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971.
The mineralization of the active hydrothermal JADE field resembles in many aspects the Kuroko-type mineralization. The JADE field is located in a back-arc graben and is associated with a bimodal volcanism. Lead isotope data from igneous rocks, sediments, and ores further emphasize the similarities with the Kuroko ores and suggest that both sediments and volcanic rocks contributed comparable amounts of lead to the deposit. When compared to the sediments, a much larger volume of volcanic rocks must have contributed lead to the deposit, because of the considerably lower lead concentration of volcanic rocks. In contrast to the crustal type lead of the JADE field and the Kuroko-type sulfide deposits the lead isotope signatures of VMS-type deposits at mid-ocean ridges is distinctly different. In the absence of a sedimentary cover it reflects the composition of the mantle source, whereas in the presence of a sedimentary cover it is either a mixture of mantle and sedimentary lead or it may even be completely dominated by the latter. Received: 5 October 1995 / Accepted: 10 May 1996  相似文献   
972.
 Yucca Mountain, the proposed site for the high-level nuclear waste repository, is located just south of where the present water table begins a sharp rise in elevation. This large hydraulic gradient is a regional feature that extends for over 100 km. Yucca Mountain and its vicinity are underlain by faulted and fractured tuffs with hydraulic conductivities controlled by flow through the fractures. Close to and parallel with the region of large hydraulic gradient, and surrounding the core of the Timber Mountain Caldera, there is a 10- to 20-km-wide zone containing few faults and thus, most likely, few open fractures. Consequently, this zone should have a relatively low hydraulic conductivity, and this inference is supported by the available conductivity measurements in wells near the large hydraulic gradient. Also, slug injection tests indicate significantly higher pressures for fracture opening in wells located near the large hydraulic gradient compared to the opening pressures in wells further to the south, hence implying that lower extensional stresses prevail to the north with consequently fewer open fractures there. Analytical and numerical modeling shows that such a boundary between media of high and low conductivity can produce the observed, large hydraulic gradient, with the high conductivity medium having a lower elevation than the water table. Further, as fractures can close due to tectonic activity, the conductivity of the Yucca Mountain tuffs can be reduced to a value near that for the hydraulic barrier due to strain release by a moderate earthquake. Under these conditions, simulations show that the elevation of the steady-state water table could rise between 150 and 250 m at the repository site. This elevation rise is due to the projected shift in the location of the large hydraulic gradient to the south in response to a moderate earthquake, near magnitude 6, along one of the major normal faults adjacent to Yucca Mountain. As the proposed repository would only be 200–400 m above the present water table, this predicted rise in the water table indicates a potential hazard involving water intrusion. Received: 7 June 1996 / Accepted: 19 November 1996  相似文献   
973.
The time evolution of stratospheric aerosol layer formed after a volcanic eruption is studied taking into account the aerosol microphysical processes of growth, coagulation and sedimentation. Using a simple model we could explain the observed evolution of the Pinatubo volcanic layer which decayed in about 3 years. The experimental data obtained by Nd:YAG backscatter lidar over Ahmedabad further supports this finding. The data obtained after the El Chichon volcanic eruption also showed that the El Chichon aerosol layer decayed in about 3 years time. Thus, though the amount of SO2 injected has been higher, in the case of Pinatubo, about two to three times more than El Chichon, it has resulted in the production of larger aerosol particles due to faster growth and coagulation processes, and subsequently a faster removal rate, to give more or less a similar background aerosol amount at the stratosphere in about 3 years time.  相似文献   
974.
975.
Electrokinetic remediation of metal contaminated glacial tills   总被引:2,自引:0,他引:2  
This paper presents the results of an experimental investigation which studied the feasibility of using the electrokinetic process to remediate contaminated clays of glacial origin, otherwise known as glacial tills. An overview of the electrokinetic phenomena, as well as previously performed laboratory and field investigations, is first presented. The methodology of the electrokinetic experiments which were conducted to investigate the removal of metals from a glacial till is then described. A total of 16 experiments were conducted using glacial till samples obtained from a project site near Chicago. Sodium and calcium were used as the surrogate cationic metallic contaminants. These experiments demonstrated that ion transport during the electrokinetic process occurs due to both electro-osmosis and electromigration, but that due to electromigration is significantly higher than that due to electro-osmosis. Unlike other clays such as kaolinite, the glacial till used for this investigation possessed high buffering capacity because of its high carbonate content which prevented the acid front migration from the anode to the cathode during the electrokinetic process. The ion removal efficiency of the electrokinetic process was found to increase when: (1) the voltage gradient applied to the soil was increased, (2) the initial concentration of the contaminants was increased, and (3) the duration of the treatment process was increased. The ion removal efficiency was also greater for smaller ions which possess less ionic charge and when the ions existed independently in the soil as compared to when they coexisted. This investigation suggests that the electrokinetic process has significant potential for remediating glacial tills contaminated with metals. However, the properties of Na and Ca are not representative of contaminants, such as heavy metals, so further investigations are needed.  相似文献   
976.
The 1900–1700 Ma Waterberg Group in the main Waterberg fault-bounded basin consists of dominantly coarse siliciclastic red beds with minor volcanic rocks. The sedimentary rocks were deposited mainly by alluvial fans, fluvial braidplains and transgressive shallow marine environments, with lesser lacustrine and aeolian settings. Uplifted, largely granitic source areas were located along the Thabazimbi-Murchison lineament (TML) fault system in the south, and along the Palala shear zone in the northeast. Palaeoplacer titanomagnetite-ilmenite-zircon heavy mineral deposits, best developed in the Cleremont Formation in the centre of the basin, reflect initial fluvial reworking and subsequent littoral marine concentration. Coarse alluvial cassiterite placer deposits are found in the Gatkop area in the southwest of the basin, and appear to have been derived from stanniferous Bushveld Complex lithologies south of the TML. Hydrothermal zinc and U-Cu mineralisation in the Alma lithologies in the same area appears to be related to the TML fault system. Small manganese deposits and anomalous tungsten values occur in the south of the basin, where they are again closely spatially associated with the TML. Copper-barium mineralisation is found associated with dolerite dykes, and in stratigraphically controlled, inferred syngenetic settings. The most interesting of these apparently syngenetic occurrences is found within green coloured reduced mudrocks and inferred volcanic rocks, at an unconformity developed within the overall red bed sequence of the Waterberg Group, adjacent to the TML in the southwest of the basin. The most important potential mineralisation in the main Waterberg basin thus encompasses shoreline placer Ti and the possibility of substantial sediment-hosted copper deposits. Received: 31 May 1996 / Accepted: 17 February 1997  相似文献   
977.
Diffusion of tetravalent cations in zircon   总被引:18,自引:1,他引:18  
Diffusion rates for the three tetravalent cations U, Th and Hf have been measured in synthetic zircon. Diffusant sources included oxide powders and ground pre-synthesized silicates. Rutherford backscattering spectrometry (RBS) was used to measure depth profiles. Over the temperature range 1400–1650 °C, the following Arrhenius relations were obtained (diffusion coefficients in m2sec−1): log D Th = (1.936 ± 0.9820) + (− 792 ± 34 kJ mol−1 /2.303 RT) log D U = (0.212 ± 2.440) + (− 726 ± 83 kJ mol−1 /2.303 RT) log D Hf = (3.206 ± 1.592) + (− 812 ± 54 kJ mol−1 /2.303 RT) The data show a systematic increase in diffusivity with decreasing ionic radius (i.e., faster diffusion rates for Hf than for U or Th), a trend also observed in our earlier study of rare earth diffusion in zircon. Diffusive fractionation may be a factor in the Lu-Hf system given the much slower diffusion rates of tetravalent cations when compared with the trivalent rare earths. The very slow diffusion rates measured for these tetravalent cations suggest that they are essentially immobile under most geologic conditions, permitting the preservation of fine-scale chemical zoning and isotopic signatures of inherited cores. Received: 12 July 1996 / Accepted: 2 December 1996  相似文献   
978.
Effect of tunnel depth on modulus of deformation of rock mass   总被引:1,自引:2,他引:1  
Summary Deformability of rock mass significantly influences its behaviour and is, therefore, an important consideration for the design of underground openings. The modulus of deformation of rock mass is, however, normally obtained from expensive and time-consuming uniaxial jacking tests, whose results often have a large scatter. An empirical correlation has, therefore, been proposed for a quick and inexpensive preliminary estimation of the modulus of deformation of rock mass on the basis of field instrumentation carried out in tunnels in India.  相似文献   
979.
Groundwater evaporation and subsequent precipitation of soluble salts at Owens Lake in eastern California have created one of the single largest sources of airborne dust in the USA, yet the evaporation and salt flux have not been fully quantified. In this study, we compare eddy correlation, microlysimeters and solute profiling methods to determine their validity and sensitivity in playa environments. These techniques are often used to estimate evaporative losses, yet have not been critically compared at one field site to judge their relative effectiveness and accuracy. Results suggest that eddy correlation methods are the most widely applicable for the variety of conditions found on large playa lakes. Chloride profiling is shown to be highly sensitive to thermal and density-driven fluxes in the near surface and, as a result, appears to underestimate yearly groundwater evaporation. Yearly mean groundwater evaporation from the playa surface estimated from the three study areas was found to range from 88 to 104 mm year−1, whereas mean evaporation from the brine-covered areas was 872 mm year−1. Uncertainties on these mean rates were estimated to be ±25%, based on comparisons between eddy correlation and lysimeter estimates. On a yearly basis, evaporation accounts for approximately 47 × 106 m3 of water loss from the playa surface and open-water areas of the lake. Over the playa area, as much as 7.5 × 108 kg (7.5 × 105 t) of salt are annually concentrated by evaporation at or near the playa surface, much of which appears to be lost during dust storms in area.  相似文献   
980.
The varve data-set from a freeze-core taken in the deepest part of Baldeggersee was subjected to different multivariate statistical analyses in order to estimate the amount of variance in the varve thickness measures explicable by past climate and by the trophic state of the lake. A comparison of two different time-periods (1902 to1992 versus 1920 to 1980) revealed that the lake restoration programme since 1982 has had a significant impact on the formation of the seasonal layers. Results of the partitioning of the variance in the varve thickness measures showed that about two thirds of the variance are unexplained by a climate and trophic state model and that trophic state explains 6%, whereas climate accounts for about 28% of the variance before the effect of lake restoration had a strong impact on the varves. Among the climate parameters the amount of annual precipitation is a strong predictor for explaining the thickness of both dark layer and total couplet thickness, whereas summer precipitation is important for the thickness of the light layer.  相似文献   
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