Xenon isotope systematics, giant impacts, and mantle degassing on the early Earth     

Robert O. Pepin  Don Porcelli   《Earth and Planetary Science Letters》2006,250(3-4):470-485

The relationships between the major terrestrial volatile reservoirs are explored by resolving the different components in the Xe isotope signatures displayed by Harding County and Caroline CO₂ well gases and mid-ocean ridge basalts (MORB). For the nonradiogenic isotopes, there is evidence for the presence of components enhanced in the light ^124–128Xe/¹³⁰Xe isotope ratios with respect to the terrestrial atmosphere. The observation of small but significant elevations of these ratios in the MORB and well gas reservoirs means that the nonradiogenic Xe in the atmosphere cannot be the primordial base composition in the mantle. The presence of solar-like components, for example U–Xe, solar wind Xe, or both, is required.For radiogenic Xe generated by decay of short-lived ¹²⁹I and ²⁴⁴Pu, the ¹²⁹Xe_rad/¹³⁶Xe₂₄₄ ratios are indistinguishable in MORB and the present atmosphere, but differ by approximately an order of magnitude between the MORB and well gas sources. Correspondence of these ratios in MORB and the atmosphere within the relatively small uncertainties found here significantly constrains possible mantle degassing scenarios. The widely held view that substantial early degassing of ¹²⁹Xe_rad and ¹³⁶Xe₂₄₄ from the MORB reservoir to the atmosphere occurred and then ended while ¹²⁹I was still alive is incompatible with equal ratios, and so is not a possible explanation for observed elevations of ¹²⁹Xe/¹³⁰Xe in MORB compared to the atmosphere. Detailed degassing chronologies constructed from the isotopic composition of MORB Xe are therefore questionable.If the present estimate for the uranium/iodine ratio in the bulk silicate Earth (BSE) is taken to apply to all interior volatile reservoirs, the differing ¹²⁹Xe_rad/¹³⁶Xe₂₄₄ ratios in MORB and the well gases point to two episodes of major mantle degassing, presumably driven by giant impacts, respectively  20–50 Ma and  95–100 Ma after solar system origin assuming current values for initial ¹²⁹I/¹²⁷I and ²⁴⁴Pu/²³⁸U. The earlier time range, for degassing of the well gas source, spans Hf–W calculations for the timing of a moon-forming impact. The second, later impact further outgassed the upper mantle and MORB source. A single event that degassed both the MORB and gas well reservoirs at the time of the moon-forming collision would be compatible with their distinct ¹²⁹Xe_rad/¹³⁶Xe₂₄₄ ratios only if the post-impact iodine abundance in the MORB reservoir was about an order of magnitude lower than current estimates. In either case, such late dates require large early losses of noble gases, so that initial inventories acquired throughout the Earth must have been substantially higher.The much larger ¹²⁹Xe_rad/¹³⁶Xe₂₄₄ ratio in the well gases compared to MORB requires that these two Xe components evolve from separate interior reservoirs that have been effectively isolated from each other for most of the age of the planet, but are now seen within the upper mantle. These reservoirs have maintained distinct Xe isotope signatures despite having similar Ne isotope compositions that reflect similar degassing histories. This suggests that the light noble gas and radiogenic Xe isotopes are decoupled, with separate long-term storage of the latter. However, without data on the extent of heterogeneities within the upper mantle, this conclusion cannot be easily reconciled with geophysical observations without significant re-evaluation of present noble gas models. Nevertheless the analytic evidence that two different values of ¹²⁹Xe_rad/¹³⁶Xe₂₄₄ exist in the Earth appears firm. If the uranium/iodine ratio is approximately uniform throughout the BSE, it follows that degassing events from separate reservoirs at different times are recorded in the currently available terrestrial Xe data.  相似文献