环境和生物样品中痕量双酚A的分析方法     

王晓春  刘晓端  杨永亮  李刚  徐清  焦杏春  罗松光  李奇 《岩矿测试》2009,28(6):557-568

作为环境类内分泌干扰物之一,双酚A由于被广泛作为化工原料使用而对环境和人类健康产生了严重的危害。文章对近年来国内外环境及生物样品中残留双酚A的最新前处理及检测技术的研究进展进行了综述。除常规前处理技术外,还介绍了包括搅拌棒吸附萃取及分子印迹等新型分离、富集技术在双酚A提取中的应用;另外,在着重介绍双酚A的色谱-质谱分析技术的基础上,对免疫分析、传感器检测和光学检测在双酚A检测中的应用也进行了详细报道。展望双酚A分析的发展趋势,二级串联质谱由于具有比其他分析方法更低的检出限,因此将会成为检测环境及生物样品中痕量双酚A的最具潜力的手段之一;研制价格低廉、重现性好、高通量的微型化、便携式、自动化仪器将是在线快速分析双酚A的另一个主要发展方向。  相似文献   

浮基多体系统自激运动响应的时域分析方法   总被引：2，自引：2，他引：2  

沈庆  陈徐均等 《海洋工程》2002,20(2):7-13

浮基多体系统上部机构作业时不仅存在多体系统内部各物体间的耦合作用 ,还存在浮基与流场间的耦合作用。本文将浮基在流场中引起的辐射势表示为浮基加速度与时域规范化速度势乘积的卷积形式 ,导出流体动压力及静水系泊恢复力与浮基运动的关系。使用多刚体力学的凯恩方法得到系统的动力学方程。最后给出了在时域中数值求解系统运动响应的具体步骤  相似文献   

大气环境卫星温室气体和气溶胶协同观测综述   总被引：1，自引：0，他引：1  

李正强  谢一凇  石玉胜  厉青  Cohen Jason  张羽中  韩颖慧  熊伟  刘毅 《遥感学报》2022,26(5):795-816

人类排放的温室气体和气溶胶是造成全球气候变暖和大气环境恶化的主要因素,也是大气环境卫星遥感的核心探测目标。与传统的单一探测目标卫星相比,实现同平台的大气温室气体和气溶胶协同监测,对于提高温室气体卫星反演精度、改善“自上而下”碳源汇估算、提升温室气体和气溶胶的人为/自然源区分能力具有重要意义,也是各国航天机构积极发展的空间探测手段。本文对欧、日、中、美等具备温室气体和气溶胶协同监测能力的卫星进行系统的介绍,包括卫星平台、传感器、处理算法和质控验证。按照卫星监测任务和传感器用途,将其分为大气综合探测卫星和温室气体监测卫星两大类,并从碳中和行动和大气环境综合治理等需求出发,提出温室气体和气溶胶协同观测星座（GACOC）的概念及其发展方向,包括主被动卫星组网观测、温室气体和气溶胶高精度联合反演算法、人为排放源识别和定量监测等应用。  相似文献   

MERSI和MODIS卫星监测京津冀及周边地区PM_2.5浓度   总被引：1，自引：0，他引：1  

陈辉  厉青  王中挺  孙云  毛慧琴  程斌 《遥感学报》2018,22(5):822-832

京津冀及周边地区是中国PM_(2.5)污染最重的区域之一,利用卫星遥感技术监测大范围的PM_(2.5)时空分布变化是一种先进的重要手段。本研究首先基于暗像元算法利用FY-3B/MERSI与AQUA/MODIS对京津冀及周边区域进行了遥感AOT反演和验证分析;然后,引入气象资料和地面观测资料利用GWR模型反演了区域PM_(2.5)浓度,并对遥感反演结果进行了交叉验证评估,综合对比分析了MERSI和MODIS的气溶胶及PM_(2.5)遥感监测能力;最后,利用MERSI数据对2017年第一季度京津冀及周边区域的PM_(2.5)月均浓度时空分布变化情况进行了初步探索分析。结果表明:FY-3B/MERSI在气溶胶及PM_(2.5)遥感监测能力方面略优于AQUA/MODIS,MERSI反演的1 km分辨率AOT和PM_(2.5)与地面站点实测结果的决定系数R2分别为0.76μg/m~3和0.79μg/m~3,均方根误差分别为0.26μg/m~3和28μg/m~3,平均绝对误差分别为0.16μg/m~3和15μg/m~3,能基本满足对京津冀及周边区域PM_(2.5)的精细化监测需要。2017年第一季度京津冀及周边区域PM_(2.5)月均浓度遥感监测结果表明该区域的PM_(2.5)空间分布格局与地形地貌关系密切,高值区整体上沿太行山脉成带成片;从时间变化来看,1—3月呈逐月下降的趋势,其中3月份PM_(2.5)区域浓度较1月和2月有大幅下降。这说明FY-3\MERSI遥感反演产品能为环境质量监测和环境管理工作效果评估提供有效参考,本研究对国产卫星在大气环境遥感业务中的大力发展应用有重要参考意义。  相似文献   

多尺度字典学习的高光谱图像压缩算法     

徐大卫  张荣  吴倩 《遥感学报》2015,19(2):263-272

结合小波变换及字典学习提出了一种针对高光谱图像的压缩算法。该算法首先通过小波变换构建多尺度样本集,在小波域使用K-均值奇异值分解(K-SVD)方法学习得到原子尺寸不同的多尺度字典,然后在稀疏表示的过程中,定义一个原子使用频次筛选因子,通过统计局部最优波段稀疏表示时原子使用情况,结合筛选因子对字典原子进行优化筛选,使用精简后的字典对其余波段进行稀疏求解,最后针对不同尺度的表示系数采用自适应的量化编码。实验结果表明,与目前常用的3D-SPIHT和其他的多尺度字典学习算法相比,本文算法在中低比特率下,具有更好的重建性能。  相似文献   

结合边缘编组的Hough变换直线提取   总被引：3，自引：0，他引：3  

王竞雪  朱庆  王伟玺  赵丽科 《遥感学报》2014,18(2):378-389

针对传统Hough变换用于直线检测存在的问题进行了细致的分析和归纳总结,在此基础上,提出一种结合边缘编组的Hough变换直线提取算法。该算法首先采用基于8邻域的边缘跟踪算法对Canny算子检测得到的边缘点进行编组;然后对每一个边缘组分别进行Hough变换,单独确定Hough变换原点和参数的取值范围。Hough变换过程中,采用迭代的"投票"方式,每次确定单一峰值点并删除对应像素。实验证明,该算法原理简单,能有效解决传统Hough变换存在的精度不高、计算复杂等问题。同时该算法具有较强的鲁棒性,可以有效处理不同类型的影像数据,适用于并行处理。  相似文献   

面向智慧旅游的游客数据库设计与实现     

杨攀  朱庆  张骏骁  曹振宇 《测绘》2016,(4):164-168,175

游客数据是智慧旅游的关键基础数据,本文深入分析了游客个性化的智慧旅游需求特点,归纳凝练了游客的偏好和交互等信息,设计了一种实用的游客数据库结构,支持相关动态信息的实时接入与动态更新,开发了典型智慧旅游原型系统,并实验验证了游客数据库的有效性。  相似文献   

Discovery of six high-redshift quasars with the Lijiang 2.4 m telescope and the Multiple Mirror Telescope     

Xue-Bing Wu  Wen-Wen Zuo  Qian Yang  Wei-Min Yi  Chen-Wei Yang  Wen-Juan Liu  Peng Jiang  Xin-Wen Shu  and Hong-Yan Zhou 《天文和天体物理学研究(英文版)》2012,(9):1185-1190

Quasars with redshifts greater than 4 are rare, and can be used to probe the structure and evolution of the early universe. Here we report the discovery of six new quasars with i-band magnitudes brighter than 19.5 and redshifts between 2.4 and 4.6 from spectroscopy with the Yunnan Faint Object Spectrograph and Camera (YFOSC) at the Lijiang 2.4 m telescope in February, 2012. These quasars are in the list of z > 3.6 quasar candidates selected by using our proposed J K/i Y criterion and the photometric redshift estimations from the SDSS optical and UKIDSS near-IR photometric data. Nine candidates were observed by YFOSC, and five among six new quasars were identified as z > 3.6 quasars. One of the other three objects was identified as a star and the other two were unidentified due to the lower signal-to-noise ratio of their spectra. This is the first time that z > 4 quasars have been discovered using a telescope in China. Thanks to the Chinese Telescope Access Program (TAP), the redshift of 4.6 for one of these quasars was confirmed by the Multiple Mirror Telescope (MMT) Red Channel spectroscopy. The continuum and emission line properties of these six quasars, as well as their central black hole masses and Eddington ratios, were obtained.  相似文献   

Mg isotopic heterogeneity,Al‐Mg isochrons,and canonical 26Al/27Al in the early solar system     

G. J. WASSERBURG  Josh WIMPENNY  Qing‐Zhu YIN 《Meteoritics & planetary science》2012,47(12):1980-1997

There is variability in the Mg isotopic composition that is a reflection of the widespread heterogeneity in the isotopic composition of the elements in the solar system at approximately 100 ppm. Measurements on a single calcium‐aluminum‐rich inclusion (CAI) gave a good correlation of ²⁶Mg/²⁴Mg with ²⁷Al/²⁴Mg, yielding an isochron corresponding to an initial (²⁶Al/²⁷Al)_o = (5.27 ± 0.18) × 10^?5 and an initial (²⁶Mg/²⁴Mg)_o = ?0.127 ± 0.032‰ relative to the standard. This isochron is parallel to that obtained by Jacobsen et al. (2008) , but is distinctively offset. This demonstrates that there are different initial Mg isotopic compositions in different samples with the same ²⁶Al/²⁷Al. No inference about uniformity/heterogeneity of ²⁶Al/²⁷Al on a macro scale can be based on the initial (²⁶Mg/²⁴Mg)_o values. Different values of ²⁶Al/²⁷Al for samples representing the same point in time would prove heterogeneity of ²⁶Al/²⁷Al. The important issue is whether the bulk solar inventory of ²⁶Al/²⁷Al was approximately 5 × 10^?5 at some point in the early solar system. We discuss ultra refractory phases of solar type oxygen isotope composition with ²⁶Al/²⁷Al from approximately 5 × 10^?5 to below 0.2 × 10^?5. We argue that the real issues are: intrinsic heterogeneity in the parent cloud; mechanism and timing for the later production of ¹⁶O‐poor material; and the relationship to earlier formed ¹⁶O‐rich material in the disk. ²⁶Al‐free refractories can be produced at a later time by late infall, if there is an adequate heat source, or from original heterogeneities in the placental molecular cloud from which the solar system formed.  相似文献   

Investigation of the correlation between morphology and luminosity for two classes of main galaxies     

Xin-Fa Deng  Xiao-Xia Qian  Cheng-Hong Luo  Ping Wu 《Astrophysics》2012,55(1):45-52

Using an apparent-magnitude limited Main galaxy sample of the Sloan Digital Sky Survey Data Release 7(SDSS DR7), we investigate the correlation between morphologies and luminosity for the Main galaxy sample. Our Main galaxy sample is divided into two classes: Main galaxies only with TARGET_GALAXY flag (bestPrimtarget = 64), and ones also with other flags. It is found that for the second class Main galaxies, the early-type proportion monotonously increases with increasing luminosity nearly in the whole luminosity region. But for the first class Main galaxies, the early-type proportion increases with increasing luminosity only within a certain luminosity region (−22.2 < M _r  < −19.8). In the high luminosity region (M _r  < −22.2), the early-type proportion of the first class Main galaxies even decreases dramatically with increasing luminosity. We also analyze the correlation between morphologies and luminosity of galaxies around the peak of the redshift distribution ( 0.07 ≤ z ≤ 0.08 ). In such a narrow redshift region, we still observe strong correlation between morphologies and luminosity, which shows that this correlation is fundamental.  相似文献