Cation distribution in pentlandites (Fe,Ni)9S8: Dependence on pressure and temperature and kinetics of the cation exchange reaction     

Katsuhiro Tsukimura  Hiromoto Nakazawa  Tadashi Endo  Osamu Fukunaga 《Physics and Chemistry of Minerals》1992,19(4):203-212

This paper describes the distribution of Fe and Ni between the octahedral and tetrahedral sites in pentlandite (Fe,Ni)₉S₈. The dependence of the distribution on pressure and temperature and the activation energy of the cation exchange reaction were determined through annealing experiments. Synthetic crystals were annealed at 433–723 K and pressures up to 4 GPa, and natural crystals were annealed at 423, 448 and 473 K in evacuated silica capillary tubes for various durations. The cation distributions in the synthetic crystals were determined with an X-ray powder method employing the anomalous dispersion effect of CuK. and FeK radiations, while those of natural crystals were calculated from the cell dimensions. The values of U, S and V for the Fe/Ni exchange reaction are –6818 J mol^–1, 20.52 J K^–1 mol^–1, and 6.99 × 10^–6 m³ mol^–1, respectively. The dependence of the Fe/Ni distribution on pressure (Pa) and temperature (Kelvin) was determined as lnK = 2.47+8.20 × 10² T ^–1+8.41 x 10^–7 T ^–1 P, where K = (Fe/Ni)_octahedral /(Fe/Ni)_tetrahedral. The activation energy of the cation exchange reaction was 185 kJ mol^–1.  相似文献   

Determination of the electromagnetic field produced by a magnetic oblique-rotator     

Osamu Kaburaki 《Astrophysics and Space Science》1981,74(2):333-356

The electromagnetic field produced by a magnetic dipole moment, , which is rotating obliquely surrounded by a corotating plasma sphere, is investigated. This corotating-plasma approximation has the same order of accuracy as the force-free one but has somewhat different physical implications. In the former the effect of non-electromagnetic forces such as the inertial force are included, though in somewhat artificial manner, as a departure from the strict MHD condition and this fact seems to guarantee the existence of physical solutions.Analogous to the relativistic force-free equation, a set of two differential equations (the corotation equation) are derived for the scalar functions associated with the electric and magnetic fields. A self-consistent solution of these equations is given and it is shown that this solution has no singularity, in spite of apparent divergence in the formal solution, on the light cylinder. It is concluded from this solution that, even in the extreme case of the largest possible corotation-radius (i.e.b=r _L , wherer _L is the light radius), the existence of a corotating plasma does not alter the field structure drastically from the vacuum case. It is also suggested through this treatment that inclusion of the inertial term in generalized Ohm's law might be essential in considering the centrifugal-wind problem.  相似文献   

Controlled experiment in the ionosphere with a rocket-borne plasma gun     

Nobuki Kawashima  Susumu Sasaki  Osamu Kaneko  Akira Yamori  Ryo Okamura  Shoichi Okamura 《Planetary and Space Science》1978,26(4):367-373

A controlled active experiment was performed by a plasma gun on-board a rocket to study the plasma stream across the magnetic field in space. A mother and daughter system was employed. An 8 kV 0.8 μF (25 J) capacitor bank on the daughter rocket was discharged every 12 s and about 10¹⁶ ion and electron pairs were ejected. A plasma signal was detected on the electron temperature probe. The propagation speed of the plasma stream is estimated to be 10⁶ cm/s, considerably lower than that obtained in the prelaunch test. The amplitude of the plasma signal decays as the inverse square of the mutual distance between the mother and daughter rockets and this decay is much slower than the free streaming. The importance of the geomagnetic field on the plasma propagation in space is discussed.  相似文献   

Subsurface thermal and hydrothermal characterization based on geothermal resources map, drill hole thermal gradients, Curie point depths and hypocenter distribution — Examples of Tohoku district, Japan     

S. Tamanyu  T. Sato  M. Kato   《Journal of Geochemical Exploration》2006,89(1-3):389

Subsurface thermal structure in Tohoku district are characterized by existing data such as geothermal resources maps, drill hole thermal gradients, Curie point depths and hypocenters distribution maps. The collected data are registered in a database system, then, compared in plan view, cross-section and bird's-eye pictures. The comparison indicates that subsurface temperatures extrapolated from drill hole thermal gradients are generally concordant to the Curie point depth, assumed to be 650 °C. Tohoku district is generally divided into 5 type areas; fore arc lowland, fore arc mountain country, Quaternary volcanic terrain, back arc lowland and back arc mountain country. The surface thermal manifestations in Quaternary volcanic terrain are mainly controlled by the magma chambers as heat sources, while, surface thermal features such as hot springs in non-volcanic areas are controlled by degrees of heat flows, and hydrothermal flows in permeable Cenozoic formations and along permeable fault zones.  相似文献   

Geochemistry and Origin of Ananai Stratiform Manganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan     

Koichiro Fujinaga    Tatsuo Nozaki  Takazumi Nishiuchi  Kiyoko Kuwahara  Asuhiro Kato 《Resource Geology》2006,56(4):399-414

Abstract. Major and trace element contents are reported for Permian manganese ore and associated greenstone from the Ananai manganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The manganese deposit occurs between greenstone and red chert, or among red chert beds. Chemical compositions of manganese ore are characterized by enrichments in Mn, Ca, P, Co, Ni, Zn, Sr and Ba, and negative Ce and positive Eu anomalies relative to post-Archean average Australian Shale (PAAS). Geochemical features of the manganese ore are similar to those of modern submarine hydrother-mal manganese deposits from volcanic arc or hotspot setting. In addition, geochemical characteristics of the greenstone closely associated with the Ananai manganese deposit are analogous to those of with-in plate alkaline basalt (WPA). Consequently, the Ananai manganese deposit was most likely formed by hydrothermal activity related to hotspot volcanism in the Panthalassa Ocean during the Middle Permian. This is the first report documenting the terrestrially-exposed manganese deposit that was a submarine precipitate at hotspot.  相似文献   

A Special Issue: Seafloor Processes and Related Mineralization in the Panthalassa: The Phanerozoic Records from the Japanese Accretionary Complexes - Part II     

Yasuhiro Kato  Kosei Komuro 《Resource Geology》2006,56(4):397-398

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Remote sensing parameterization of the processes of energy and water cycle over desertification areas     

Yaoming Ma  Osamu Tsukamoto  Hirohiko Ishikawa 《中国科学D辑(英文版)》2002,45(1):47-53

In order to understand the processes of land surface-atmosphere interaction over desertification area, it is indispensable to utilize of satellite remote sensing. Two scenes of Landsat TM were used to produce a set of maps of surface reflectance, MSAVI, vegetation coverage, surface temperature, net radiation, soil heat flux, sensible heat flux and latent heat flux. Statistical analysis based on these maps revealed some quantitative significant land surface characteristics. Future developments of the method are also discussed.  相似文献   

Effect of Sliding Rate on the Activity of Acoustic Emission During Stable Sliding     

Y. Yabe  N. Kato  K. Yamamoto  T. Hirasawa 《Pure and Applied Geophysics》2003,160(7):1163-1189

--The mechanical and statistical characteristics of acoustic emission (AE) events during stable sliding are investigated through a laboratory experiment using a granite specimen with a pre-cut fault. Numerous AE events are found to be generated on the pre-cut fault, indicating that microscopically unstable fracture occurs during macroscopically stable sliding. The composite focal mechanism solution of AE events is determined from the first motion directions of P-waves. The determined mechanism is consistent with the double-couple one expected for the slip on the pre-cut fault. The source radii of large AE events are estimated to be about 10 mm from the widths of the first P-wave pulses. These indicate that the AE events are generated by shear fracture whose faulting area is a part of the pre-cut fault plane. The occurrence of AE events as a stochastic process approximately obeys the Poisson process, if the effect of mutually dependent events consti tuting clusters is corrected. The observed amplitude-frequency relation of AE events approximately follows a power law for a limited amplitude range. As the macroscopic sliding rate increases, the number of AE events per unit sliding distance decreases. This rate dependence of the AE activity is qualitatively consistent with the observation that the real area of contact between sliding surfaces decreases with an increase in the sliding rate as reported in the literature.  相似文献   

GPS-measured land subsidence in Ojiya City, Niigata Prefecture, Japan   总被引：1，自引：0，他引：1  

Hiroshi P. Sato  Kaoru Abe  Osamu Ootaki 《Engineering Geology》2003,67(3-4):379-390

Land subsidence caused by compression of clay layers in Ojiya City, Japan was measured by global positioning system (GPS) between 1 April 1996 and 31 December 1998.

Three baselines were selected in and around the city, and height difference on a WGS-84 ellipsoid was measured by GPS on each baseline. The ground at the GPS station in the city subsides and rebounds 7 cm every winter and spring, respectively. Measurement accuracy was 9.5 mm standard deviation. Ground water level was observed at a well near the GPS station. Regression analysis between total strain, calculated as ratio of the height difference displacement to the total thickness of the clay layers, and the layers' effective stress change with ground water level change gave good correlation. The slope of regression line 7.0×10⁻¹¹ m²/N was obtained as an average apparent coefficient of volume compressibility of the layers.  相似文献   

Distribution of vertical crustal movement rates in the Tohoku district, Japan, predicted by least-squares collocation     

G. S. El-Fiky  Teruyuki Kato  Yoichiro Fujii 《Journal of Geodesy》1997,71(7):432-442

Least-squares prediction using an empirically deduced local covariance function was performed to investigate the temporal change in the rates of vertical crustal movements in the Tohoku district, Japan. Levelling data covering an area of approximately 450 × 275 km² observed between 1966 and 1995 were used and the results shown in the form of contour maps. Firstly we derived a covariance function of the rates of vertical crustal movement with a Gaussian form function. We used this function to estimate the spatial distribution of the rates of vertical crustal movements. By the present method, a steady tilt of the Tohoku district to the east, toward the Japan Trench and an areal uplift in the southwestern part were well reproduced. Moreover, a significant temporal change in vertical movement rates is clearly seen. Received: 15 July 1996   相似文献