Records of organochlorine pesticides in soils and sediments on the southwest of Buenos Aires Province,Argentina     

Norma Tombesi  Karla Pozo  Andrés Arias  Mónica Alvarez  Petra Pribylova  Ondrej Audy  Jana Klánová 《Environmental Earth Sciences》2018,77(11):403

The present study fills a gap in the knowledge in regards to the occurrence of banned pesticides at both coastal and inland locations at the Southwest Buenos Aires region, Argentina. Superficial sediment and soil samples were collected from different sites along the Bahia Blanca Estuary and surrounding sites to assess the concentration levels and spatial distribution of 12 selected organochlorine pesticides (OCs); 13 spatial locations including inland and shore-coast were sampled to evaluate occurrence and concentration levels of hexachlorocyclohexanes α-HCH, β-HCH, δ-HCH, γ-HCH, dichlorodiphenyltrichloroethane and its degradation products (DDXs: p,p′-DDT, o,p′-DDT, p,p′-DDE, o,p′-DDE, p,p′-DDD, o,p′-DDD) and the polychlorobenzenes PeCB (pentachlorobenzene) and HCB (hexachlorobenzene). After cleaning and extractions steps, samples were analyzed by means of gas chromatography/mass spectrometry. ∑OCs (sum of all studied compounds) ranged between 0.206 and 1040 ng g^?1 dw (mean?=?82.4 and SD?=?277 ng g^?1 dw). Total HCHs (sum of α-HCH, β-HCH, γ-HCH and δ-HCH) ranged from 0.0858 to 0.876 ng g^?1 dw (mean?=?0.43 and SD?=?0.23 ng g^?1 dw), DDXs (sum of p,p′and o,p′ isomers) from 0.080 to 1040 ng g^?1 dw (mean?=?81.3 and SD?=?277 ng g^?1 dw). Lower concentrations were found for PeCB (mean?=?0.095 and SD 0.17 ng g^?1 dw) and HCB (mean?=?0.56 and SD 1.7 ng g^?1 dw). Principal component analysis (PCA) permitted the extraction of underlying information about common factors, providing an overview of the distribution of pesticides and allowing the characterization of sites in regards to the major pesticide signature.  相似文献   

Increased soil gas radon and indoor radon concentrations in Neoproterozoic olistostromes of the Teplá-Barrandian unit (Czech Republic)     

Ivan Barnet  Petra Pacherová 《Environmental Earth Sciences》2013,69(5):1601-1607

The Neoproterozoic olistostromes were first distinguished as a special geological unit in a generalised geological map of the Czech Republic on a scale 1:500,000. The olistostromes represent a tectonic mélange or subaquatic continental slope-slides formed by a mixture of black shales, greywackes, carbonates and shales, forming an extremely inhomogeneous geological environment. The extreme over-limit values of indoor radon (Rn, ²²²Rn) were first detected during check measurements performed for final building approval by team of the National Radiation Protection Institute in a house situated on bedrock of black shales—lithological component of olistostromes north-eastward from Plzeň. Additional measurements of soil gas Rn performed by the Czech Geological Survey were oriented to cover the whole olistostrome belt extending over 65 × 25 km area NE of Plzeň–Prague general direction. The increased concentrations both of soil gas and indoor Rn were confirmed in the whole extent of Neoproterozoic olistostrome belt compared to neighbouring geological units (Neoproterozoic metasediments on NW and Cambrian Palaeovolcanites and Ordovician sediments on SE). This observation lead to increasing the radon index of olistostromes to medium radon category (from the low one) both in general and detailed Rn index maps. Drawing the attention to this lithological type enables to improve the radon risk prevention for newly built houses and interest of remediation of existing houses not only in the specific area of the Czech Republic, but also in other European countries, where Neoproterozoic olistostromes form the geological basement.  相似文献   

High‐resolution synchrotron X‐ray fluorescence investigation of calcite coralloid speleothems: Elemental incorporation and their potential as environmental archives     

Valentina Vanghi  Andrea Borsato  Silvia Frisia  Daryl L. Howard  Gertruida Gloy  John Hellstrom  Petra Bajo 《Sedimentology》2019,66(7):2661-2685

Synchrotron high‐resolution and micro‐X‐ray fluorescence elemental mapping of two coeval coralloid speleothems from Lamalunga Cave (Italy) are complemented with petrographic, morphological and microstratigraphic studies. The importance of these speleothems relies on their direct and indirect association with a complete Neanderthal skeleton (‘Altamura Man’) found inside the cave. The coralloids grew discontinuously between 64·6 ka and the Holocene and reveal exceptionally high concentrations of Mg, Sr and Si, particularly on convex surfaces, where evaporation is more intense. The incorporation of trace elements depends on several factors including location, shape and geometrical evolution during their growth, as well as climate and environmental parameters. This resulted in calcite precipitation with Sr compositions from 100 to 1200 ppm and an average concentration of 7000 ppm Mg. An unusually high Si content (up to 16%) is possibly derived from volcanic ash transported as particulate and in solution inside the cave. The most common fabrics observed consist of non‐fluorescent elongated columnar calcite forming clean isopachous bands and fluorescent fibre‐like crystals associated with laminated, lenticular bands high in Sr, Mg and Si. Variability in Sr, Mg and Si concentrations appears to induce fabric changes in the coralloids. Elongation and lattice distortion of the crystals was found to coincide with high Mg concentrations. The transition from compact elongated to open to fibre‐like, is here interpreted as due to high concentrations of Si and Sr, which are preferentially incorporated in the speleothem at crystal boundaries and intra‐laminae. It is here inferred that coralloid fabric changes and their elemental content potentially record local rainfall variations through time, with the clean compact calcite marking high infiltration and open fibre‐like and micrite fabrics recording dry periods.  相似文献   

High concentrations of amorphous,biogenic Si (BSi) in the sediment of a small high-latitude lake: implications for biogeochemical Si cycling and for the use of BSi as a paleoproxy     

Petra Tallberg  Sophie Opfergelt  Jean-Thomas Cornelis  Anne Liljendahl  Jan Weckström 《Aquatic Sciences - Research Across Boundaries》2015,77(2):293-305

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Importance of Spatial Resolution in Global Groundwater Modeling     

Robert Reinecke  Alexander Wachholz  Steffen Mehl  Laura Foglia  Christoph Niemann  Petra Döll 《Ground water》2020,58(3):363-376

Global-scale gradient-based groundwater models are a new endeavor for hydrologists who wish to improve global hydrological models (GHMs). In particular, the integration of such groundwater models into GHMs improves the simulation of water flows between surface water and groundwater and of capillary rise and thus evapotranspiration. Currently, these models are not able to simulate water table depth adequately over the entire globe. Unsatisfactory model performance compared to well observations suggests that a higher spatial resolution is required to better represent the high spatial variability of land surface and groundwater elevations. In this study, we use New Zealand as a testbed and analyze the impacts of spatial resolution on the results of global groundwater models. Steady-state hydraulic heads simulated by two versions of the global groundwater model G³M, at spatial resolutions of 5 arc-minutes (9 km) and 30 arc-seconds (900 m), are compared with observations from the Canterbury region. The output of three other groundwater models with different spatial resolutions is analyzed as well. Considering the spatial distribution of residuals, general patterns of unsatisfactory model performance remain at the higher resolutions, suggesting that an increase in model resolution alone does not fix problems such as the systematic overestimation of hydraulic head. We conclude that (1) a new understanding of how low-resolution global groundwater models can be evaluated is required, and (2) merely increasing the spatial resolution of global-scale groundwater models will not improve the simulation of the global freshwater system.  相似文献   

In memoriam for Prof. Tadepalli (Tad) Murty (1937–2018)     

Van Steenbergen  Petra 《Natural Hazards》2019,96(2):551-552

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Morphostratigraphy and provenance of Plio‐Pleistocene terraces in the south‐eastern Alpine foreland: the Mislinja and Upper Savinja valleys,northern Slovenia     

Eva Mencin Gale  Petra Jam&#x;ek Rupnik  Mirka Trajanova  Milo&#x; Bavec  Flavio S. Anselmetti  Andrej &#x;muc 《第四纪科学杂志》2019,34(8):633-649

This study focuses on the Plio‐Pleistocene fluvial deposits preserved in the terrace staircases in the south‐eastern Alpine foreland of the Mislinja (MV) and Upper Savinja valleys (USV) in northern Slovenia. The area is located at the north‐eastern margin of the Adria microplate, where neotectonic activity is the prevailing driving force for the terrace formation. The aim of this study is to determine the morphostratigraphy and provenance of the Pliocene to Early Pleistocene gravels using geomorphic and clast lithological analysis. The established morphostratigraphic framework encompasses three terraces in the MV and five terraces in the USV. Due to the lack of age‐relevant data, the morphostratigraphy of the MV and USV is based on the results of geomorphic analysis, clast petrography and data from the literature. Low‐level, middle‐level and high‐level terrace groups were tentatively attributed to the Late and Middle Pleistocene, Early Pleistocene–Pliocene and Pliocene, and compared with the traditional Quaternary stratigraphy of the Alpine foreland. The results of the clast lithological analysis revealed major provenance areas. Moreover, the evolution of long‐term drainage from the Miocene onward was inferred, which suggests that the system reached conformity with the present‐day drainage pattern at the Miocene to Plio‐Pleistocene transition. Copyright © 2019 John Wiley & Sons, Ltd.  相似文献   

Palaeolimnology of Lake Sapanca and identification of historic earthquake signals,Northern Anatolian Fault Zone (Turkey)     

Markus J. Schwab  Petra Werner  Peter Dulski  Edward McGee  Norbert R. Nowaczyk  Sébastien Bertrand  Suzanne A.G. Leroy 《Quaternary Science Reviews》2009,28(11-12):991-1005

Lake Sapanca is located on a strand of the Northern Anatolian Fault Zone (NAFZ, Turkey), where a series of strong earthquakes (Ms >6.0) have occurred over the past hundred years. Identifying prehistoric earthquakes in and around Lake Sapanca is key to a better understanding of plate movements along the NAFZ. This study contributes to the development of palaeolimnological tools to identify past earthquakes in Lake Sapanca. To this end several promising proxies were investigated, specifically lithology, magnetic susceptibility, grain size (thin-section and laser analysis), geochemistry, pollen concentration, diatom assemblages, ¹³⁷Cs and ²¹⁰Pb. Sedimentological indicators provided evidence for reworked, turbidite-like or homogeneous facies (event layers) in several short cores (<45 cm). Other indicators of sediment input and the historical chronicles available for the area suggest that three of these event layers likely originated from the AD 1957, 1967 and 1999 earthquakes. Recent changes in sediment deposition and nutrient levels have also been identified, but are probably not related to earthquakes. This study demonstrates that a combination of indicators can be used to recognize earthquake-related event layers in cores that encompass a longer period of time.  相似文献   

A 40 ka record of temperature and permafrost conditions in northwestern Europe from noble gases in the Ledo‐Paniselian Aquifer (Belgium)     

Petra Corinne Blaser  Rolf Kipfer  Heinz Hugo Loosli  Kristine Walraevens  Marc van Camp  Werner Aeschbach‐Hertig 《第四纪科学杂志》2010,25(6):1038-1044

The Ledo‐Paniselian Aquifer in Belgium offers unique opportunities to study periglacial groundwater recharge during the Last Glacial Maximum (LGM), as it was located close to the southern boundary of the ice sheets at that time. Groundwater residence times determined by ¹⁴C and ⁴He reveal a sequence of Holocene and Pleistocene groundwaters and a gap between about 14 and 21 ka, indicating permafrost conditions which inhibited groundwater recharge. In this paper, a dataset of noble gas measurements is used to study the climatic evolution of the region. The derived recharge temperatures indicate that soil temperatures in the periods just before and after the recharge gap were only slightly above freezing, supporting the hypothesis that permafrost caused the recharge gap. The inferred glacial cooling of 9.5°C is the largest found so far by the noble gas method. Yet, compared to other palaeoclimate reconstructions for the region, recharge temperatures deduced from noble gases for the cold periods tend to be rather high. Most likely, this is due to soil temperatures being several degrees higher than air temperatures during periods with extended snow cover. Thus the noble‐gas‐derived glacial cooling of 9.5°C is only a lower limit of the maximum cooling during the LGM. Some samples younger than the recharge gap are affected by degassing, possibly related to gas production during recharge in part of the recharge area, especially during times of melting permafrost. The findings of this study, such as the occurrence of a recharge gap and degassing related to permafrost and its melting, are significant for groundwater dynamics and geochemistry in periglacial areas. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Inland-coastal demographic transformations in a karst area:a case study of the surroundings of Krka National Park (Croatia)     

TELBISZ Tamás  RADELJAK KAUFMANN Petra  BOI Neven 《山地科学学报》2022,(2):305-321

According to geographic possibilism,environment does not determine socio-economic development.However,the environment sets certain constraints and limitations f...  相似文献