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Polycyclic aromatic hydrocarbons (PAH) were measured in mussels (Mytilus trossulus) collected between 1990 and 2002 from 11 sites on the shores of Prince William Sound (PWS), Alaska, that were heavily oiled by the 1989 Exxon Valdez oil spill (EVOS). This study, utilizing the methods of the NOAA Status and Trends Mussel Watch Program, found that concentrations of PAH released from spill remnants have decreased dramatically with time and by 2002 were at or near the range of total PAH (TPAH) of 3-355 ng/g dry weight obtained for mussels from unoiled reference sites in PWS. Time-series TPAH data indicate a mean TPAH half-life in mussel tissues of 2.4 years with a range from 1.4 to 5.3, yielding an annual mean loss of bioaccumulated TPAH of 25%. The petroleum-derived TPAH fraction in mussel tissues has decreased with time, reflecting the decreasing release of EVOS residues in shoreline sediments. These results show that PAH from EVOS residues that remain buried in shoreline sediments after the early 1990s are in a form and at locations that have a low accessibility to mussels living in the intertidal zone.  相似文献   
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Long-term exposure of animals to sub-lethal doses of toxicants such as benzene (B) and dimethylnaphthalene (DMN) may result in subtle changes in their physiology and biochemistry. In crustaceans such changes include decreased rate of limb regeneration, extended time to molt and decreased growth increment at molt.1,2 These processes depend upon an adequate supply of stored nutrients in the tissues and appropriate release of neuroendocrine substances from the central nervous system.3,4 We are examining the effects of sub-lethal doses of B and DMN on osmotic and ionic regulation and on nutrient storage in the blue crab, Callinectes sapidus, and the green crab, Carcinus maenas. Disturbances in these physiological processes may reflect alterations in neuroendocrine functions brought about by the presence of toxicants. We find that exposure of C. maenas to B or DMN, followed by transfer to a dilute medium, results in impaired osmoregulatory capacity, while addition of these compounds to a dilute medium to which the animal is already acclimated does not affect their regulatory ability. Storage of carbohydrate in the midgut gland (hepatopancreas) is decreased by B or DMN, while the accessory storage tissues (gill, muscle) are not significantly affected.  相似文献   
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The spatial variability of porosity and permeability was determined for a section in the uppermost Maastrichtian chalk exposed in the Sigerslev quarry at Stevns Klint. The aims were threefold: (1) to quantify the spatial variability pattern and its link to geology by applying systematic variogram analysis procedure, (2) to detect potential cyclicity in the petrophysical properties in this pure and overtly homogeneous chalk, and (3) to compare the section with chalk reservoirs in the North Sea in order to asses to what extent this onshore sequence has a potential as an analogue of the offshore, more deeply buried chalk reservoirs. The interval is of comparable stratigraphic age to the uppermost reservoir zones in the Tor Formation of the North Sea chalk reservoirs. The variability and spatial correlation of porosity and permeability in both horizontal and vertical directions are interpreted in a geological context and show indications of small-scale heterogeneity at 15–25 cm scale, but the clear cyclic layering described from other chalk deposits is not recognised at this locality. The investigated outcrop is not a close analogue to North Sea reservoir chalk, but some aspects are common including basic material properties, porosity/permeability trends and the variability pattern. The outcrop has a potential as analogue for some of the onshore subsurface chalk successions at shallow burial depth that form important aquifers.  相似文献   
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In order to prevent the generation of spurious free sub- and superharmonics of random waves in a laboratory channel, the control signal for the wave board has to be derived according to a higher-order wave theory. An expression for this control signal has been derived with the perturbation method of multiple scales. It is much less complex and requires less computation time than the expressions obtained from the full second-order theory. The new method for second-order subharmonics was verified experimentally for waves with bichromatic and continuous first-order spectra. The data were analysed with the complex-harmonic principal-component analysis to reduce the influence of noise.  相似文献   
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The discharge of radioactive waste, from nuclear fuel reprocessing facilities, into the coastal waters of north-west Europe has resulted in a significant increase in the inventories of a number of artificial radionuclides in the North Atlantic. Radiocaesium, 90Sr and 99Tc, which behave conservatively in seawater, have been used widely as tracers of water movement through the North Sea, Norwegian Coastal Current, Barents Sea, Greenland Sea, Fram Strait, Eurasian Basin, East Greenland Current and Denmark Strait overflow. These studies are summarised in the present paper. It has been estimated that 22% of the 137Cs Sellafield discharge has passed into the Barents Sea, en route to the Nansen Basin, via the Bjomoya-Fugloya Section, with another 13% passing through the Fram Strait. This amounts to 14 PBq 137Cs. Quantifying the influx of other radionuclides has been more problematic. The inflowing Atlantic water now appears to be diluting waters in the Arctic Basin, which were contaminated in the late 1970s and early 1980s as a result of the substantial decrease in the discharge of reprocessing wastes. Sellafield (U.K.) has dominated the supply of 134Cs, 137Cs, 90Sr, 99Tc and Pu, whereas La Hague (France) has contributed a larger proportion of 129I and 125Sb.  相似文献   
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Tritium data were collected between 1985 and 1987 on several cruises of the German research icebreaker “Polarstern” to the Weddell Sea. Maximum tritium concentrations in the surface waters are of the order of 200 mTU. The minimum values observed in the Weddell Sea Deep Water at about 1000 m depth are about 15–40 mTU. The bottom waters show tritium concentrations of about 70–100 mTU in the central gyre, increasing to about 120 mTU in the northwestern corner of the Weddell Sea. The overflowing Ice Shelf Water observed on the continental slope west of the Filchner Depression has tritium concentrations close to those of the surface waters, indicating rapid renewal of this water mass. The data reflect the rapid renewal of the bottom waters in the northwestern corner of the Weddell Sea and the mixing of bottom water from this boundary current into the bottom waters of the central Weddell Gyre.  相似文献   
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