The compressional behaviour and the mechanical properties of talc [Mg3Si4O10(OH)2]: a density functional theory investigation     

Gianfranco Ulian  Sergio Tosoni  Giovanni Valdrè 《Physics and Chemistry of Minerals》2014,41(8):639-650

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Thermodynamic properties of chlorite and berthierine derived from calorimetric measurements     

Philippe Blanc  Hélène Gailhanou  Jacques Rogez  Georges Mikaelian  Hitoshi Kawaji  Fabienne Warmont  Stéphane Gaboreau  Sylvain Grangeon  Jean-Marc Grenèche  Philippe Vieillard  Claire I. Fialips  Eric Giffaut  Eric C. Gaucher  F. Claret 《Physics and Chemistry of Minerals》2014,41(8):603-615

In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al_0.975FeIII_0.182FeII_1.422Mg_0.157Li_0.035Mn_0.002)(Si_1.332Al_0.668)O₅(OH)₄] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si_2.633Al_1.367)(Al_1.116FeIII_0.215Mg_2.952FeII_1.712Mn_0.012Ca_0.011)O₁₀(OH)₈]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature.  相似文献   

Tectono-stratigraphic evolution of an inverted extensional basin: the Cameros Basin (north of Spain)     

Silvia Omodeo Salè  Joan Guimerà  Ramón Mas  José Arribas 《International Journal of Earth Sciences》2014,103(6):1597-1620

The Cameros Basin is a part of the Mesozoic Iberian Rift. It is an extensional basin formed during the late Jurassic and early Cretaceous, in the Mesozoic Iberian Rift context, and it was inverted in the Cenozoic as a result of the Alpine contraction. This work aims to reconstruct the tectono-stratigraphic evolution of the basin during the Mesozoic, using new and revised field, geophysical and subsurface data. The construction of a basin-wide balanced section with partial restorations herein offers new insights into the geometry of the syn-rift deposits. Field data, seismic lines and oil well data were used to identify the main structures of the basin and the basin-forming mechanisms. Mapping and cross-sectional data indicate the marked thickness variation of the depositional sequences across the basin, suggesting that the extension of the depositional area varied during the syn-rift stage and that the depocentres migrated towards the north. From field observation and seismic line interpretation, an onlap of the depositional sequences to the north, over the marine Jurassic substratum, can be deduced. In the last few decades, the structure and geometry of the basin have been strongly debated. The structure and geometry of the basin infill reconstructed herein strongly support the interpretation of the Cameros Basin as an extensional-ramp synclinal basin formed on a blind south-dipping extensional ramp. The gradual hanging-wall displacement to the south shifted the depocentres to the north over time, thus increasing the basin in size northwards, with onlap geometry on the pre-rift substratum. The basin was inverted by means of a main thrust located in a detachment located in the Upper Triassic beds (Keuper), which branched in depth with the Mesozoic extensional fault flat. The reconstruction of the tectono-stratigraphic evolution of the Cameros Basin proposed herein represents a synthesis and an integration of previous studies of the structure and geometry of the basin. This study can be used as the basis for future basin-scale research and for modelling the ancient petroleum system of the basin.  相似文献   

Simulation of spatial and temporal trends in nitrate concentrations at the regional scale in the Upper Dyle basin,Belgium     

E. César  S. Wildemeersch  Ph. Orban  S. Carrière  S. Brouyère  A. Dassargues 《Hydrogeology Journal》2014,22(5):1087-1100

Models are the only tools capable of predicting the evolution of groundwater systems at a regional scale, by taking into account a large amount of information. This study presents the association of a water balance model (WetSpass) with a groundwater flow and solute transport model (SUFT3D, saturated and unsaturated flow and transport in 3D) in order to simulate the present and future groundwater quality in terms of nitrate in the Upper Dyle basin (439 km²) Belgium. The HFEMC (hybrid finite element mixing cell) method implemented in the SUFT3D code is used to model groundwater flow and nitrate transport. Spatially distributed recharge, modelled with WetSpass, is considered for prescribing the recharge to the groundwater flow model. The feasibility of linking the WetSpass model with the finite-elements SUFT3D code is demonstrated. Time evolution and distribution of nitrate concentration are then simulated using the calibrated model. Nitrate inputs are spatially distributed according to land use. The spatial simulations and temporal trends are compared with previously published data on this aquifer and show good results.  相似文献   

Referees for volume 8     

Andrew U. Frank  Eva Grum  Bérengère Vasseur 《Journal of Geographical Systems》2006,8(4):437-437

Acknowledgement

Referees for volume 8  相似文献   

Polychlorinated biphenyls and DDT residues distribution in sediments of Cortiou (Marseille, France)   总被引：1，自引：0，他引：1  

Wafo E  Sarrazin L  Diana C  Schembri T  Lagadec V  Monod JL 《Marine pollution bulletin》2006,52(1):104-107

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Focusing on monofilament nets while overlooking the priorities of artisanal fisheries governance in Senegal     

D Thiao  A Mbaye  M Dème  HD Diadhiou 《African Journal of Marine Science》2017,39(3):339-348

Despite its legal prohibition since 1998, the nylon monofilament net is still widely used in Senegalese artisanal fisheries. To achieve a complete ban on monofilament use, it is necessary to understand the main arguments for its continued use and what alternatives exist. Using a field experiment among local fishers as well as empirical knowledge and a literature review, this article highlights the challenges to the eradication of nylon monofilament. Our study shows that in a context where decision-makers pay too much attention to social, economic and political stakes, the efficiency of nylon monofilament nets confers a major advantage upon which fishers rely, and this counters any regulatory action against this type of gear. Moreover, numerous studies globally have indicated that communication campaigns that focus on the ghost-fishing power of this type of net seem to be inappropriate. We concluded that the issue of continued use of monofilament should be addressed through an integrated fisheries management programme that reduces overcapacity and fosters sustainable fishing practices.  相似文献   

Facies and geometry of tidal channel-fill deposits (Arcachon Lagoon, SW France)     

Hugues Fenies  Jean-Claude Faugres 《Marine Geology》1998,150(1-4):131-148

The Arcachon Lagoon has an important network of tidal channels and well developed tidal flats covered by the marine grass Zostera marina. Based on 66 piston cores taken from the Graveyron tidal channel, and observations on the neighbouring channels, this paper documents the facies and geometry of the channel-fill deposits. In the inner lagoon (studied area) the tidal channels are 80 to 150 m wide and have a meandering morphology with sandy point bars 2 to 5 m thick. The channel-fill does not consist of the classic inclined heterolithic bedding typical of many channel-fills (Reineck, 1958), but of cross-stratified sandy deposits characterized by the absence of slack-water clay-drapes. These unusual facies characteristics are due to the low turbidity of the lagoonal waters which is caused by the lack of significant river inflow and the dense coverage of Zostera marina on the tidal flats. The overall geometry of the channel-fill deposits is characterized by a narrow sand-ribbon shape, a few kilometres long, 80 to 150 m wide and 1 to 5 m thick. This sand ribbon is made of elliptical sand bodies, deposited as point bars, that coalesce longitudinally along the channel axis. This narrow shape is due to the fact that the lateral migration of the channel is virtually nil (reduced to a few metres). In spite of their characteristic meandering morphology, these channels do not deposit extensive tabular sand sheets of amalgamated point bars like the tidal creeks on the North Sea tidal flats. Two factors are thought to control this lack of channel migration. (1) The tidal flats adjacent to the tidal channels are made of 3- to 5-m-thick cohesive muddy sediments covered by Zostera marina that prevents the erosion of the channel banks. This first mechanism is supported by the observation that the tidal creeks that drain the muddy tidal flats covered by Zostera marina do not migrate laterally, whereas those that drain the sandy tidal flats devoid of a dense coverage of marine grass do have active lateral migration. (2) The tidal channels are not fed by any river and therefore do not receive any fluvial sand influx during the winter floods. Their morphology is in equilibrium with the tidal discharge and represents a stable stage in the development of the channel. This second mechanism is supported by the fact that the only tidal channels that actively migrate laterally in the lagoon receive sandy fluvial influx from the River Leyre located in the southeastern corner of the lagoon.  相似文献   

The sediment-fill of Pago Pago Bay (Tutuila Island,American Samoa): New insights on the sediment record of past tsunamis     

Brieuc Riou  Eric Chaumillon  Jean-Luc Schneider  Thierry Corrège  Catherine Chagué 《Sedimentology》2020,67(3):1577-1600

Extensive bathymetric and two-dimensional seismic surveys have been carried out and cores collected in Pago Pago Bay (Tutuila, American Samoa) in order to describe and gain a better understanding of the sediment fill of the bay, which was affected by the 2009 South Pacific Tsunami. Eight sedimentary units were identified over the volcanic bedrock. The basal transgressive unit displays retrograding onlaps towards the shore, whereas the overlying seven aggradational layers alternate between four draping units and three pinching out seaward units. ‘Core to seismic’ correlation reveals that draping units are composed of homogeneous silts, while pinching out units are dominated by very coarse coral fragments showing fresh cuts, mixed with Halimeda plates. The basal unit is attributed to transgressive sedimentation in response to flooding of the bay after the last glacial maximum, followed by the upper aggradational units corresponding to highstand sedimentation. The changeovers in these upper units indicate an alternation between low-energy silt units and high-energy coral debris units interpreted as tsunami-induced deposits. The ¹⁴C dating reveals that high-energy sedimentation units can last up to approximately 2000 years while low-energy sedimentation units can last up to approximately 1000 years. This alternation, deposited during the last highstand, may be explained by cycles of tectonic activity and quiescence of the Tonga Trench subduction, which is the main source of tsunamigenic earthquakes impacting the Samoan archipelago. In the uppermost silt unit, only the geochemical signature of the terrestrial input of the 2009 SPT backwash deposits was detected between 7 cm and 9 cm depth. Hence, Pago Pago Bay offers a unique sediment record of Holocene bay-fill under the impact of past tsunamis intermittently during the last 7000 years.  相似文献   

Regionalization and dependence of coda Q on frequency and lapse time in the seismically active Peloritani region (northeastern Sicily,Italy)     

Elisabetta Giampiccolo  Tiziana Tuvè 《Journal of Seismology》2018,22(4):1059-1074

The Peloritani region is one of the most seismically active regions in Italy and, consequently, the quantification of attenuation of the medium plays an important role for seismic risk evaluation. Moreover, it is necessary for the prediction of earth ground motion and future seismic source studies. An in depth analysis has been made here to understand the frequency and lapse time dependence of attenuation characteristics of the region by using the coda of local earthquakes. A regionalization is likewise performed in order to investigate the spatial variation of coda Q across the whole region. Finally, our results are jointly interpreted with those obtained from recently published 3D velocity tomographies for further insights.  相似文献