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921.
The aim of this study is to recognize the basic clastic rock types on the basis of Hounsfield Units (HUs) by using statistical methods (hypothesis tests, distribution fitting, and confidence intervals). How does this recognition depend on depositional history of samples tested? Does the numerical pattern of HUs obtained from small-scale analyzing of some particular sedimentary structures coincide to the textural expectations of those sedimentary structures? Are the HU values provided by the CT measurements capable of evidencing micro-cycles belonging to a particular depositional history?For testing the numerical recognition, we analyze macroscopically homogeneous argillaceous marl, siltstone and fine sandstone samples with similar depositional background, age, and degree of diagenesis. The preliminary research shows that the Hounsfield Units can identify different sedimentary rocks considerably well. There are significant differences among the confidence intervals belonging to the different rock types. However, there also have been some slight overlaps among them.For analyzing the effects of the depositional processes in case of a particular rock type, samples from channel sandstone, distributary mouth-bar, massive (structureless) sandstone from a delta-fed turbidity fan, and channel sandstone with traction carpet origin from a delta-fed turbidity fan (all coming from Pannonian basin filling series) are used. The results prove again the significant differences in the terms of both confidence intervals and distribution-types; however, some overlapping also occurs.  相似文献   
922.
The lateral transport of bicarbonate as dissolved inorganic carbon (DIC) to the oceans is an integral component of the global carbon budget and can represent the sequestration of CO2 from the atmosphere. Recently studies have implicated land use change, in particular agricultural development, as an accelerator of bicarbonate export. However, due to the co-variation of land use, bedrock and surficial geologies, and the relationship between bicarbonate export and climate, the impact of anthropogenic activities on DIC export remains an important research question. In order to examine the land use controls on DIC export from small temperate watersheds we sampled 19 streams draining catchments of varying land uses with similar bedrock and surficial geologies. In addition to an agricultural effect, there was a strong correlation between the percent of watershed in urban development and DIC concentrations and DIC yields. Urban watersheds exported 7.8 times more DIC than their nearby forested counterparts and 2.0 times more DIC than nearby agricultural catchments. Isotopic data suggest that excess DIC export from altered systems results from increased chemical weathering, enhanced CO2 production within urban green spaces, and as a result of organic matter loading from septic systems and leaky sewer lines. Furthermore, we found that nitrogen additions (e.g. fertilizers and manure) are aiding in the dissolution of lime, increasing the total export of DIC from agricultural watersheds. Calculated anthropogenic loading rates ranged from 0.43 to 0.86 mol C m− 2 yr− 1. These loading rates suggest that a significant portion of global DIC export might be attributable to human activities, although the impacts on CO2 sequestration are difficult to determine.  相似文献   
923.
The results of several recent studies challenge the reigning paradigm that continental soil dust provides the only significant atmospheric source of dissolved iron to the surface ocean. This evidence includes correlations between the operational solubility of aerosol iron and atmospheric loadings of black carbon and aluminum-normalized vanadium and nickel, each of which are associated with emissions from the combustion of fossil fuel oil. These observations suggest that the relative solubility of aerosol iron, hence the eolian flux of soluble iron to the surface ocean, may be significantly impacted by anthropogenic oil combustion products. Using recent field data from the Bermuda region, we have developed an empirical method to estimate the solubility of aerosol iron using bulk aerosol concentrations of Fe, V and Al. We apply this method to a large body of published data from the AEROCE program for North Atlantic island sites on Tenerife, Barbados, Bermuda and Ireland, where the relative proportions of anthropogenic aerosols range from minor to major, respectively. Our aerosol iron solubility estimates suggest that anthropogenic emissions contribute approximately 70% and 85% of the annual dry deposition of soluble iron to the surface ocean near Bermuda and Ireland, respectively, implying that human activities have profoundly affected the iron budget of the North Atlantic region. The annual mean dry deposition of soluble iron at Barbados and Izana is dominated by soil dust. The anthropogenic contribution at these two sites ranges from 12% to 30% and is highly dependent on the soil dust solubility of Fe employed in the model. The low end (∼12%) estimate appears to be more representative of these high-dust sites.  相似文献   
924.
Oxygen and hydrogen isotope fractionation factors in the talc-water and serpentine-water systems have been determined by laboratory experiment from 250 to 450 °C at 50 MPa using the partial exchange technique. Talc was synthesized from brucite + quartz, resulting in nearly 100% exchange during reaction at 350 and 450 °C. For serpentine, D-H exchange was much more rapid than 18O-16O exchange when natural chrysotile fibers were employed in the initial charge. In experiments with lizardite as the starting charge, recrystallization to chrysotile enhanced the rate of 18O-16O exchange with the coexisting aqueous phase. Oxygen isotope fractionation factors in both the talc-water and serpentine-water systems decrease with increasing temperature and can be described from 250 to 450 °C by the relationships: 1000 ln  = 11.70 × 106/T2 − 25.49 × 103/T + 12.48 and 1000 ln  = 3.49 × 106/T2 − 9.48 where T is temperature in Kelvin. Over the same temperature interval at 50 MPa, talc-water D-H fractionation is only weakly dependent on temperature, similar to brucite and chlorite, and can be described by the equation: 1000 ln = 10.88 × 106/T2 − 41.52 × 103/T + 5.61 where T is temperature in Kelvin. Our D-H serpentine-water fractionation factors calibrated by experiment decrease with temperature and form a consistent trend with fractionation factors derived from lower temperature field calibrations. By regression of these data, we have refined and extended the D-H fractionation curve from 25 to 450 °C, 50 MPa as follows: 1000 ln  = 3.436 × 106/T2 − 34.736 × 103/T + 21.67 where T is temperature in Kelvin. These new data should improve the application of D-H and 18O-16O isotopes to constrain the temperature and origin of hydrothermal fluids responsible for serpentine formation in a variety of geologic settings.  相似文献   
925.
Carbon isotopic exchange between graphite and three polymorphs of CaCO3 was investigated at temperatures of 600-1400 °C and at pressures from 1.4 to 2.3 GPa. Fractionation factors at all temperatures were determined by the partial exchange treatment of Northrop and Clayton (1966).Graphite starting material for the majority of the experiments was milled in water for 20-25 h, producing aggregates of nanosheets. The sheets range in width from 50 to 1000 nm and in thickness from 20 to 30 nm, and they retain hexagonal symmetry.Isotopic exchange appears to be the sum of surface exchange and interior exchange. At 1100-1400 °C, interior exchange exceeded surface exchange, probably by a combination of grain growth, as determined by increase in crystallite size, recrystallization, as observed in FESEM images, and diffusion. In some runs at 1200 and 1400 °C with an isotopic contrast between the initial graphite and calcite of close to 50‰, equilibrium fractionation was actually overstepped due to a kinetic effect. A weighted regression of fractionation factors from the high-temperature runs yields the line of equilibrium interior exchange:
  相似文献   
926.

Discussion

Paleoproterozoic Boninite-Like Rocks in an Intracratonic Setting from Northern Bastar Craton, Central India by D.V. Subba Rao, V. Balaram, K. Naga Raju and D.N. Sridhar. Jour. Geol. Soc. India, v.72, 2008, pp.373–380  相似文献   
927.
The Qilian Orogen of north western China records mid-Paleozoic collisional suturing of arc and continental blocks onto the south western margin of the North China craton. Silurian strata from the retroarc foreland basin mark the transition from ocean closure and northward subduction to the initiation of collision suturing. Detrital zircons were analysed from the western and eastern parts of the basin and show a spectrum of ages from Archean to Paleozoic with major age concentrations at around 2.5 Ga, 1.6 Ga, 1.2 Ga, 0.98 Ga, 0.7 Ga and 0.45 Ga. Archean age grains are derived from the North China craton, whereas the Central Qilian Bloc, which lies to the south provides the likely source for the bulk of the Proterozoic detritus. Paleozoic grains are restricted to Early Silurian samples from the western part of the basin and are considered to have been derived from the magmatic arc related to ocean closure and ultimate collision of the Central Qilian Belt with the North China craton.  相似文献   
928.
929.
At least three sets of moraines mark distinct glacial stands since the last glacial maximum (LGM) in the Three Sisters region of the Oregon Cascade Range. The oldest stand predates 8.1 ka (defined here as post-LGM), followed by a second between ∼ 2 and 8 ka (Neoglacial) and a third from the Little Ice Age (LIA) advance of the last 300 years. The post-LGM equilibrium line altitudes were 260 ± 100 m lower than that of modern glaciers, requiring 23 ± 9% increased winter snowfall and 1.4 ± 0.5°C cooler summer temperatures than at present. The LIA advance had equilibrium line altitudes 110 ± 40 m lower than at present, implying 10 ± 4% greater winter snowfall and 0.6 ± 0.2°C cooler summer temperatures.  相似文献   
930.
Latest Pleistocene and Holocene glacier variations in the European Alps   总被引:1,自引:0,他引:1  
In the Alps, climatic conditions reflected in glacier and rock glacier activity in the earliest Holocene show a strong affinity to conditions in the latest Pleistocene (Younger Dryas). Glacier advances in the Alps related to Younger Dryas cooling led to the deposition of Egesen stadial moraines. Egesen stadial moraines can be divided into three or in some cases even more phases (sub-stadials). Moraines of the earliest and most extended advance, the Egesen maximum, stabilized at 12.2 ± 1.0 ka based on 10Be exposure dating at the Schönferwall (Tyrol, Austria) and the Julier Pass-outer moraine (Switzerland). Final stabilization of moraines at the end of the Egesen stadial was at 11.3 ± 0.9 ka as shown by 10Be data from four sites across the Alps. From west to east the sites are Piano del Praiet (northwestern Italy), Grosser Aletschgletscher (central Switzerland), Julier Pass-inner moraine (eastern Switzerland), and Val Viola (northeastern Italy). There is excellent agreement of the 10Be ages from the four sites. In the earliest Holocene, glaciers in the northernmost mountain ranges advanced at around 10.8 ± 1.1 ka as shown by 10Be data from the Kartell site (northern Tyrol, Austria). In more sheltered, drier regions rock glacier activity dominated as shown, for example, at Julier Pass and Larstig valley (Tyrol, Austria). New 10Be dates presented here for two rock glaciers in Larstig valley indicate final stabilization no later than 10.5 ± 0.8 ka. Based on this data, we conclude the earliest Holocene (between 11.6 and about 10.5 ka) was still strongly affected by the cold climatic conditions of the Younger Dryas and the Preboreal oscillation, with the intervening warming phase having had the effect of rapid downwasting of Egesen glaciers. At or slightly before 10.5 ka rapid shrinkage of glaciers to a size smaller than their late 20th century size reflects markedly warmer and possibly also drier climate. Between about 10.5 ka and 3.3 ka conditions in the Alps were not conducive to significant glacier expansion except possibly during rare brief intervals. Past tree-line data from Kaunertal (Tyrol, Austria) in concert with radiocarbon and dendrochronologically dated wood fragments found recently in the glacier forefields in both the Swiss and Austrian Alps points to long periods during the Holocene when glaciers were smaller than they were during the late 20th century. Equilibrium line altitudes (ELA) were about 200 m higher than they are today and about 300 m higher in comparison to Little Ice Age (LIA) ELAs. The Larstig rock glacier site we dated with 10Be is the type area for a postulated mid-Holocene cold period called the Larstig oscillation (presumed age about 7.0 ka). Our data point to final stabilization of those rock glaciers in the earliest Holocene and not in the middle Holocene. The combined data indicate there was no time window in the middle Holocene long enough for rock glaciers of the size and at the elevation of the Larstig site to have formed. During the short infrequent cold oscillations between 10.5 and 3.3 ka small glaciers (less than several km2) may have advanced to close to their LIA dimensions. Overall, the cold periods were just too short for large glaciers to advance. After 3.3 ka, climate conditions became generally colder and warm periods were brief and less frequent. Large glaciers (for example Grosser Aletschgletscher) advanced markedly at 3.0–2.6 ka, around 600 AD and during the LIA. Glaciers in the Alps attained their LIA maximum extents in the 14th, 17th, and 19th centuries, with most reaching their greatest LIA extent in the final 1850/1860 AD advance.  相似文献   
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