Fe,Mn, P and S Speciation in Sediments from the Capivara Hydroelectric Dam Lake (Brazil) as an Indicator of Anthropogenic Influences     

Wagner José Barreto  Dilson Norio Ishikawa  Ieda Spacino Scarminio  João de Souza Costa  Paulo dos Santos Nora  Miriam de Fatima Soares  Romilaine Mansano Nicolau  Adriana Celeste Esteves Gonçalves  Sonia Regina Giancoli Barreto 《洁净——土壤、空气、水》2008,36(4):353-359

The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments.  相似文献   

Evidences of Holocene transgression on Domingos Petrolini Swamp, southern coastal plain, Rio Grande do Sul, Brazil     

Soraia G.Bauermann  Paulo C.P.Neves  Marleni Marques-Toigo  Abdul R.Ashraf 《东北亚地学研究》2005,(Z1)

The Domingos Petrolini Swamp, located on the Southern Coastal Plain of Rio Grande do Sul, near the town of Rio Grande, constitutes an ample holocene lagoonal deposit. Events related to the holocene transgression and their diverse phases of glacial-eustatic ocillations were found through palynological analysis. Bases on these palynological data, four distinct phases to the paleoenvironmental evolution of the ecosystem were identified. It has also shown a transgressive restricted marine sequence on the base , which suggests the existence of a coastal brackish lagoon or a marisme type of environment. Later, there was a gradation for continentality conditions along with a scarce pollinical record. The third phase is characterized by the presence of marine components and halophyte vegetation, showing another transgressive event in that place. Lastly, the end of direct marine influence over the swamp was recorded and also the vegetation development as it appears these days.  相似文献   

Angular momenta in binary systems     

Ramon Julian Quiroga  Luiz Paulo Ribeiro Vaz 《Astrophysics and Space Science》1988,146(1):99-137

The correlations angular momentaL to massesM are studied for different types of spectroscopic binaries. The functionsL=AM ^b have the coefficientb with the values expected from a Keplerian mechanics, but the valuesA(q, T), A(q, a), A(q, v), associated tob=5/3, 3/2, and 2, respectively, are given (statistically speaking) by multiples or submultiples of discrete values of: the mass ratiosq, the semi-major axesa, periodsT, and velocitiesv of the reduced mass. This indicates the existence of a discrete unit of actionL=(1/2)×potential energy xperiod. Postulates about equivalent states of angular momenta for different orbital parameters are introduced, being this coherent with the analysis of the up-to-date data. Among other examples of the application of such equivalence postulates, we haveL(M) (W-type of the WUMa systems)L(M) (main group of the Algol binaries). The quantum units of action seen here are equivalent to those seen in the solar system in one of our previous works. From comparisons with galaxies and single stars, it is evidence that there is not an unique universal functionL=AM ^b, when the fine structure of the relation is analysed: each type of object has its own coefficients,A, b. It sems to be that there are an upper and a lower limit for all the possible functions. The upper limit isL=A _gM^5/3, withA _g1 associated to periodsT Hubble time, and the lower limit isL=GM ^2/c, with 1. The existence of the upper limit can be investigated with studies of pairs of galaxies, and the lower limit can be tested with analysis of single G, K, M stars. The quantical hypothesis introduced here can be checked definitely, when available larger samples of data with low errors, with similar quality as the selected list of almost 80 eclipsing binaries (mainly detached systems) analysed here.  相似文献   

Geochemical characterization of heavy metal contaminated area using multivariate factorial kriging   总被引：1，自引：0，他引：1  

Joaquim C. B. Queiroz  José R. Sturaro  Augusto C. F. Saraiva  Paulo M. Barbosa Landim 《Environmental Geology》2008,55(1):95-105

This paper describes a geostatistical method, known as factorial kriging analysis, which is well suited for analyzing multivariate spatial information. The method involves multivariate variogram modeling, principal component analysis, and cokriging. It uses several separate correlation structures, each corresponding to a specific spatial scale, and yields a set of regionalized factors summarizing the main features of the data for each spatial scale. This method is applied to an area of high manganese-ore mining activity in Amapá State, North Brazil. Two scales of spatial variation (0.33 and 2.0 km) are identified and interpreted. The results indicate that, for the short-range structure, manganese, arsenic, iron, and cadmium are associated with human activities due to the mining work, while for the long-range structure, the high aluminum, selenium, copper, and lead concentrations, seem to be related to the natural environment. At each scale, the correlation structure is analyzed, and regionalized factors are estimated by cokriging and then mapped.  相似文献   

Origin of the Tongshankou porphyry–skarn Cu–Mo deposit,eastern Yangtze craton,Eastern China: geochronological,geochemical, and Sr–Nd–Hf isotopic constraints     

Jian-Wei Li  Xin-Fu Zhao  Mei-Fu Zhou  Paulo Vasconcelos  Chang-Qian Ma  Xiao-Dong Deng  Zorano Sérgio de Souza  Yong-Xin Zhao  Gang Wu 《Mineralium Deposita》2008,43(3):315-336

The Tongshankou Cu–Mo deposit, located in the westernmost Daye district of the Late Mesozoic Metallogenic Belt along the Middle-Lower reaches of the Yangtze River, eastern China, consists mainly of porphyry and skarn ores hosted in the Tongshankou granodiorite and along the contact with the Lower Triassic marine carbonates, respectively. Sensitive high-resolution ion microprobe zircon U–Pb dating constrains the crystallization of the granodiorite at 140.6 ± 2.4 Ma (1σ). Six molybdenite samples from the porphyry ores yield Re–Os isochron age of 143.8 ± 2.6 Ma (2σ), while a phlogopite sample from the skarn ores yields an ⁴⁰Ar/³⁹Ar plateau age of 143.0 ± 0.3 Ma and an isochron age of 143.8 ± 0.8 Ma (2σ), indicating an earliest Cretaceous mineralization event. The Tongshankou granodiorite has geochemical features resembling slab-derived adakites, such as high Sr (740–1,300 ppm) and enrichment in light rare earth elements (REE), low Sc (<10 ppm), Y (<13.3 ppm), and depletion in heavy REE (<1.2 ppm Yb), and resultant high Sr/Y (60–92) and La/Yb (26–75) ratios. However, they differ from typical subduction-related adakites by high K, low MgO and Mg#, and radiogenic Sr–Nd–Hf isotopic compositions, with (⁸⁷Sr/⁸⁶Sr) _t  = 0.7062–0.7067, ɛ _Nd(t) = −4.37 to −4.63, (¹⁷⁶Hf/¹⁷⁷Hf) _t  = 0.282469–0.282590, and ɛ _Hf(t) = −3.3 to −7.6. The geochemical and isotopic data, coupled with geological analysis, indicate that the Tongshankou granodiorite was most likely generated by partial melting of enriched lithospheric mantle that was previously metasomitized by slab melts related to an ancient subduction system. Magmas derived from such a source could have acquired a high oxidation state, as indicated by the assemblage of quartz–magnetite–titanite–amphibole–Mg-rich biotite in the Tongshankou granodiorite and the compositions of magmatic biotite that fall in the field between the NiNiO and magnetite–hematite buffers in the Fe³⁺–Fe²⁺–Mg diagram. Sulfur would have been present as sulfates in such highly oxidized magmas, so that chalcophile elements Cu and Mo were retained as incompatible elements in the melt, contributing to subsequent mineralization. A compilation of existing data reveals that porphyry and porphyry-related Cu–Fe–Au–Mo mineralization from Daye and other districts of the Metallogenic Belt along the Middle-Lower reaches of the Yangtze River took place coevally in the Early Cretaceous and was related to an intracontinental extensional environment, distinctly different from the arc-compressive setting of the Cenozoic age that has been responsible for the emplacement of most porphyry Cu deposits of the Pacific Rim.  相似文献   

The structure of the lower crust at the Argentine continental margin, South Atlantic at 44°S     

Michael Schnabel  Dieter Franke  Martin Engels  Karl Hinz  Snke Neben  Volkmar Damm  Stefan Grassmann  Hugo Pelliza  Paulo Ricardo Dos Santos 《Tectonophysics》2008,454(1-4):14-22

It is well established that the Argentine passive margin is of the rifted volcanic margin type. This classification is based primarily on the presence of a buried volcanic wedge beneath the continental slope, manifested by seismic data as a seaward dipping reflector sequence (SDRS). Here, we investigate the deep structure of the Argentine volcanic margin at 44°S over 200 km from the shelf to the deep oceanic Argentine Basin. We use wide-angle reflection/refraction seismic data to perform a joint travel time inversion for refracted and reflected travel times. The resulting P-wave velocity-depth model confirms the typical volcanic margin structure. An underplated body is resolved as distinctive high seismic velocity (v_p up to 7.5 km/s) feature in the lower crust in the prolongation of a seaward dipping reflector sequence. A remarkable result is that a second, isolated body of high seismic velocity (v_p up to 7.3 km/s) exists landward of the first high-velocity feature. The centres of both bodies are 60 km apart. The high-velocity lower-crustal bodies likely were emplaced during transient magmatic–volcanic events accompanying the late rifting and initial drifting stages. The lateral variability of the lower crust may be an expression of a multiple rifting process in the sense that the South Atlantic rift evolved by instantaneous breakup of longer continental margin segments. These segments are confined by transfer zones that acted as rift propagation barriers. A lower-crustal reflector was detected at 3 to 5 km above the modern Moho and probably represents the lower boundary of stretched continental crust. With this finding we suggest that the continent–ocean boundary is situated 70 km more seaward than in previous interpretations.  相似文献   

Supergene geochemistry and crystal morphology of gold in a semiarid weathering environment: application to gold exploration     

Paulo Vasconcelos  J. Richard Kyle 《Journal of Geochemical Exploration》1991,40(1-3)

Oxidation of sulfide- and carbonate-rich vein gold deposits under semiarid conditions can be represented as a three-stage process, each creating supergene environments conducive to dissolution and reprecipitation of gold-silver alloys. The three-stage weathering process of sulfide-carbonate gold veins is depth-dependent, and develops from the relatively young, lowermost weathering horizon just below the water table, through an intermediate weathering horizon in the oxidation zone above the water table, and culminating in the oxide-rich upper saprolite and oxisol.Neoformed gold crystals in the weathering profile have distinct composition and morphologic characteristics from the hypogene gold crystals associated with the sulfide- and carbonate-rich ores. Two distinct types of secondary gold are present in the weathering profile: (1) gold crystals associated with sulfates and arsenates; and (2) gold crystals associated with iron and aluminum oxides/hydroxides, or with kaolinite. The distinct crystal morphologies and mineralogical associations of primary and secondary gold are useful in prospecting for gold deposits in weathered terrains.  相似文献   

Tunneling of seismic body waves through thin high-velocity layers in complex structures     

Vlastislav Červený  Paulo R. A. Aranha 《Studia Geophysica et Geodaetica》1992,36(2):115-138

Summary The hybrid ray-reflectivity method is applied to the problem of the transmission of the reflected wave field through a thin high-velocity layer (or through a thin stack of high velocity layers), situated in the overburden of the reflector. In the hybrid ray-reflectivity method, the standard ray method is applied in the smooth parts of the model, and the reflectivity method is used locally at the thin high-velocity layer. With the exception of small epicentral distances, the standard ray method itself fails in such computations. The reason is that a considerable part of the energy for overcritical angles of incidence may be tunneled through the thin high-velocity layer along complex ray-paths, corresponding to inhomogeneous waves. The reflectivity method, applied locally at the thin high-velocity layer, automatically includes all inhomogeneous wave contributions. Thus, the hybrid ray-reflectivity method removes fully the limitations of the standard ray method, but still retains its main advantages, such as its applicability to 2-D and 3-D complex layered structures, flexibility, and low-cost computations. In the numerical examples, the hybrid ray-reflectivity synthetic seismograms are compared with standard ray synthetic seismograms and with full reflectivity computations. The numerical examples show that the hybrid ray-reflectivity method describes the tunneling of seismic energy through a thin high-velocity layer with sufficient accuracy.  相似文献   

Spatial interpolation of precipitation indexes in Sierra Nevada (Spain): comparing the performance of some interpolation methods     

Paulo Pereira  Marc Oliva  Ieva Misiune 《Theoretical and Applied Climatology》2016,123(3-4):683-691

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Ionospheric tomography using GNSS: multiplicative algebraic reconstruction technique applied to the area of Brazil     

Fabricio dos Santos Prol  Paulo de Oliveira Camargo 《GPS Solutions》2016,20(4):807-814

Experimental analysis was performed using multiplicative algebraic reconstruction technique (MART) to map the ionosphere over Brazil. Code and phase observations from the global navigation satellite system (GNSS) together with the international reference ionosphere (IRI) enabled the estimation of ionospheric profiles and total electron content (TEC) over the entire region. Twenty-four days of data collected from existing ground-based GNSS receivers during the recent solar maximum period were used to analyze the performance of the MART algorithm. The results were compared with four ionosondes. It was demonstrated that MART estimated the electron density peak with the same degree of accuracy as the IRI model in regions with appropriate geometrical coverage by GNSS receivers for tomographic reconstruction. In addition, the slant TEC, as estimated with MART, presented lower root-mean-square error than the TEC calculated by ionospheric maps available from the International GNSS Service (IGS). Furthermore, the daily variations of the ionosphere were better represented with the algebraic techniques, compared to the IRI model and IGS maps, enabling a correlation of the elevation of the ionosphere at higher altitudes with the equatorial ionization anomaly intensification. The tomographic representations also enabled the detection of high vertical gradients at the same instants in which ionospheric irregularities were evident.  相似文献