Time dependence of organic matter decay and mixing processes in Framvaren, a permanently anoxic fjord in South Norway     

David W. Dyrssen  Per O. J. Hall  Conny Haraldsson  Melissa Chierici  Jens M. Skei  H. Göte östlund 《Aquatic Geochemistry》1996,2(2):111-129

Three different layers have been identified in Framvaren, which has a maximum water depth of 184 m. One oxic layer above the redoxcline at 18–20 m. One anoxic layer from 20 to 100 m which is occasionally ventilated by a flow over the sill (which has a depth of 2.5 m), and finally a stagnant layer below 100 m. Using the release rate of silica from the bottom and measurements of the concentration of HTO it is possible to make some calculations on the annual volume of interleaving in the layers 25–50 m, 50–75 m, and 75–100 m together with the advective flows. Reliable values of the sulfide concentration were obtained by precipitating and weighing HgS together with careful protection of all anoxic water samples with argon. The light yellow color of the precipitate in the depth range 25 to 80 m indicates that the occasional ventilation will cause such reactions as 0.50₂ + H₂S S(colloidal) + H₂O. The elemental sulfur, being stabilized with HS^–, is set free upon the precipitation of HgS. The new data for the concentration of sulfide give an acceptable stoichiometry for the decay reaction of organic matter. This is not the case with the data of Yao and Millero. The mean values for the concentrations of ammonium and phosphate agree with the new data of Yao and Millero. The mol/mol C/N ratio of 10.1 found in trapped material by Naess and coworkers (1988) agrees with the stoichiometry of the dissolved constituents, i.e. C/N = 9.92 ± 0.45. A denitrification reaction is suggested to explain the high values of C/N. The vertical diffusion coefficient at 100 m calculated from the depth profile of silica was 0.92 × 10^–6 m² s^–1 which lies in the range of values given by Fröyland. Finally, the ¹⁴C age of the total dissolved inorganic carbon (Ct) in the water below 90 m was about 1600 years indicating a bioproduction in the period 8000 years B.P. to A.D. 1853 when a channel was opened between the fjord outside (Helvikfjord) and Framvaren.  相似文献   

Ottar Basin, SW Barents Sea: a major Upper Palaeozoic rift basin containing large volumes of deeply buried salt   总被引：1，自引：0，他引：1  

Asbjørn Johan Breivik  Steinar Thor Gudlaugsson  Jan Inge Faleide 《Basin Research》1995,7(4):299-312

Seismic mapping and gravity modelling of the Ottar Basin - a little studied Upper Palaeozoic graben in the south-western Barents Sea - demonstrates the presence of a major rift basin with large accumulations of unmobilized salt. Buried beneath thick, flat-lying Mesozoic strata, the NE-trending fault-bounded basin is at least 170 km long, varies in width between 50 and 80 km and coincides with a negative gravity anomaly of more than — 10 mgal. Seismic observations show that the south-western part is a half-graben tilted to the north-west whereas the north-eastern part appears to be more symmetric in shape. A large mass deficiency in the north-eastern part of the basin, indicated by a gravity anomaly of more than — 30 mgal, makes it necessary to postulate large amounts of salt within the basin. The preferred gravity model shows a total basin depth of 9.5 km, basin relief of 4.2 km and a salt volume of 6800 km³ corresponding to a 2.4-km-thick salt layer. Similar basin depths, but only 500–600 km³ of salt, are indicated beneath the Samson Dome in the south-western part of the basin. Unlike salt bodies in other Barents Sea basins, the thick salt deposit in the north-eastern part of the Ottar Basin is relatively unaffected by halokinesis. Interfingering of different basin facies, lack of tectonic reactivation of the basin and a relatively late differential loading by protruding cover strata probably explain these differences in development. The large size and voluminous salt deposits establish the Ottar Basin as one of the major Barents Sea evaporite basins and an important structural component of the Upper Palaeozoic rift system.  相似文献   

Gold in the volcanogenic mercury-rich sulfide deposit Långsele,Skellefte ore district,northern Sweden     

Per Nysten 《Mineralium Deposita》1986,21(2):116-120

The mineralogy of gold from a volcanogenic sulfide deposit in northern Sweden (Långsele) was studied. The enrichment of gold and silver in massive ore occurs associated with an intrusive metadolerite vein which can be traced across the ore. The emplacement of this vein mobilized the precious metals together with galena and Pb-Sb sulfosalts into fractures and low pressure zones. A high mercury content at L»ngsele (average 250 ppm) has influenced the gold mineralogy. Thus, gold occurs as Au-Ag amalgam, native gold and rarely as aurostibite (AuSb₂). The results of microprobe analyses of amalgam cluster around Au_0.45Ag_0.45Hg_0.10. The composition of ternary amalgam is discussed in connection with the synthetic Au-Ag-Hg system. Furthermore, native gold was found myrmekitically integrown with stibnite which has been interpreted as a breakdown product of aurostibite at low temperature.  相似文献   

Intrinsic biodegradation of toluene coupled to the microbial reduction of ferric iron: laboratory column experiments     

Zuoping Zheng  Per Aagaard  Gijs D. Breedveld 《Environmental Geology》2002,42(6):649-656

Intrinsic biodegradation of toluene coupled with the microbial reduction of ferric iron (Fe(III)) as the terminal electron acceptor was studied by using laboratory column experiments under continuous flow conditions. Columns were packed with contaminated aquifer sediment and N₂-purged groundwater taken from the western part of the Gardermoen aquifer. The columns were operated anaerobically at 8 °C (in-situ temperature). Chloride was initially used to characterize flow properties of the columns. Intrinsic biodegradation of toluene, including abiotic loss and biological loss, was estimated by comparing breakthrough curves of toluene for live columns and sterilized control columns based on mass balance in steady-state conditions. The column experiments were run at two different flow velocities. The estimated average intrinsic rate was -0.73 and -0.53 mM day^-1 for pore-water velocities of 1.75 and 2.68 cm h^-1, respectively, corresponding to -0.27 and -0.22 mM day^-1 in biological loss rate. The results indicate that intrinsic biodegradation of toluene could be used as an efficient remediation approach for contaminated groundwater at the Gardermoen fire-fighting training site.  相似文献   

Sorption and anaerobic biodegradation of soluble aromatic compounds during groundwater transport. 2. Computer modeling     

Zuoping Zheng  Per Aagaard  Gijs D. Breedveld 《Environmental Geology》2002,41(8):933-941

. The natural attenuation of a binary mixture of toluene and 1,2,4-trimethylbenzene, which was previously experimentally demonstrated in anaerobic column experiments, was simulated with the newly-developed PHREEQC model to reveal the biogeochemical processes involved. The processes considered in this model include advection, diffusion, sorption, redox reactions (e.g., oxidation of toluene and 1,2,4-trimethylbenzene coupled to the reduction of microbial ferric iron), precipitation of secondary minerals such as siderite and magnetite, and dissolution of hydrous ferric oxides, as well as other thermodynamic equilibrium reactions. The functions of advection and diffusion built into the PHREEQC were conventionally simulated. The sorption was kinetically simulated based on a bicontinuum model, whereas biodegradation was described using a multiple-term Monod model. The processes mentioned above were coupled with a geochemical equilibrium model. The consistency between the experimental and modeling results indicates that the processes defined and the controlling parameters chosen could describe the coupled interactions between transport and biogeochemical reactions for the studied system. The discrepancy between modeling and experimental observations, however, also revealed the limitation of the modeling approach. In general, the model approach, which incorporates simplified mathematical representations of the true physico-chemical dynamics of the sorption and biodegradation processes of toluene and 1,2,4-trimethylbenzene under anaerobic conditions is a very efficient and good predictive tool in management and remediation of contaminant groundwater aquifers.  相似文献   

Stratigraphic evidence for a high marine shore-line during the late Weichselian deglaciation on the Kullen Peninsula,southern Sweden     

Per Sandgren  Ian F. Snowball  Dan Hammarlund  Jan Risberg 《第四纪科学杂志》1999,14(3):223-237

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Toward accountable land use mapping: Using geocomputation to improve classification accuracy and reveal uncertainty     

Johan Beekhuizen  Keith C. Clarke 《International Journal of Applied Earth Observation and Geoinformation》2010

The classification of satellite imagery into land use/cover maps is a major challenge in the field of remote sensing. This research aimed at improving the classification accuracy while also revealing uncertain areas by employing a geocomputational approach. We computed numerous land use maps by considering both image texture and band ratio information in the classification procedure. For each land use class, those classifications with the highest class-accuracy were selected and combined into class-probability maps. By selecting the land use class with highest probability for each pixel, we created a hard classification. We stored the corresponding class probabilities in a separate map, indicating the spatial uncertainty in the hard classification. By combining the uncertainty map and the hard classification we created a probability-based land use map, containing spatial estimates of the uncertainty. The technique was tested for both ASTER and Landsat 5 satellite imagery of Gorizia, Italy, and resulted in a 34% and 31% increase, respectively, in the kappa coefficient of classification accuracy. We believe that geocomputational classification methods can be used generally to improve land use and land cover classification from imagery, and to help incorporate classification uncertainty into the resultant map themes.  相似文献   

Holocene glacial history and sea-level changes on James Ross Island,Antarctic Peninsula     

Christian Hjort   lafur Inglfsson  Per Mller  Juan Manuel Lirio 《第四纪科学杂志》1997,12(4):259-273

A reconstruction of deglaciation and associated sea-level changes on northern James Ross Island, Antarctic Peninsula, based on lithostratigraphical and geomorphological studies, shows that the initial deglaciation of presently ice-free areas occurred slightly before 7400 ¹⁴C yr BP. Sea-level in connection with the deglaciation was around 30 m a.s.l. A glacier readvance in Brandy Bay, of at least 7 km, with the initial 3 km over land, reached a position off the present coast at ca. 4600 yr BP. The culmination of the advance was of short duration, and by 4300 yr BP the coastal lowlands again were ice-free. A distinct marine level at 16–18 m a.s.l. was contemporaneous with or slightly post-dates the Brandy Bay advance, thus indicating the relative sea-level around 4600–4500 yr BP. Our results from James Ross Island confirm that over large areas in this part of Antarctica the last deglaciation occurred late. © 1997 John Wiley & Sons, Ltd.  相似文献   

The planet formation imager     

John D. Monnier  Stefan Kraus  Michael J. Ireland  Fabien Baron  Amelia Bayo  Jean-Philippe Berger  Michelle Creech-Eakman  Ruobing Dong  Gaspard Duchêne  Catherine Espaillat  Chris Haniff  Sebastian Hönig  Andrea Isella  Attila Juhasz  Lucas Labadie  Sylvestre Lacour  Stephanie Leifer  Antoine Merand  Ernest Michael  Stefano Minardi  Christoph Mordasini  David Mozurkewich  Johan Olofsson  Claudia Paladini  Romain Petrov  Jörg-Uwe Pott  Stephen Ridgway  Stephen Rinehart  Keivan Stassun  Jean Surdej  Theo ten Brummelaar  Neal Turner  Peter Tuthill  Kerry Vahala  Gerard van Belle  Gautam Vasisht  Ed Wishnow  John Young  Zhaohuan Zhu 《Experimental Astronomy》2018,46(3):517-529

The Planet Formation Imager (PFI, www.planetformationimager.org) is a next-generation infrared interferometer array with the primary goal of imaging the active phases of planet formation in nearby star forming regions. PFI will be sensitive to warm dust emission using mid-infrared capabilities made possible by precise fringe tracking in the near-infrared. An L/M band combiner will be especially sensitive to thermal emission from young exoplanets (and their disks) with a high spectral resolution mode to probe the kinematics of CO and H₂O gas. In this paper, we give an overview of the main science goals of PFI, define a baseline PFI architecture that can achieve those goals, point at remaining technical challenges, and suggest activities today that will help make the Planet Formation Imager facility a reality.  相似文献   

Green and Eco‐Friendly Removal of Mycotoxins with Organo‐Bentonites; Isothermal,Kinetic, and Thermodynamic Studies     

Muhammad Saeed  Komal Farooq  Muhammad Nafees  Muhammad Arshad  Mohammad Salim Akhter  Amir Waseem 《洁净——土壤、空气、水》2020,48(9)

In the current study the application of organo‐modified bentonite for the adsorption of mycotoxins (aflatoxin B1, citrinin, patulin, and zearalenone) is presented. The modification of clays is carried out using benzyl‐tri‐n‐butyl ammonium bromide (BTB), benzethonium chloride (BTC), and dioctyl sodium sulfosuccinate (DSS). Various experimental parameters such as pH, time, adsorbent dose, and mycotoxins concentration are thoroughly studied. The modified clays (B‐BTB, B‐BTC and B‐DSS) are characterized by X‐ray fluorescence, X‐ray diffraction, and Fourier transform infrared spectroscopy. The results depicted the high detoxification efficiency (≈99%) of modified clays for the removal of mycotoxins under optimized conditions (pH 5, time: 30 min, adsorbent amount: 50 mg). The adsorption capacities of modified clays are found in the order of: B‐BTC (AFB1: 18.02, CIT: 18.35, PAT: 18.21, ZEA: 18.09 mg g^?1) > B‐BTB (AFB1: 17.7, CIT: 18.11, PAT: 17.95, ZEA: 17.90 mg g^?1) > B‐DSS (AFB1: 17.5, CIT: 18.02, PAT: 17.86, ZEA: 17.80 mg g^?1). The obtained results fitted well with thermodynamic, isothermal (Langmuir) and pseudo‐second order kinetics. Low cost organo‐modified bentonite shows the promise in mitigating mycotoxin contamination, which could improve food safety and reduce environmental contamination.  相似文献