted as a result of an ancient melting event before the Proto-Tethys evolution.  相似文献   
57.
We present the whole-rock and the mineral chemical data for upper mantle peridotites from the Harmanc?k region in NW Turkey and discuss their petrogenetic–tectonic origin. These peridotites are part of a Tethyan ophiolite belt occurring along the ?zmir-Ankara-Ercincan suture zone in northern Turkey, and include depleted lherzolites and refractory harzburgites. The Al2O3 contents in orthopyroxene and clinopyroxene from the depleted lherzolite are high, and the Cr-number in the coexisting spinel is low falling within the abyssal field. However, the orthopyroxene and clinopyroxene in the harzburgites have lower Al2O3 contents for a given Cr-number of spinel, and plot within the lower end of the abyssal field. The whole-rock geochemical and the mineral chemistry data imply that the Harmanc?k peridotites formed by different degrees of partial melting (~%10–27) of the mantle. The depleted lherzolite samples have higher MREE and HREE abundances than the harzburgitic peridotites, showing convex-downward patterns. These peridotites represent up to ~16 % melting residue that formed during the initial seafloor spreading stage of the Northern Neotethys. On the other hand, the more refractory harzburgites represent residues after ~4–11 % hydrous partial melting of the previously depleted MOR mantle, which was metasomatized by slab-derived fluids during the early stages of subduction. The Harmanc?k peridotites, hence, represent the fragments of upper mantle rocks that formed during different stages of the tectonic evolution of the Tethyan oceanic lithosphere in Northern Neotethys. We infer that the multi-stage melting history of the Harmanc?k peridotites reflect the geochemically heterogeneous character of the Tethyan oceanic lithosphere currently exposed along the ?zmir-Ankara-Erzincan suture zone.  相似文献   
58.
The Taurides, the southernmost of the three major tectonic domains that constitute present‐day Turkey, were emplaced following consumption of the Tethyan Ocean in Late Mesozoic to mid‐Tertiary times. They are generally assigned an origin at the northern perimeter of Gondwana. To refine palaeogeographic control we have investigated the palaeomagnetism of a range of Jurassic rocks. Forty‐nine samples of Upper Jurassic limestones preserve a dual polarity remanence (D/I=303/−9°, α95=6°) interpreted as a primary magnetization acquired close to the equator and rotated during emplacement of the Taurides. Result from mid‐Jurassic dolerites confirm a low palaeolatitude for the Tauride Platform during Jurassic times at the Afro–Arabian sector of Gondwana. Approximately 4000 km of Tethyan closure subsequently occurred between Late Jurassic and Eocene times. Although related Upper Jurassic limestones and Liassic redbeds preserve a sporadic record of similar remanence, the dominant signature in these latter rocks is an overprint of probable mid‐Miocene age, probably acquired during a single polarity chron and imparted by migration of a fluid front during nappe loading. This is now rotated consistently anticlockwise by c. 30° and conforms to results of previous studies recording bulk Neogene rotation of the Isparta region following Lycian nappe emplacement. The regional distribution of this overprint implies that the Isparta Angle (IA) has been subject to only small additional closure (<10°) since Late Miocene time. A smaller amount (c. 6°) of clockwise rotation within the IA since Early Pliocene times is associated with an ongoing extensional regime and reflects an expanding curvature of the Tauride arc produced by southwestward extrusion of the Anatolian collage as a result of continuing northward motion of Afro–Arabia. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
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