The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C     

Rabindra N Roy  Lakshimi N Roy  Kathleen M Vogel  C Porter-Moore  Tara Pearson  Catherine E Good  Frank J Millero  Douglas M Campbell 《Marine Chemistry》1993,44(2-4)

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell: where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell: The results have been fitted to the equations: where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.  相似文献   

ENSO related modulation of coastal upwelling in the eastern Atlantic   总被引：1，自引：0，他引：1  

Claude Roy  Chris Reason   《Progress in Oceanography》2001,49(1-4)

An index of ENSO in the Pacific during early boreal winter is shown to account for a significant part of the variability of coastal SST anomalies measured a few months later within the wind driven West African coastal upwelling region from 10°N to 26°N. This teleconnection is thought to result from an atmospheric bridge between the Pacific and Atlantic oceans, leading to warm (cold) ENSO events being associated with a relaxation (intensification) of the Atlantic trade winds and of the wind-induced coastal upwelling. This ENSO related modulation of the wind-driven coastal upwelling appears to contribute to the connection observed at the basin-scale between ENSO and SST in the north Atlantic. The ability to use this teleconnection to give warnings of large changes in the West African upwelling several months in advance is successfully tested using data from the 1998 and 1999 ENSO events.  相似文献   

The petroleum evaluation of a tectonically complex area: The western margin of the Southeast Basin (France)     

A. Mascle  R. Vially  E. Deville  B. Biju-Duval  J.P. Roy 《Marine and Petroleum Geology》1996,13(8):941-961

The Southeast Basin of France is the thickest onshore French sedimentary basin which contains locally as much as 10 km of Mesozoic-Cenozoic sediment. Basin development occurred in several stages between late Carboniferous and late Cretaceous times. Partial tectonic inversion took place during two compressive events, the so-called ‘Pyrenean’ and ‘Alpine’ phases of late Cretaceous-early Tertiary and late Tertiary ages respectively. They are separated by an intervening stretching event of Oligocene age, which further south resulted in the opening of the western Mediterranean oceanic basin. As a result of this complex tectonic history, structural traps were difficult to image on the seismic data shot during the first phase of exploration prior to 1980. Oil and gas natural seeps, and shows in several wells, indicate that some petroleum systems are, or have been active, at least in some places.The present erosional western margin of the basin is more or less superimposed on the initial Triassic-Jurassic margin. Margin subsidence and Tertiary inversion are discussed using regional sections on which the polyphase history of the entire basin is well shown. These sections are located on three major segments where the Mesozoic margin is either partly preserved (Ardèche), or has been partly inverted in late Tertiary times (Vercors-Chartreuse), or has been completely inverted in early Tertiary times (Corbières-eastern Pyrenees). 1-D ‘Genex’ basin modelling on the Ardèche segment, and 2-D ‘Thrustpack’ structural-maturity modelling in the Vercors-Chartreuse segment are used to further assess the remaining petroleum plays.  相似文献   

印度东南部海岸拉梅斯沃勒姆滨外保克湾底层水特征对底栖有孔虫的影响     

Kumar V  高莉玲 《海洋地质前沿》2001,17(12):13-15

有孔虫生活在海洋和半咸水环境。底栖有孔虫的存在很大程度上受物理因素（深度、温度、光量、水体扰动）、化学因素（盐度、溶解氧和可用元素）和生物因素（食物供给量和底层沉积物特征）的制约。研究人员对印度东、西岸现代底栖有孔虫生态学和分布状态进行了研究。Ｎａｉｄｕ等在对Ｖｉｓａｋｈａｐａｔｎａｍ港复合体有孔虫进行分析后提出 ,可以将有孔虫作为海洋污染的指示物。ＳｒｅｅｎｉｖａｓａＲａｏ等采用Ｑ模式系数分析对尼赞伯德讷姆湾有孔虫的分布进行了研究 ,确认此区域存在４种组合 ,受不同环境条件的影响。Ｋｈａｒｅ等对门格…  相似文献   

Experimental study on loss factor for corrugated plates by bandwidth method     

Nirmal Kumar Mandal  Roslan Abd. Rahman  M. Salman Leong 《Ocean Engineering》2004,31(10):1313-1323

The material loss factor for technically orthotropic plates was measured by half-power bandwidth method. Rectangular and trapezoidal corrugated plates of steel were considered. A simple isotropic steel plate was also considered for comparison of the results. The concept of single degree of freedom system was adopted. The tests were undertaken at very low frequency range (0–100) Hz. The plate models were suspended freely with two wires to minimize or prevent excessive extraneous energy dissipation. Out of plane point force, random in nature was applied to the top middle of the plates and the responses were measured from the middle point of the plates by FFT analyzer using miniature small mass accelerometer as sensor. The aim of these tests is to investigate the effects of bending rigidity and mode orders over material loss factor. The values of estimated modal damping loss factors are compared and tabulated for the plates models considered. Natural frequencies of some of the initial modes of the plates are also presented.It is observed that the higher the value of bending rigidity of the plates, the larger the values of loss factor of it. There was a significant increase in value of loss factor in corrugated plates to that of the isotropic plate.  相似文献   

Comparison of TOPEX/POSEIDON Altimeter Derived Wind Speed and Wave Parameters with Ocean Buoy Data in the North Indian Ocean   总被引：1，自引：0，他引：1  

Jignesh Kshatriya  Abhijit Sarkar  Raj Kumar 《Marine Geodesy》2001,24(3):131-138

Results of comparison exercises carried out between the state-of-the-art TOPEX/POSEIDON altimeter-derived ocean surface wind speed and ocean wave parameters (significant wave height and wave period) and those measured by a set of ocean data buoys in the North Indian Ocean are presented in this article. Altimeter-derived significant wave height values exhibited rms deviation as small as ±0.3 m, and surface wind speed of ±1.6 m/s. These results are found consistent with those found for the Pacific Ocean. For estimation of ocean wave period, the spectral moments-based semiempirical approach, earlier applied on GEOSAT data, was extended to TOPEX/POSEIDON. For this purpose, distributions of first four years of TOPEX/POSEIDON altimeter data and climatology over the North Indian Ocean were analyzed and a new set of coefficients generated for estimation of wave period. It is shown that wave periods thus estimated from TOPEX/POSEIDON data (for the subsequent two years), when compared with independent data set of ocean data buoys deployed in the North Indian Ocean, exhibit improved accuracy (rms ~ ±1.4 nos) over those determined earlier with GEOSAT data.  相似文献   

Long-term effects of tributyltin compounds on the baltic amphipod, Gammarus oceanicus     

Roy Laughlin  Karin Nordlund  Olof Lindn 《Marine environmental research》1984,12(4):243-271

Amphipod larvae, Gammarus oceanicus, were exposed for 8 weeks to bis(tributyltin) oxide (TBTO) or tributyltin fluoride (TBTF), or for 5 weeks to leachates from tributyltin-containing antibiofouling paints. No larvae survived 8 weeks' exposure to 3 μg/litre TBTO or TBTF. Differential larval survival occurred during exposure to 0·3 gmg/litre of these same compounds. Paint leachates were shown to cause similar toxicity responses at comparable aqueous tributyltin concentrations. An examination of sublethal responses showed slight decreases in growth for larvae exposed to TBTO and to paint leachates, although responses at tributyltin levels below 1 μg/litre were not marked. Whole-animal oxygen consumption rates were not affected by low tributyltin exposure levels. While these studies demonstrate low level toxicity of tributyltins, effects on oxygen consumption and growth do not indicate a mode of action for these compounds.  相似文献   

Bottom Simulating Reflector and Gas Seepage in Okinawa Trough： Evidence of Gas Hydrate in an Active Back-Arc Basin     

栾锡武  Kelin  Wang  Roy  Hyndman  Eleanor  Willoughby 《中国地质大学学报(英文版)》2008,19(2):152-161

To look for gas hydrate, 22 multi-channel and 3 single-channel seismic lines on the East China Sea (ECS) shelf slope and at the bottom of the Okinawa Trough were examined. It was found that there was indeed bottom simulating reflector (BSR) occurrence, but it is very rare. Besides several BSRs, a gas seepage was also found. As shown by the data, both the BSR and gas seepage are all related with local geological structures, such as mud diapir, anticline, and fault-controlled graben-like structure. However, similar structural "anomalies" are quite common in the tectonically very active Okinawa Trough region, but very few of them have developed BSR or gas seepage. The article points out that the main reason is probably the low concentration of organic carbon of the sediment in this area. It was speculated that the rare occurrence of gas hydrates in this region is governed by structure-controlled fluid flow. Numerous faults and fractures form a network of high-permeability channels in the sediment and highly fractured igneous basement to allow fluid circulation and ventilation. Fluid flow in this tectonic environment is driven primarily by thermal buoyancy and takes place on a wide range of spatial scales. The fluid flow may play two roles to facilitate hydrate formation:to help gather enough methane into a small area and to modulate the thermal regime.  相似文献   

Impact of the tsunami and earthquake of 26th December 2004 on the vital coastal ecosystems of the Andaman and Nicobar Islands assessed using RESOURCESAT AWiFS data   总被引：2，自引：0，他引：2  

Anjali Bahuguna  Shailesh Nayak  Dam Roy 《International Journal of Applied Earth Observation and Geoinformation》2008,10(2):229-1

Tsunami waves struck the Indian coast on 26th December 2004 affecting the Andaman and Nicobar group of islands. A quick assessment of the status of the vital coastal ecosystems has been made using pre- and post-tsunami Advance Wide Field Sensor (AWiFS) data of Indian satellite RESOURCESAT with an accuracy of 87–90% and the Kappa ranging from 0.8696 to 0.9053. Among the coastal ecosystems the coral reefs have suffered the maximum with the Nicobar reefs (69% eroded and 29% degraded) bearing the brunt more than the Andaman reefs (54% eroded and 22% degraded). Significant improvement to the condition of the reef damaged due to backwash has been noted. About 41% of the Sentinel reef area has undergone significant improvement. The continuance of the erosion of the southwestern Andaman reefs is due to the impact of recurring earthquakes. The impact on mangroves of both the groups of islands has been due to uprooting as well as inundation of seawater and resulting stagnation. Changes are expected in community structure of mangroves as a result of tsunami.  相似文献   

Urban cadastral mapping using very high resolution remote sensing data     

K. N. Prudhvi Raju  Sarvajeet Kumar  Kshitij Mohan  Manish Kumar Pandey 《Journal of the Indian Society of Remote Sensing》2008,36(3):283-288

With growing urban expanses, one of the pre-requisites for effective governance is Urban Information Systems (UIS) with content down to individual properties (and individuals). The basic input i.e., a map, in UIS should show individual property boundaries showing the plan outline of all structures existing within, at a scale of 1:1000 and larger with sub-metre to centimeters planimetric and geometric accuracy. With very high resolution remote sensing data of the order of 1m available in hand, it is possible to prepare maps with high resolution spatial content. The present exercise demonstrates a method of preparing a geometrically and planimetrically accurate urban cadastral map on very large scale for a small area of about 5 sq km. IKONOS merged data with 1m resolution is used for the purpose. Mapping was done in conjunction with on-site measurements and sketches. Guides are used to maintain shape symmetry and accuracy of buildings and other features. Working out cost of mapping per unit area is another objective in the present exercise. For want of fully or semi-automatic methods of information extraction from very high resolution remote sensing data, it is imperative that mapping should be carried out in conjunction with some on-site measurements wherever necessary.  相似文献