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The isostructural lithium (Li2SiO3) and sodium (Na2SiO3) metasilicates have been investigated from room temperature up to the melting point by single-crystal Raman spectroscopy and energy-dispersive X-ray powder diffraction. The unit-cell parameters and Raman frequencies of Li2SiO3 vary regularly with temperature up to the melting point, which is consistent with the lack of premelting effects in calorimetric measurements. In contrast, Na2SiO3 undergoes a transition at about 850 K from orthorhombic Cmc 21 symmetry, to a lower symmetry (possibly Pmc 21), and shows near 1200 K changes in the Raman spectra that correlate well with the premelting effects as determined from calorimetry observations. In both compounds, a high alkali mobility likely sets in several hundreds of degrees below the melting point. Premelting in Na2SiO3 is associated with extensive deformation of the silicate chains as evidenced near the melting point by similarities in the Raman spectra of the crystalline and liquid phases.  相似文献   
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Downhole measurements recorded in the context of the Ocean Drilling Program in Hole 504B, the deepest hole drilled yet into the oceanic crust, are analyzed in terms of accretion processes of the upper oceanic crust at intermediate spreading-rate. The upper part of the crust is found to support the non steady-state models of crustal accretion developed from seafloor observations (Kappel and Ryan, 1986; Gente, 1987). The continuous and vertical nature of borehole measurements provides stratigraphic and structural data that cannot be obtained solely from seafloor studies and, in turn, these models define a framework to analyze the structural, hydrological, and mineralogical observations made in the hole over the past decade.Due to the observed zonation with depth of alteration processes, and its relation to lava morphologies, the 650-m-thick effusive section penetrated in Hole 504B is postulated to be emplaced as the result of two main volcanic sequences. Massive lava flows are interpreted as corresponding to the onset of these sequences emplaced on the floor of the axial graben. The underlying lava made of structures with large porosity values and numerous cm-scale fractures is thus necessarily accreted at the end of the previous volcanic episode. On top of such high heterogeneous and porous intervals, the thick lava flows constitute crustal permeability barriers, thereby constraining the circulation of hydrothermal fluids.Accreted in the near vicinity of the magma chamber, the lower section is that exposed to the most intense hydrothermal circulation (such as black smokers activity). Once capped by a massive flow at the onset of the second volcanic phase, the lower interval is hydrologically separated from ocean-waters. A reducing environment develops then below it resulting, for example, in the precipitation of sulfides. Today, whereas the interval corresponding to the first volcanic episode is sealed by alteration minerals, the second-one is still open to fluid circulation in its upper section. Thus, upper part of the volcanic edifice is potentially never exposed to fluids reaching deep into the crust, while the lower one is near the ridge axis.Considering that most of the extrusives are emplaced within a narrow volcanic zone, the first unit extruded for a given vertical cross-section is necessarily emplaced at the ridge-axis. In Hole 504B, the 250-m-thickTransition Zone from dikes to extrusives is interpreted as the relict massive unit flooding the axial graben at the onset of the first volcanic sequence, and later ruptured by numerous dikes. Further from the axis, the same massive unit constitutes a potential permeability cap for vertical crustal sections accreted earlier. Also, the upper 50 meters of the basement might be considered as the far-end expression of massive outpours extruded near the ridge-axis.  相似文献   
447.
One-Centimeter Orbit Determination for Jason-1: New GPS-Based Strategies   总被引:2,自引:0,他引:2  
The U.S./French Jason-1 satellite is carrying a state-of-the-art GPS receiver to support precise orbit determination (POD) requirements. The performance of the Jason-1 “BlackJack” GPS receiver was strongly reflected in early POD results from the mission, enabling radial accuracies of 1-2 cm soon after the satellite's 2001 launch. We have made further advances in the GPS-based POD for Jason-1, most notably in describing the phase center variations of the on-board GPS antenna. We have also adopted new geopotential models from the Gravity Recovery and Climate Experiment (GRACE). The new strategies have enabled us to better exploit the unique contributions of the BlackJack GPS tracking data in the POD process. Results of both internal and external (e.g., laser ranging) comparisons indicate that orbit accuracies of 1 cm (radial RMS) are being achieved for Jason-1 using GPS data alone.  相似文献   
448.
The French Transportable Laser Ranging System (FTLRS), a highly transportable Satellite Laser Ranging (SLR) instrument, was set up in Corsica (from January to September 2002) for participating to the JASON-1 altimeter verification phase. In addition to the tracking of oceanographic satellite missions and in order to perform an accurate positioning, the FTLRS also acquired laser ranging data on geodetic satellites, STARLETTE and STELLA essentially.

The paper describes the analysis strategy mainly based on the use of a short-arc orbit technique to compute accurate 1 cm local orbits, and then the geocentric positioning (2-3 mm relative to GPS). Finally, we established the JASON-1 absolute calibration value, based on 9 SLR short-arcs (between cycles 1 and 26), at 108.2 ± 8.7 mm; the 10-day repeatability is of 26.1 mm showing that a great accuracy has been reached.  相似文献   
449.
The Algiers region, northern Algeria, is known to be seismically active, with recurrent large (M>6) earthquakes. Because of the lack of high-resolution bathymetry, the offshore structures remained for a long time poorly known. Thanks to a new marine data base (MARADJA 2003 cruise), the offshore part of the margin is accurately mapped, and new active and recent structures are described. West of the bay of Algiers, the margin enlarges, forming the Khayr al Din bank, interpreted as a tilted block of the passive margin born during the opening of the Algero-Provençal basin. At the slope break, a 80 km-long fault-tip Quaternary fold, namely the Khayr al Din fault, extends at the foot of the margin off NW Algiers and represents the largest active structure of the coastal area, together with the Sahel anticline. We also map for the first time a set of overlapping, en echelon active folds in the upper part of the Khayr al Din bank, located off previously known active structures on land. Most of these faults represent actually a threat for the Algiers region in terms of seismic hazard but also geological hazards, such as tsunamis, as most of them depicts significant dimensions and slip rates. The highest long-term horizontal shortening rate is found on the Khayr al Din fault and is estimated at 0.5 ± 0.1 mm/yr, with a maximal magnitude of 7.3, which provides one of the highest seismogenic potential in the region.A new tectonic framework for the Algiers region is proposed, in which the main south-dipping offshore structure, of opposite vergence relative to most thrusts on land, appears to be nowadays the main driving fault system, as also found further east in the Boumerdès (M 6.8) 2003 rupture zone. The overall apparent pop-up structure of the recent and active faults may result from a progressive migration of the plate limit from the Late Miocene, north-dipping suture zone on land, to the Quaternary, south-dipping main Khayr al Din fault at sea, suggesting a process of subduction inception.  相似文献   
450.
New fossil remains of the proboscidean genus Anancus are described. Among them, a complete skull allows us to revisit for the first time the entire Chadian Anancus fossil record. This genus occurred in the Old World from the late Miocene up to the early Pleistocene. The analysis of dental and cranial characters was allowed individual variations from specific characters to be distinguished. In this study we show that Anancus kenyensis and Anancus osiris are very likely synonym taxa which leads us to emend the diagnosis of A. kenyensis. In addition, this study shows that dental characters in anancines lineage are of little significance for biostratigraphical inference, by contrast to previous works. This study brings new data about the phylogenetical and palaeobiogeographical history of the African anancines.  相似文献   
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