Comment on: “The dissolution rates of gibbsite in the presence of chloride, nitrate, silica, sulfate and citrate in open and closed systems at 20 °C” by M. Dietzel and G. Böhme     

David J. Wesolowski  Donald A. Palmer 《Geochimica et cosmochimica acta》2006,70(8):2140-2142

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Dating ancient wood by high-sensitivity liquid scintillation counting and accelerator mass spectrometry—Pushing the boundaries     

Alan G. Hogg  L. Keith Fifield  Chris S.M. Turney  Jonathan G. Palmer  Rex Galbraith  Mike G.K. Baillie 《Quaternary Geochronology》2006,1(4):241-248

It is critical that a comprehensive terrestrial radiocarbon (¹⁴C) calibration curve is developed beyond 26 ka for high-precision calibration and correlation of climatic, environmental and archaeological records. Abundant sub-fossil New Zealand kauri (Agathis australis) wood, preserved in Oxygen Isotope Stage-2 and 3 peat swamps, provides an important resource for ¹⁴C calibration; nowhere else in the world does such an extensive collection of ancient wood exist. Although finite ¹⁴C ages beyond 50 ka are becoming routinely reported, few attempts have been made to demonstrate their accuracy or precision. Finite ages beyond 50 ka require optimization of all elements involved in sample preparation and ¹⁴C analysis. Here we discuss the methodology employed for optimizing the ¹⁴C dating of near-background wood samples by both benzene synthesis for liquid scintillation counting (LSC) or graphite synthesis for accelerator mass spectrometry (AMS). We report the mean background blank activities for both methods and present a statistical model for assigning blank standard errors when blank activity variation is over and above counting statistics. We also present duplicate analyses (using LSC and AMS) of nine successive samples of wood obtained from a sub-fossil kauri log near-background in age to investigate the significance of the measured blank levels and variability.  相似文献   

Solid-solution aqueous-solution reactions between jarosite (KFe₃(SO₄)₂(OH)₆) and its chromate analog   总被引：1，自引：0，他引：1  

Dirk Baron  Carl D. Palmer 《Geochimica et cosmochimica acta》2002,66(16):2841-2853

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Energy losses of solar cosmic rays in interplanetary space     

I. D. Palmer 《Solar physics》1973,30(1):235-242

A simple model of solar cosmic ray propagation which includes diffusion, convection, and energy loss by adiabatic deceleration is studied. A Monte Carlo technique is employed to investigate the variation of mean particle energy in the interplanetary medium after the impulsive release of mono-energetic particles at the Sun. At 1 AU typical energy losses are 43% at 20 h and 64% at 60 h after particle release for a diffusion coefficient (r)= ₀r with =+1/2 and ₀=1.33 × 10²¹ cm² s^–1. When ₀ in this model is reduced by a factor of 4, the energy loss is greater by a factor of 2 at 60 h after particle release. When is increased, the energy losses are greater. Using the model parameters above, an increase in solar wind speed from 300 to 600 km s^–-1 gives rise to energy losses that are greater again by factor of 2 at a time of 60 h. Results are compared with an observation by Murray et al. (1971) of a knee in the energy spectrum of solar protons. It is not considered likely that the change in the energy of the knee with time requires, in addition to adiabatic deceleration, another energy change process which acts to increase the energy of particles.Part of this work was performed while the author was at CSIRO, Division of Radiophysics, Epping, NSW, Australia; also supported in part by the U.S. Atomic Energy Commission.  相似文献   

Canadian Cordilleran displacement: palaeomagnetic results from the Early Jurassic Hazelton Group, Terrane I, British Columbia, Canada     

T. A. Vandall  H. C. Palmer 《Geophysical Journal International》1990,103(3):609-619

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Revisiting the accurate calculation of block-sample covariances using Gauss quadrature     

James R. Carr  Jeffrey A. Palmer 《Mathematical Geology》1993,25(5):507-524

Block-sample covariances may be calculated by discretizing a block into regularly spaced grid points, computing punctual covariance between each grid point and the sample, then averaging. Gauss quadrature is a better, more accurate method for calculating block-sample covariance as has been demonstrated in the past by other authors (the history of which is reviewed herein). This prior research is expanded upon to provide considerably more detail on Gauss quadrature for approximating the areal or volumetric integral for block-sample covariance. A 4 × 4 Gauss point rule is shown to be optimal for this procedure. Moreover, pseudo-computer algorithms are presented to show how to implement Gauss quadrature in existing computer programs which perform block kriging.  相似文献   

Characterization of Turkish coals: a nationwide perspective     

Curtis A. Palmer  Ertem Tuncal&#x;  Kristen O. Dennen  Timothy C. Coburn  Robert B. Finkelman 《International Journal of Coal Geology》2004,60(2-4):85-115

The U.S. Geological Survey (USGS) and the Turkish General Directorate of Mineral Research and Exploration (Maden Tetkik ve Arama Genel Müdürlügü, MTA) are working together to provide a better understanding of the chemical properties of Turkish coals from major Turkish lignite producing areas.The coals in Turkey are generally low rank (lignite or subbituminous) formed in several different depositional environments at different geologic times and have differing chemical properties. Eocene coals are limited to northern Turkey; Oligocene coals, found in the Thrace Basins of northwestern Turkey, are intercalated with marine sediments; Miocene coals are generally located in Western Turkey. The coal deposits, which have limnic characteristics, have relatively abundant reserves. Pliocene–Pleistocene coals are found in the eastern part of Turkey. Most of these coals have low calorific values, high moisture, and high ash contents.Analysis of 143 coal channel samples (most are lignite and subbituminous in rank, but a few are bituminous and one is anthracitic in rank) has been completed for up to 54 elements and other coal properties using a variety of analytical techniques, including inductively coupled plasma emission and mass spectrometry, instrumental neutron activation analysis, and various single element techniques and ASTM standard procedures. Many of these coals have elemental concentrations similar to U.S. lignites found in the Gulf Coast and Fort Union regions. However, maximum or mean concentrations of B, Cr, Cs, Ni, As, Br, Sb, Cs, and U in Turkey are higher than the corresponding maximum or mean values found in either the Fort Union or Gulf Coast regions.  相似文献   

Modeling the surface complexation of calcium at the rutile-water interface to 250°C     

Moira K. Ridley  Michael L. Machesky  Donald A. Palmer 《Geochimica et cosmochimica acta》2004,68(2):239-251

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Sea-level pressure variability around Antarctica since A.D. 1750 inferred from subantarctic tree-ring records     

R. Villalba  E. R. Cook  R. D. D’Arrigo  G. C. Jacoby  P. D. Jones  M. J. Salinger  J. Palmer 《Climate Dynamics》1997,13(6):375-390

 A tree-ring chronology network recently developed from the subantarctic forests provides an opportunity to study long-term climatic variability at higher latitudes in the Southern Hemisphere. Fifty long (1911–1985), homogeneous records of monthly mean sea-level pressure (MSLP) from the southern latitudes (15–65^°S) were intercorrelated on a seasonal basis to establish the most consistent, long-term Trans-Polar teleconnections during this century. Variations in summer MSLP between the South America-Antarctic Peninsula and the New Zealand sectors of the Southern Ocean are significantly correlated in a negative sense (r=−0.53, P<0.001). Climatically sensitive chronologies from Tierra del Fuego (54–55^°) and New Zealand (39–47^°) were used to develop verifiable reconstructions of summer (November to February) MSLP for both sectors of the Southern Ocean. These reconstructions, which explain between 37 and 43% of the instrumentally recorded pressure variance, indicate that inverse trends in MSLP from diametrically opposite sides of Antarctica have prevailed during the past two centuries. However, the strength of this relationship varies over time. Differences in normalized MSLP between the New Zealand and the South America-Antarctic Peninsula sectors were used to develop a Summer Trans-Polar Index (STPI), which represents an index of sea-level pressure wavenumber one in the Southern Hemisphere higher latitudes. Tree-ring based reconstructions of STPI show significant differences in large-scale atmospheric circulation between the nineteenth and the twentieth centuries. Predominantly-negative STPI values during the nineteenth century are consistent with more cyclonic activity and lower summer temperatures in the New Zealand sector during the 1800s. In contrast, cyclonic activity appears to have been stronger in the mid-twentieth than previously for the South American sector of the Southern Ocean. Recent variations in MSLP in both regions are seen as part of the long-term dynamics of the atmosphere connecting opposite sides of Antarctica. A detailed analysis of the MSLP and STPI reconstructions in the time and frequency domains indicates that much of the interannual variability is principally confined to frequency bands with a period around 3.3–3.6 y. Cross spectral analysis between the STPI reconstruction and the Southern Oscillation Index suggests that teleconnections between the tropical ocean and extra-tropical MSLP variations may be influencing climate fluctuations at southern latitudes. Received: 18 December 1996/Accepted: 10 January 1997  相似文献   

Controls on accumulation of a volcaniclastic fan,Ruapehu composite volcano,New Zealand     

Beth A Palmer  Andrew M Purves  Sue L Donoghue 《Bulletin of Volcanology》1993,55(3):176-189

The Whangaehu fan is the youngest sedimentary component on the eastern ring plain surrounding Ruapehu volcano. Fan history comprises constructional (830–200 years bp) and dissectional (<200 years bp) phases. The constructional phase includes four aggradational periods associated with both syneruptive and inter-eruptive behavior. All four aggradational periods began when deposition by large lahars changed flow conditions on the fan from channelized to unchannelized. Subsequent behavior was a function of the rate of sediment influx to the fan. The rate of sediment influx, in turn, was controlled by frequency and magnitude of volcanic eruptions, short-term climate change, and the amount of sediment stored on the volcano flanks. Fanwide aggradation occurred when rates of sediment influx and deposition on the fan were high enough to maintaìn unchannelized flow conditions on the fan surface. Maintenance of an undissected surface required sedimentation from frequent and large lahars that prevented major dissection between events. These conditions were best met during major eruptive episodes when high frequency and magnitude eruptions blanketed the volcano flanks with tephra and rates of lahar initiation were high. During major eruptive episodes, volcanism is the primary control on sedimentation. Climatic variations do not influence sediment accumulation. Local aggradation occurred when lahars were too small to maintain unchannelized flow across the entire fan. In this case, only the major channel system received much sediment following the deposition from the initial lahar. This localized aggradation occurred if (1) the sediment reservoir on the flank was large enough for floods to bulk into debris flows and (2) sedimentation events were frequent enough to maintain sediment supply to only some parts of the fan. These conditions were met during both minor eruptive and inter-eruptive episodes. In both cases, a large sediment reservoir remained on the volcano flanks from previous major eruptive intervals. Periods of increased storm activity produced floods that bulked to relatively small debris flows. When the sediment reservoir was depleted, the fan entered the present dissectional phase. Syneruptive and noneruptive lahars are mostly channelized and sediment bypasses the fan. Fan deposits are rapidly reworked. This is the present case at Ruapehu, even though the volcano is in a minor eruptive episode and the climate favors generation of intense storm floods.  相似文献