Sampling Strategies for Estimation of Parameters Related to Ground Water Quality     

by Pamela E. Crane  Stephen E. Silliman 《Ground water》2009,47(5):699-708

Multiple theoretical sampling designs are studied to determine whether sampling designs can be identified that will provide for characterization of ground water quality in rural regions of developing nations. Sampling design in this work includes assessing sampling frequency, analytical methods, length of sampling period, and requirements of sampling personnel. The results answer a set of questions regarding whether using innovative sampling designs can allow hydrogeologists to take advantage of a range of characterization technologies, sampling strategies, and available personnel to develop high-value, water-quality data sets. Monte Carlo studies are used to assess different sampling strategies in the estimation of three parameters related to a hypothetical chemical observed in a ground water well: mean concentration (MeanC), maximum concentration (MaxC), and total mass load (TML). Five different scenarios are simulated. These scenarios are then subsampled using multiple simulated sampling instruments, time periods (ranging from 1 to 10 years), and sampling frequencies (ranging from weekly to semiannually to parameter dependent). Results are analyzed via the statistics of the resulting estimates, including mean square error, bias, bias squared, and precision. Results suggest that developing a sampling strategy based on what may be considered lower quality instruments can represent a powerful field research approach for estimating select parameters when applied at high frequency. This result suggests the potential utility of using a combination of lower quality instrument and local populations to obtain high frequency data sets in regions where regular monitoring by technicians is not practical.  相似文献   

Magnetic spherules in coastal plain sediments,Sullivan's Island,South Carolina,USA     

Pamela L. Taylor  Robert L. Nusbaum  A. Kem Fronabarger  Michael P. Katuna  Neil Summer 《Meteoritics & planetary science》1996,31(1):77-80

Abstract— We extracted black, magnetic spherules from well cuttings of Oligocene sediments in the coastal plain of South Carolina, USA. Three possible origins were considered: industrial, volcanic, and extraterrestrial. An extraterrestrial origin by ablation of parent meteoroid material is proposed, based on the spherule morphologies, the presence of metallic Fe cores in many of the spherules, and the detection of wüstite in some of the oxide rims. Low Ni contents are problematic but may be attributed to the ablation of a low-Ni parental body, such as hexahedrite. The presence of spherules in somewhat clay-like, sandy sediments is unusual, as most magnetic spherules are found in abyssal muds. Based on benthic foraminiferal assemblages and sediment distribution above, within, and below the beds containing spherules, it is unlikely that the spherules were transported from a deep-sea environment.  相似文献   

The lunar farside: The nature of highlands east of Mare Smythii     

Pamela E. Clark  B. Ray Hawke 《Earth, Moon, and Planets》1991,53(2):93-107

Available lunar orbital data were studied in detail to determine the nature and origin of geochemical variation in a portion of the farside highlands east of the Smythii basin. Such data exist for the elements Al, Mg, Fe, Ti, and Th (Clark and Hawke, 1981; Davis, 1980; Metzger et al., 1977). As in our previous studies (Clarke and Hawke, 1981, 1987), averages and ranges of concentrations for these elements are calculated and correlated for photogeologically defined units associated with features such as Babcock, King, Al-Khwarezmi, Langemak, Pasteur, and Sklodowska and with the region as a whole. In addition, comparisons are made between this and other highland regions which have been investigated by other workers in a similar manner (Andre et al., 1977; Haines et al., 1978; Maxwell and Andre, 1981). The region is shown to be distinctively enriched in the anorthositic end-members of the ANT-suite. Anomalies which have been reported for this region (Hawke et al., 1985) are confirmed by this study. An area south of Pasteur shows enrichment in some mafic components, giving evidence for the presence of buried mare basalt, and lending support to the hypothesis that volcanic activity may be fairly widespread even in the farside highlands. The units just southeast of Mare Smythii appear to be geochemically related to the area partly surrounding the Smythii on the west (Clark and Hawke, 1987). Considerable geochemical heterogeneity exists in this area, as in areas of the nearside highlands (Clark and Hawke, 1981, 1982, 1987; Hawke et al., 1985).  相似文献   

Modeling the effects of bond environment on equilibrium iron isotope fractionation in ferric aquo-chloro complexes     

Pamela S. Hill  Edwin A. Schauble 《Geochimica et cosmochimica acta》2008,72(8):1939-1958

Four or five sets of ab initio models, including Unrestricted Hartree Fock (UHF) and hybrid Density Functional Theory (DFT) are calculated for each species in a series of aqueous ferric aquo-chloro complexes: , , , FeCl₃(H₂O)₃, FeCl₃(H₂O)₂, , FeCl₅H₂O²⁻, , ) in order to determine the relative isotopic fractionation among the complexes, to compare the results of different models for the same complexes, to examine factors that influence the magnitude of the isotopic fractionation, and to compare bond-partner-driven fractionation with redox-driven fractionation.Relative to , all models show a nearly linear decrease in ⁵⁶Fe/⁵⁴Fe as the number of Cl⁻ ions per Fe³⁺ ion increases, with slopes of −0.8‰ to −1.0‰ per Cl⁻ at 20 °C. At 20 °C, 1000 ln β (β = ⁵⁶Fe/⁵⁴Fe reduced partition function ratio relative to a dissociated Fe atom) values range from 8.93‰ to 9.73‰ for , 8.04-9.12‰ for , 7.61-8.73‰ for , 7.14-8.25‰ for , and 3.09-4.41‰ for . The fractionation between and ranges from 1.5‰ to 2.6‰, depending on the model; this is comparable in magnitude to fractionation effects due to Fe³⁺/Fe²⁺ redox reactions. β values from the UHF models are consistently higher than those from the hybrid DFT models.Isotopic fractionation is shown to be sensitive to differences in ligand bond stiffness (above), coordination number, bond length, and the frequency of the asymmetric Fe-X stretching vibrational mode, as predicted by previous theoretical studies. Complexes with smaller coordination numbers have higher 1000 ln β (7.46‰, 5.25‰, and 3.48‰ for , ,, respectively, from the B3LYP/6-31G(d) model). Species with the same number of chlorides but fewer waters also show the effect of coordination number on 1000 ln β: (7.46‰ vs. 7.05‰ for FeCl₃(H₂O)₂ vs. FeCl₃(H₂O)₃ and 5.25‰ vs. 4.94‰ for vs. FeCl₅H₂O²⁻ with the B3LYP/6-31G(d) model). As more Fe-Cl bonds substitute for Fe-OH₂ bonds (with a resulting decrease in β), the lengths of the Fe-Cl bonds and the Fe-O bonds increase.Preliminary modeling of shows an Fe³⁺/Fe²⁺ fractionation of 3.2‰ for the B3LYP/6-31G(d) model, in agreement with previous studies. The addition of an explicit outer hydration sphere of 12 H₂O molecules to models of improves agreement with measured vibrational frequencies and bond lengths; 1000 ln β increases by 0.8-1.0‰. An additional hydration sphere around increases 1000 ln β by only 0.1‰.Isotopic fractionations predicted for this simple system imply that ligands present in an aqueous iron environment are potentially important drivers of fractionation, and suggest that significant fractionation effects are likely in other aqueous systems containing sulfides or organic ligands. Fractionation effects due to both speciation and redox must be considered when interpreting iron isotope fractionations in the geological record.  相似文献   

Rates of zinc and trace metal release from dissolving sphalerite at pH 2.0–4.0     

Mark R. Stanton  Pamela A. Gemery-HillWayne C. Shanks III  Cliff D. Taylor 《Applied Geochemistry》2008

High-Fe and low-Fe sphalerite samples were reacted under controlled pH conditions to determine nonoxidative rates of release of Zn and trace metals from the solid-phase. The release (solubilization) of trace metals from dissolving sphalerite to the aqueous phase can be characterized by a kinetic distribution coefficient, (D_tr), which is defined as [(R_tr/X(tr)_Sph)/(R_Zn/X(Zn)_Sph)], where R is the trace metal or Zn release rate, and X is the mole fraction of the trace metal or Zn in sphalerite. This coefficient describes the relationship of the sphalerite dissolution rate to the trace metal mole fraction in the solid and its aqueous concentration. The distribution was used to determine some controls on metal release during the dissolution of sphalerite. Departures from the ideal D_tr of 1.0 suggest that some trace metals may be released via different pathways or that other processes (e.g., adsorption, solubility of trace minerals such as galena) affect the observed concentration of metals.  相似文献   

The Cost(s) of Geospatial Open Data          下载免费PDF全文

Peter A. Johnson  Renee Sieber  Teresa Scassa  Monica Stephens  Pamela Robinson 《Transactions in GIS》2017,21(3):434-445

The provision of open data by governments at all levels has rapidly increased over recent years. Given that one of the dominant motivations for the provision of open data is to generate ‘value’, both economic and civic, there are valid concerns over the costs incurred in this pursuit. Typically, costs of open data are framed as internal to the data providing government. Building on the strong history of GIScience research on data provision via spatial data infrastructures, this article considers both the direct and indirect costs of open data provision, framing four main areas of indirect costs: citizen participation challenges, uneven provision across geography and user types, subsidy of private sector activities, and the creation of inroads for corporate influence on government. These areas of indirect cost lead to the development of critical questions, including constituency, purpose, enablement, protection, and priorities. These questions are posed as a guide to governments that provide open data in addressing the indirect costs of open data.  相似文献   

A commentary on: Effects of tropical deforestation on global and regional atmospheric chemistry     

Peter M. Vitousek  Pamela A. Matson 《Climatic change》1991,19(1-2):159-162

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Restoration of an impounded salt marsh in New England     

Theresa L. Sinicrope  Pamela G. Hine  R. Scott Warren  William A. Niering 《Estuaries and Coasts》1990,13(1):25-30

The restoration of a 20 ha tidal marsh, impounded for 32, yr, in Stonington, Connecticut was studied to document vegetation change 10 yr after the reintroduction of tidal flushing. These data were then compared to a 1976 survey of the same marsh when it was in its freshest state and dominanted byTypha angustifolia. Currently,T. angustifolia remains vigorous only along the upland borders and in the upper reaches of the valley marsh. Live coverage ofT. angustifolia has declined from 74% to 16% and surviving stands are mostly stunted and depauperate. Other brackish species have also been adversely effected, except forPhragmites australis which has increased. In contrast, the salt marsh speciesSpartina alterniflora has dramatically expanded, from <1% to 45% cover over the last decade. Locally, high marsh species have also become established, covering another 20% of the marsh.  相似文献   

Microsomal cytochrome P-450 function in fish evaluated with polyclonal and monoclonal antibodies to cytochrome P-450E from scup (Stenotomus chrysops)     

John J. Stegeman  Bruce R. Woodin  Sang S. Park  Pamela J. Kloepper-Sams  Harry V. Gelboin 《Marine environmental research》1985,17(2-4)

Monooxygenase reactions catalyzed by cytochromes P-450 are paramount in the oxidative metabolism of many xenobiotics, determining both the persistence and effects of numerous types of compounds. Immunological probes are proving useful in evaluating the functions of P-450 isozymes in microsomal preparations from many species. The regulation of specific isozymes by endogenous and exogenous factors can also be evaluated with such probes. Here we describe studies on the activities apparently catalyzed by induced P-450 in fish, evaluated with both polyclonal and monoclonal antibodies to cytochrome P-450E, the apparent major β-naphthoflavone(BNF) or methylcholanthrene(MC)-inducible isozyme purified from scup (S. chrysops) liver.  相似文献   

CYP1B1 knockdown does not alter synergistic developmental toxicity of polycyclic aromatic hydrocarbons in zebrafish (Danio rerio)     

Timme-Laragy AR  Noyes PD  Buhler DR  Di Giulio RT 《Marine environmental research》2008,66(1):85-87

Polycyclic aromatic hydrocarbons (PAHs) are contaminants increasing in the environment largely due to burning of fossil fuels. Our previous work identified a synergistic toxicity interaction in zebrafish embryos occurring when PAHs that are agonists for the aryl hydrocarbon receptor (AHR) co-occur with PAHs that are CYP1A inhibitors. This toxicity is mediated by the AHR2, and morpholino knockdown of CYP1A exacerbated toxicity. This study tested two hypotheses: (1) in the absence of functional CYP1A, metabolism of PAHs is shunted towards CYP1B1, which has been shown in mammals to produce more reactive metabolites of PAHs; alternatively, (2) CYP1B1 serves a protective role similar to CYP1A. We used a morpholino approach to knockdown CYP1B1 alone and in co-knockdown with CYP1A to determine whether we could alter deformities caused by synergistic toxicity of PAHs. CYP1B1 knockdown was not different from non-injected controls; nor were CYP1B1+CYP1A co-knockdown deformities different from CYP1A knockdown alone. These data suggest that CYP1B1 is not a significant factor in causing synergistic toxicity of PAHs, nor, in contrast to CYP1A, in providing protection.  相似文献