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991.
992.
采用平均离子强度下30年雨量的模拟酸雨淋滤珠江三角洲潮土,电感耦合等离子体质谱法测定重金属元素,研究潮土0~90 cm处各节土壤柱中重金属镉、钴、铜、锌、铅、砷、钛、钒、铬、锰等元素的释放情况。研究表明,在高强度模拟酸雨淋滤下,潮土中重金属元素的释放情况存在较大差异。长期的酸雨淋滤,土壤中的镉、钴、铜、锌和铅在不同深度均有不同程度的淋失;砷、钛、钒、铬、锰等元素不会造成大量的淋失。利用这种差异可以评估重金属元素对环境的潜在影响,为农田生态系统的预警预测提供依据。 相似文献
993.
Juraj Majzlan Peter Glasnák Robert A. Fisher Mary Anne White Michel B. Johnson Brian Woodfield Juliana Boerio-Goates 《Physics and Chemistry of Minerals》2010,37(9):635-651
Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C
p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe3(SO4)2(OH)6, where A = K, Na, Rb, and NH4. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred
to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:
There are additional configurational entropies of 13.14 and 8.23 J mol−1 K−1 in defect and NH4-jarosite, respectively. A detailed analysis of the synchrotron X-ray diffraction patterns showed a large anisotropic peak
broadening for defect and NH4-jarosite. The fits to the low-temperature (approx. <12 K) C
p data showed that our samples can be divided into two groups. The first group is populated by the K-, Na-, Rb-, and NH4-jarosite samples, antiferromagnetic at low temperatures. The second group contains the H3O-jarosite (studied previously) and the defect jarosite. H3O- and defect jarosite are spin glasses and their low-T
C
p was fit with the expression C
p = γT + ΣB
j
T
j
, where j = (3, 5, 7, 9). The linear term is typical for spin glasses and the sum represents the lattice contribution to C
p. Surprisingly, the C
p of the K-, Na-, Rb-, and NH4-jarosite samples, which are usually considered to be antiferromagnetic at low temperatures, also contains a large linear
term. This finding suggests that even these phases do not order completely, but have a partial spin-glass character below
their Néel transition temperature. 相似文献
Sample | Chemical composition | S o/(J mol−1 K−1) |
---|---|---|
K-jarosite | K0.92(H3O)0.08Fe2.97(SO4)2(OH)5.90(H2O)0.10 | 427.4 ± 0.7 |
Na-jarosite | Na0.95(H3O)0.05Fe3.00(SO4)2(OH)6.00 | 436.4 ± 4.4 |
Rb-jarosite | RbFe2.98(SO4)2(OH)5.95(H2O)0.05 | 411.9 ± 4.1 |
NH4-jarosite | (NH4)0.87(H3O)0.13Fe3.00(SO4)2(OH)6.00 | 447.2 ± 4.5 |
Defect jarosite | K0.94(H3O)0.06Fe2.34(SO4)2(OH)4.01(H2O)1.99 | 412.7 ± 4.1 |
994.
995.
辉长岩大多为地幔岩石部分熔融的产物,辉绿岩脉及碱性正长岩的形成通常与伸展构造有关,本文对海南岛万宁辉长岩及辉绿岩脉和分界洲正长岩进行了系统的年代学和岩石地球化学研究,并以此来讨论其构造意义。LA-ICP-MS锆石U-Pb定年结果表明,万宁辉长岩及辉绿岩脉形成约在240 Ma,分界洲正长岩形成约在231 Ma,主量元素特征表明万宁辉长岩和辉绿岩分别属碱性系列和亚碱性系列,分界洲正长岩属于典型的碱性岩浆岩。万宁辉长岩及辉绿岩脉的稀土元素具有轻稀土富集的特点(LREE/HREE=7.22~8.50和8.11~11.10),微量元素具有岛弧型火山岩的特征,富集大离子亲石元素K、Rb、Ba、Th,贫高场强元素Nb、Ta和Zr、Hf;分界洲正长岩的微量元素特征显示出与A型花岗岩类似的特征。海南岛三叠纪中基性岩如分界洲正长岩和万宁辉长岩及辉绿岩脉形成的构造背景为陆内伸展环境,指示海南岛在240~230 Ma处于印支造山运动的应力松弛阶段。 相似文献
996.
Reduction of surface subsidence risk by fly ash exploitation as filling material in deep mining areas 总被引:1,自引:1,他引:0
The possibility of filling empty underground spaces, which exist owing to the extraction of mineral raw materials, with fly
ash and cement fly ash mixes has been studied for the purpose of reducing the impact of deep mining on the surface. The method
of physical modelling was used to study the behaviour of fly ash mixes deposited in extracted mine spaces. The models were
constructed for two different geometries of underground extracted mine spaces: into cavities of the type of large slits created
in the course of mining in steeply lode deposits without subsequently filling the empty space and in vertical shafts of rectangular
or circular cross-section with horizontal side headings that have partly caved in due to mine shocks or other seismic events. 相似文献
997.
998.
M. Villalobos D. G. García-Payne J. L. López-Zepeda A. E. Ceniceros-Gómez M. E. Gutiérrez-Ruiz 《Aquatic Geochemistry》2010,16(2):225-250
Arsenic from natural and anthropogenic sources is a worldwide contaminant of aqueous environments, such as groundwater and
soils. The present investigation was performed on Mexican soils contaminated with residues from metallurgical processes that
have shown a natural As attenuation. Experimental aqueous arsenic extractions in these were successfully simulated for almost
half of the soil samples using a database updated for all known metal arsenate formation constants, revealing the predominance
of solubility-controlled As mobility via Pb, mixed Pb–Cu, and Ca arsenate solid formation. The relatively low total Fe/As
ratios (2–13 w/w) present in the soils studied, together with the high and equivalent contents of As, Pb, and Cu in these,
favor the precipitation process over As(V) adsorption to Fe oxides, despite a 2% average Fe content in the soils studied.
Under these conditions bicarbonate was found to be a highly unsuitable extractant due to its indirect As release from the
solid arsenates, via heavy metal carbonate precipitation processes. 相似文献
999.
Linking geomorphology and hydrodynamics: a case study from Península Valdés, Patagonia, Argentina 总被引:1,自引:0,他引:1
A case study is presented to assess the relevance of geomorphology in hydrogeological phenomena in an arid coastal area in the Argentinean extra-Andean Patagonia (Península Valdés) with an average rainfall of 232 mm/year and a soil moisture deficit of about 472 mm/year. Various geomorphic units were identified by interpreting Landsat 7 satellite images processed with ER Mapper software and then surveyed in the field, as well as by geological characterization. The hydrodynamic analysis was based on a survey of 89 wells, the construction of equipotential maps, and the interpretation of pumping-test results by a non-equilibrium method. The hydrochemical characterization was based on chemical tests analyzed with the Easy_Quim 6.0 application. The combination of geomorphological, geological, hydrodynamic and hydrochemical elements allowed the definition of hydromorphological units that are typical of recharge, circulation and discharge areas, the latter both for coastal and inland areas in wetlands (salt pans) with elevations to ?40 m relative to sea level. These units and the criteria used for their definition allow immediate recognition of hydrogeological phenomena in arid regions such as the extra-Andean Patagonia, with low information density but with near-optimal satellite imaging of landforms due to the lack of vegetation cover. 相似文献
1000.
The southeast area of the Argentine Pampas is characterized by the presence of an unconfined aquifer in a wide plain. A methodology is proposed that deals with the aquifer vulnerability where the homogeneity of the hydrogeological variables used by traditional methods (in this case, DRASTIC-P) causes vulnerability maps to show more than 80% of the territory under the same class. This absence of discrimination renders vulnerability maps of little use to decision-makers. In addition, the proposed methodology avoids the traditional vague classification (high, low, and moderate vulnerability) which is highly dependent on subjectivity in its association of each class with hydrogeological considerations. That traditional vulnerability assessment methodology was adapted using a geographic information system to reclassify classes, based on the Natural Breaks (Jenks) method. The pixel-to-pixel comparison between the result obtained by the DRASTIC-P and the reclassified classes generates the so-called operational vulnerability index (OVI), which shows four classes, associating each with different hydrogeological requirements to make decisions. 相似文献