Surface complexation of neodymium at the rutile-water interface: A potentiometric and modeling study in NaCl media to 250°C     

Moira K. Ridley  Michael L. Machesky  Donald A. Palmer 《Geochimica et cosmochimica acta》2005,69(1):63-81

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Intensification of Southern Hemisphere westerly winds 2000–1000 years ago: evidence from the subantarctic Campbell and Auckland Islands (52–50°S)          下载免费PDF全文

Chris S. M. Turney  Matt McGlone  Jonathan Palmer  Christopher Fogwill  Alan Hogg  Zoë A. Thomas  Mathew Lipson  Janet M. Wilmshurst  Pavla Fenwick  Richard T. Jones  Ben Hines  Graeme F. Clark 《第四纪科学杂志》2016,31(1):12-19

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Spatial Modeling of Geometallurgical Properties: Techniques and a Case Study     

Jared L. Deutsch  Kevin Palmer  Clayton V. Deutsch  Jozef Szymanski  Thomas H. Etsell 《Natural Resources Research》2016,25(2):161-181

High-resolution spatial numerical models of metallurgical properties constrained by geological controls and more extensively by measured grade and geomechanical properties constitute an important part of geometallurgy. Geostatistical and other numerical techniques are adapted and developed to construct these high-resolution models accounting for all available data. Important issues that must be addressed include unequal sampling of the metallurgical properties versus grade assays, measurements at different scale, and complex nonlinear averaging of many metallurgical parameters. This paper establishes techniques to address each of these issues with the required implementation details and also demonstrates geometallurgical mineral deposit characterization for a copper–molybdenum deposit in South America. High-resolution models of grades and comminution indices are constructed, checked, and are rigorously validated. The workflow demonstrated in this case study is applicable to many other deposit types.  相似文献   

Testing for similarity in area‐based spatial patterns: Alternative methods to Andresen's spatial point pattern test          下载免费PDF全文

Andrew Palmer Wheeler  Wouter Steenbeek  Martin A. Andresen 《Transactions in GIS》2018,22(3):760-774

Andresen's spatial point pattern test (SPPT) compares two spatial point patterns on defined areal units; it identifies areas where the spatial point patterns diverge and aggregates these local (dis)similarities to one global measure. We discuss the limitations of the SPPT and provide two alternative methods to calculate differences in the point patterns. In the first approach we use differences in proportions tests corrected for multiple comparisons. We show how the size of differences matters, as with large point patterns many areas will be identified by SPPT as statistically different, even if those differences are substantively trivial. The second approach uses multinomial logistic regression, which can be extended to identify differences in proportions over continuous time. We demonstrate these methods by identifying areas where pedestrian stops by the New York City Police Department are different from violent crimes for 2006–2016.  相似文献   

Evidence for centennial-scale Lateglacial and early Holocene climatic complexity from Quoyloo Meadow,Orkney, Scotland     

Rhys G. O. Timms  Ashley M. Abrook  Ian P. Matthews  Christopher P. Francis  Agnieszka Mroczkowska  Ian Candy  Stephen J. Brooks  Alice M. Milner  Adrian P. Palmer 《第四纪科学杂志》2021,36(3):339-359

The influence of the North Atlantic on the margins of Europe means the region is particularly sensitive to changes in the ocean–atmospheric system. During the Last Glacial–Interglacial Transition (16–8 cal ka bp ) this system was repeatedly disrupted, leading to a series of abrupt and short-lived shifts in climate. Despite much research, the number and magnitude of these ‘centennial-scale’ events is not well understood. To address this, we expand upon investigations at Quoyloo Meadow, Orkney, Scotland, one of the best chronologically constrained palaeoclimate records in northern Britain. By coupling stable isotope and chironomid fossil analyses with existing data, this study identifies multiple phases of centennial-scale disturbance at: c. 14.0, 11.1, 10.8, 10.5, 10.45 and 10.3 cal ka bp , with the events at 14.0 and 10.3 exhibiting a particularly pronounced cold-climate signature. During the Holocene, the strongest response to climate forcing was at c. 10.3–10.0 cal ka bp , expressed as a two-stage drop in mean July temperatures, a shift in pollen spectra indicative of ‘less-stable’ climatic regimes, and a depletion in δ¹⁸O values. We interpret this as the first reliably dated incidence of the ‘10.3-ka event’ in the British Isles and consider the wider impact of this climatic reversal in other Holocene records.  相似文献   

An analytical description of three-dimensional heliocentric solar sail orbits     

Brian Stewart  Phil Palmer  Mark Roberts 《Celestial Mechanics and Dynamical Astronomy》2017,128(1):61-74

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Correction of the paper “A study of meteorite falls”     

Frans E Wickman  Carl D Palmer 《Journal of Earth System Science》1985,94(2):185-186

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Strontium and its isotopic composition in interstitial waters of marine carbonate sediments     

J.M. Gieskes  H. Elderfield  M.R. Palmer   《Earth and Planetary Science Letters》1986,77(2)

The concentrations and isotopic compositions of strontium in interstitial waters from several DSDP sites, where sediments consist chiefly of carbonate oozes and chalks, are used as indicators of carbonate diagenesis by reference to a recently-produced curve showing detailed variations in the⁸⁷Sr/⁸⁶Sr ratio of seawater with time. Carbonate sediments of the Walvis Ridge show increases in interstitial Sr²⁺ concentrations in the upper carbonate-ooze sections with the highest concentrations near the ooze-chalk boundary where maximum rates of carbonate recrystallization occur. Below this, in situ production of Sr²⁺ diminishes and there is a diffusive flux of Sr to an underlying sink, presumably volcanogenic sediments or basalts, leading to Sr isotopic disequilibrium between carbonates and interstitial waters. In some other sites, however, there is no apparent Sr sink at depth and isotopic equilibrium is retained. Overall, diffusive smoothing of profiles exerts an important control on the⁸⁷Sr/⁸⁶Sr ratios, although lower ratios than contemporaneous seawater values in the carbonate oozes often correlate with zones of Mg²⁺ loss and reflect a combination of a flux of Sr²⁺ from the zone of maximum recrystallization rates together with a contribution from the in situ alteration of volcanic matter.  相似文献   

Gravity Modeling of the Brimfield Township Buried Valley and Associated Aquifer, Portage County, Ohio     

Thomas E. Culek  Donald F. Palmer 《Ground water》1987,25(2):167-175

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Potential for Solute Retardation on Monitoring Well Sand Packs and Its Effect on Purging Requirements for Ground Water Sampling   总被引：1，自引：0，他引：1  

Carl D. Palmer  Joseph F. Keely  William Fish 《Ground Water Monitoring & Remediation》1987,7(2):40-47

Monitoring well sand packs are theoretically capable of retarding metal ions and organic contaminants. If this retardation does indeed occur it may have a significant effect on the purging requirements of newly installed monitoring wells. Calculations based on mass balance and retardation concepts demonstrate that if common guidelines for well purging are followed, contaminants may not be detected or may be detected in lower concentrations than are actually present in the ground water. This problem is greatest in relatively shallow wells installed in low to moderate permeability materials. In most cases, the effect of solute retardation in the sand pack can be avoided simply by additional purging prior to the first sampling of the monitoring well. Common purging guidelines can then be applied to subsequent samplings. The methodology outlined in this paper can be used to calculate the purging requirements of existing monitoring wells or it may be applied to alternative monitoring well designs to test which will require the smallest volume of purged water.  相似文献