Impact of sediment organic matter quality on the fate and effects of fluoranthene in the infaunal brittle star Amphiura filiformis     

Selck H  Granberg ME  Forbes VE 《Marine environmental research》2005,59(1):19-45

Hydrophobic contaminants, such as polycyclic aromatic hydrocarbons (PAHs) readily adsorb to organic matter. The aim of this study was to determine the importance of the quality of sedimentary organic matter for the uptake, biotransformation and toxicity of the PAH, fluoranthene (Flu), in the infaunal brittle star Amphiura filiformis. Brittle stars were exposed to a base sediment covered by a 2 cm Flu-spiked top layer (30 microg Flu/g dry wt. sed.), enriched to the same total organic carbon content with either refractory or labile organic matter. The labile carbon source was concentrated green flagellate: Tetraselmis spp. The refractory carbon source was lignin from a paper mill. Tissue concentrations of Flu both in disk and arm-fractions were determined as total Flu, parent Flu (i.e. untransformed), aqueous Flu-metabolites, polar Flu-metabolites and tissue residue Flu (i.e. unextractable). Our results showed that sediment particle ingestion is a pathway by which Flu can enter benthic food webs. Flu toxicity (measured as arm-regeneration), but not net accumulation, was dependent on the nutritional quality of the ingested sediment particles. Flu bioaccumulation could not be attributed solely to equilibrium partitioning between organism lipid content and organic content of the sediment. Biotransformation of Flu by brittle stars was very limited and unaffected by organic matter quality. A. filiformis contributed to the downward transport of Flu from the surface sediment to the burrow lining. The limited breakdown of parent Flu by brittle stars and/or microorganisms was relatively higher in burrows compared to surface sediment, and highest in the presence of labile organic matter. Tissue concentrations were higher in disk than in arms, but the proportion of metabolic products relative to parent Flu was higher in arms than in the disk fraction. We estimate that the yearly mobilization of sediment-associated Flu by arm-regeneration in A. filiformis is in the range of 3.8-29.4 microg total Flu eq. m(-2) year(-1) at a sediment concentration of 30 microg Flu/g dry wt. sed.  相似文献   

Assessing degradation capability of aerobic indigenous microflora in PAH-contaminated brackish sediments     

Abbondanzi F  Campisi T  Focanti M  Guerra R  Iacondini A 《Marine environmental research》2005,59(5):419-434

A study was conducted to determine polycyclic aromatic hydrocarbons (PAHs) distribution and microbial population changes in brackish sediments from an Italian lagoon included in the Ramsar List of Wetlands of International Importance. The presence and level of PAH-degrading bacteria were estimated by the most probable number (MPN) enumeration technique, whereas degradation capability towards target compounds was checked against loss of spiked PAHs (Phenanthrene, Anthracene and Fluoranthene) in MPN tubes after incubation in optimal conditions. Chemical analyses and microbiological counts suggested a potential for PAHs biodegradation by natural occurring populations of sediment microorganisms, thus indicating an "optimal range" in sediment PAHs concentrations, outside of which the natural selection of the indigenous microflora did not occur. The MPN procedure here described, provided an effective and reliable way to simultaneously determine microbial population densities and subsequent confirmation of the biodegradation capability of sediment indigenous microflora when exposed to laboratory and environmental concentrations of PAHs.  相似文献   

Measuring and modelling temporal trends of 226Ra in waters of a Spanish estuary affected by the phosphate industry     

Periáñez R 《Marine environmental research》2005,60(1):35-49

The presence and temporal evolution (1990-2001) of (226)Ra in a tidal estuary affected by the phosphate industry has been investigated. Water samples collected in the course of four separate sampling campaigns were analysed for (226)Ra content using a gas flow proportional counter following Ba coprecipitation. Two (226)Ra sources have been identified: direct discharges from the industrial complex and run-off from a phosphogypsum pile. Although activity levels are similar, or even higher, than those found in other environments affected by the phosphate industry, there has been a general decrease in contamination since direct discharges ceased in 1998 due to new regulations from the EU. However, sediments are now acting as a source of Ra to the water column due to redissolution processes. A numerical model of the estuary has been developed to describe quantitatively the experimental results. The model solves the hydrodynamics and the dispersion equation of (226)Ra including interactions with sediments. Model results are, in general, in good agreement with observations.  相似文献   

Measurement of stress effects (scope for growth) and contaminant levels in mussels (Mytilus edulis) collected from the Irish Sea     

Widdows J  Donkin P  Staff FJ  Matthiessen P  Law RJ  Allen YT  Thain JE  Allchin CR  Jones BR 《Marine environmental research》2002,53(4):327-356

The objective of this research was to quantify the impact of pollution along the coastlines of the Irish Sea. Pollution assessment was based on the combined measurement of scope for growth (SFG), and chemical contaminants in the tissues of mussels (Mytilus edulis) collected from 38 coastal sites around the Irish Sea during June-July in 1996 and 1997. On the UK mainland coast, the SFG showed a general trend with a significant decline in water quality in the Liverpool and Morecambe Bay region. High water quality was recorded along the west coast of Wales, as well as southwest England and northwest Scotland (clean reference sites outside the Irish Sea). Along the coast of Ireland there was a similar trend with reduced SFG within the Irish Sea region. SFG was generally low north of Duncannon and then improved north of Belfast. The poor water quality on both sides of the Irish Sea is consistent with the prevailing hydrodynamics and the spatial distribution of contaminants associated with urban/ industrial development. The decline in SFG of mussels on both sides of the Irish Sea was associated with a general increase in contaminant levels in the mussels. Certain contaminants, including PAHs, TBT, sigmaDDT, Dieldrin, gamma-HCH, PCBs, and a few of the metals (Cd, Se, Ag, Pb), showed elevated concentrations. Many of these contaminants were particularly elevated in the coastal margins of Liverpool Bay, Morecambe Bay and Dublin Bay. A quantitative toxicological interpretation (QTI) of the combined tissue residue chemistry and SFG measurements indicated that at the majority of coastal sites, c. 50 to > 80% of the observed decline in SFG was due to PAHs as a result of fossil fuel combustion and oil spills. TBT levels were highest at major ports and harbours, but these concentrations only made a minor contribution to the overall reduction in SFG. At no sites were individual metals accumulated to concentrations that could cause a significant effect on SFG. The study identified many sites where the observed reduction in SFG was far greater than predicted from the limited number of chemical contaminants analysed, thus indicating the presence of additional 'unknown toxicants'. Sewage (containing domestic, agricultural and industrial components) appears to be an important contributor to reduced SFG and linear alkylbenzenes (LABs) and As may provide suitable 'sewage markers'. There was a highly significant positive correlation between SFG and As (P < 0.001). This relationship may be due to reduced As uptake by algal food material and mussels at sites with elevated P04 concentrations (e.g. at sites with sewage inputs). Phosphate is a known competitive inhibitor of As accumulation, at least in algae. The results highlight that further research is required on 'sewage markers' in mussels. The SFG approach therefore provides a rapid, cost-effective and quantitative measure of pollution impact, as well as a means of identifying the causes through a QTI of tissue contaminants levels. It also serves to identify the presence of unidentified toxicants and areas that require further study.  相似文献   

Anthropogenic trace metals in sediment and settling particulate matter on a high-energy continental shelf (Sydney,Australia)     

Matthai C  Birch GF  Bickford GP 《Marine environmental research》2002,54(2):99-127

The anthropogenic contribution of trace metals to settling particulate matter (SPM) and surficial sediments was determined on the high-energy continental shelf adjacent to Sydney, Australia. Settling particulate matter and surficial sediment was collected in the vicinity of a major sewage outfall and at five control sites on the middle shelf (80-100 m water depth). Sediment traps were deployed on 10 occasions for up to 2 weeks during the summer and winter of 1995 and SPM was analyzed for Ag, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn. Cobalt, Fe, Mn and Ni act conservatively in SPM and in sediments regionally and are used as normalizing elements to determine anthropogenic enrichment. Surficial sediments and SPM are enriched in Ag, Cr, Cu, Pb and Zn near a major ocean outfall and at four of the five control sites, although sewage particles contribute < 5% of trace metals in the total sample. Silver is the most sensitive trace metal tracer for establishing the presence of sewage particulate matter. Sewage particulate matter flux near the outfall was estimated using a two end-member mixing model and is below 0.5 g m(-2) day(-1) during all deployment periods. The mean sewage particulate matter flux at sampling locations 30 km and 60 km north of the outfall are <0.13 g m(-2) day(-1) and <0.01 g m(-2) day(-1), respectively, indicating an efficient dispersal of anthropogenic material on this high energy continental shelf.  相似文献   

Patterns of heritability of decreased EROD activity and resistance to PCB 126-induced teratogenesis in laboratory-reared offspring of killifish (Fundulus heteroclitus) from a creosote-contaminated site in the Elizabeth River,VA, USA     

Meyer J  Di Giulio R 《Marine environmental research》2002,54(3-5):621-626

Killifish (Fundulus heteroclitus) from a highly contaminated site on the Elizabeth River are resistant to the acute toxicity and the cytochrome P4501A (CYP1A)-inducing activity of both the sediments from the site and chemically pure polycyclic aromatic hydrocarbons (PAHs). These effects are highly heritable for one generation, but heritable to a lesser degree by subsequent generations, in clean conditions in the laboratory. We show that offspring of this population of Elizabeth River killifish are also resistant to the teratogenicity and P4501A-inducing activity of PCB congener 126, a prototypical coplanar halogenated aromatic hydrocarbon (HAH). Furthermore, the pattern of greater resistance to acute toxicity and P4501A-inducing activity in the first generation and less in subsequent generations is also observed upon exposure to PCB-126.  相似文献   

1985年空间海洋学的状况和展望     

D.J.贝克  倪振荣 《海洋开发与管理》1986,(3)

1984年海洋学工程的主要措施是在空间建立海洋观察站。新的海军遥控海洋测向系统卫星(NROSS)和欧洲空间站的地球资源卫星(ERS—Ⅰ)已得到政府的批准,列入了预算项目,开展了利用卫星调查内容的计划和操作运行的计划。NROSS 的传感器有用于风的 NASA(国家航空和航天局)的传播计量器;用于水面温度,冰的性质和海冰边端的微波无线  相似文献   

大西洋中脊的热液矿泉     

R．P.VonHerzen 《海洋地质前沿》1997,(2)

在过去10年中，通过国际合作，对大西洋中肯的热液矿泉及周围地质背景进行了研究。TAG热液矿泉位于26°N，45°W，距大西洋中脊轴数公里，它是世界卜已发现的最大热液矿泉之一．这个活动的热泉位于一直径为10m的烟囱上，该烟囱位于一直径为150－200m、高40m的椭圆形硫化矿山上．在这个硫化矿山附近几公里范围内还发现了几个不活动的热泉。TAG靠近两条转换断层之间的大西洋中脊．区域重力调查表明，TAG北部的剪切带在向北漂移．分析TAG海底玄武岩表明，源岩在10－15km深处．从旁侧声纳资料看出，TAG由两个复杂的烟囱组成．近海底地球…  相似文献   

LARGE-SCALE CIRCULATION CONDITIONS AFFECTING THE HURRICANE FORMATION OVER THE NORTH ATLANTIC OCEAN     

丁一汇  ELMAR R. REITER 《海洋学报(英文版)》1985,4(1):21-34

A contrasting study of the large-scale circulation features responsible for months or seasons with many hurricanes and those with few hurricanes has revealed that the frequency of hurricane formation over the North Atlantic Ocean is enhanced by the following conditions:There exists a well-developed subtropical high-pressure belt displaced to the north; a deep Icelandic low; a stronger-than-normal polar vortex with a deep polar trough dipping far southward along the eastern part of the United States; a dominant high-pressure ridge over western Canada and the United States; and a jet stream displaced northward over these regions. At 200 hPa, an anomalous anticyclonic circulation prevails over the subtropical North Atlantic. A stronger-than-normal upper easterly flow prevails. Positive sea surface temperature anomalies prevailing on a seasonal or long-term basis tend to be favorable for the formation of hurricanes.  相似文献   

全新世长江水下三角洲浅层物探资料的地质意义   总被引：5，自引：2，他引：5  

黄慧珍  沈邦培  胡强生 《海洋地质与第四纪地质》1985,(4)

近年来,随着海区第四纪地质研究的深入,为开展全新世长江水下三角洲沉积模式的研究,我局在西起长江沿岸、东至124°E,北起 32°N、南至30°10′N的四万平方公里测区内进行了3000公里的测深和浅地层剖面测量工作.浅地层剖面调查采用EG＆G公司的地层剖面系统.大量浅地层剖面结合浅钻进行的地质解释,提供了该三角洲研究中重要地质问题的依据和佐证.加强了海区浅部地层划分、厚度变化、区域分布规律,和浅部地层不稳定性的研究.一、地震反射层序的划分及其特征(一)层组的划分:沉积过程中由于岩层的密度、速度差异,沉积物内出现了声学层面和不整合面的两种物性波阻抗界面.浅地层剖面利用声波在海水和海底沉积物中的传播和界面上的反射,根据声波到达海底和各个界面的传播时间及其在地层中的速度来研究海底沉积层.根据这个原理可以按以下原则划分浅地层剖面:  相似文献