Anion chemistry on Titan: A possible route to large N-bearing hydrocarbons     

Ján Žabka  Claire Romanzin  Christian Alcaraz  Miroslav Polášek 《Icarus》2012,219(1):161-167

The reaction of CN^? with cyanoacetylene (HC₃N), has been studied as a function of the HC₃N pressure in a quadrupole tandem mass spectrometer. The mass spectra revealed the fast depletion of the CN^? parent ion and formation of larger anions of rapidly growing size. Most of the ions observed were found to belong to two series of products: (HC₃N)_x·C_2p+1N^? and (HC₃N)_x·C_2pN^? resulting from the sequential additions of HC₃N molecules and loss of HCN or HCCN molecules. The mechanism and energetics of the first two reaction steps are briefly discussed. The laboratory data are compared with those from the Cassini CAPS-ELS spectrometer. It is believed that the reactions observed could account for the growth of anions in Titan’s ionosphere.  相似文献   

Groundwater Quality in the Yucatan Peninsula: Insights from Stable Isotope and Metals Analysis     

F. Arcega-Cabrera  J. O. Sickman  L. Fargher  J. Herrera-Silveira  D. Lucero  I. Oceguera-Vargas  E. Lamas-Cosío  P. A. Robledo-Ardila 《Ground water》2021,59(6):878-891

High surface water-groundwater connectivity characterizes watersheds underlain by karsts, increasing contaminant transport risks. However, karsts are highly complex, making research necessary to understand the transport of contaminants from the surface, through the aquifer, to discharge areas. In Yucatan, the lack of waste water treatment raises the risk of groundwater contamination. We monitored stable isotopes (δ¹⁸O-NO₃ and δ¹⁵N-NO₃), cadmium, and lead to document waste water contamination and transport during the rainy and dry seasons, using water samples collected along the Ring of Cenotes during each season. Specific conductance and pH showed no consistent seasonality, with conductance ranging from 0.5 to 55 mS/cm and pH ranging from 6.6 to 8.6 for most samples. Nitrate concentrations in the cenotes averaged 205 ± 260 μM and no seasonal pattern was observed. Cd and Pb concentrations were 0.1 to 37.9 μg/L and 0.2 to 243.2 μg/L, respectively. Nitrate stable isotope values were 2.6 to 27.2‰ for δ¹⁸O and 1.2 to 20.7‰ for δ¹⁵N. The statistical relationship between δ¹⁵N and δ¹⁸O, in dry season samples, indicated that denitrification was occurring. A scale measure for waste water recognition showed: (1) high variability among sites probably related with dry/rainy seasons and/or diverse anthropogenic activities; and (2) specific water quality variables that contribute to contamination at each site during each season. Importantly, our analyses indicate that in the area surrounding the Ring of Cenotes, waste water exhibits spatial and temporal patterns related to complex transport and dilution processes, as is the case in karsts in general.  相似文献   

The active layer in gravel-bed rivers: An empirical appraisal     

D. Vázquez-Tarrío  G. Piqué  D. Vericat  R.J. Batalla 《地球表面变化过程与地形》2021,46(2):323-343

The vertical position of the streambed–water boundary fluctuates during the course of sediment transport episodes, due to particle entrainment/deposition and bedform migration, amongst other hydraulic and bedload mechanisms. These vertical oscillations define a topmost stratum of the streambed (i.e. the ‘active layer or active depth’), which usually represents the main source of particles entrained during long and high-magnitude bedload transport episodes. The vertical extent of this layer is hence a capital parameter for the quantification of bedload volumes and a major driver of stream ecology in gravel-bed rivers. However, knowledge on how the active depth scales to flow strength and the nature of the different controls on the relation between the flow strength and the active depth is still scarce. In this paper we present a meta-analysis over active depth data coming from ~130 transport episodes extracted from a series of published field studies. We also incorporate our own field data for the rivers Ebro and Muga (unpublished), both in the Iberian Peninsula. We explore the database searching for the influence of flow strength, grain size, streambed mobility and channel morphology on the vertical extent of the active layer. A multivariate statistical analysis (stepwise multiple regression) confirms that the set of selected variables explains a significant amount of variance in the compiled variables. The analysis shows a positive scaling between active depth and flow strength. We have also identified some links between the active depth and particle travel distances. However, these relations are also largely modulated by other fluvial drivers, such as the grain size of the bed surface and the dominant channel macro-bedforms, with remarkable differences between plane-bed, step-pool and riffle-pool channels. © 2020 John Wiley & Sons, Ltd.  相似文献   

Model prediction capacity of ephemeral gully evolution in conservation tillage systems     

Eduardo Luquin  Miguel A. Campo-Bescós  Rafael Muñoz-Carpena  Ronald L. Bingner  Richard M. Cruse  Henrique G. Momm  Robert R. Wells  Javier Casalí 《地球表面变化过程与地形》2021,46(10):1909-1925

Ephemeral gully (EG) erosion has an important impact on agricultural soil losses and increases field surface hydrology connectivity and transport of pollutants to nearby water bodies. Watershed models including an EG component are scarce and not yet properly evaluated. The objective of this study is to evaluate the capacity of one such tool, AnnAGNPS, to simulate the evolution of two EG formed in a conservation tillage system. The dataset for model testing included runoff measurements and EG morphological characteristics during 3 years. Model evaluation focused on EG evolution of volume, width, and length model outputs, and included calibration and testing phases and a global sensitivity analysis (GSA). While the model did not fully reproduce width and length, the model efficiency to simulate EG volume was satisfactory for both calibration and testing phases, supporting the watershed management objectives of the model. GSA revealed that the most sensitive factors were EG depth, critical shear stress, headcut detachment exponent coefficient b, and headcut detachment leading coefficient a. For EG outputs the model was additive, showing low sensitivity to interactions between the inputs. Prediction of EG spatial evolution on conservation tillage systems requires improved development of gully erosion components, since many of the processes were developed originally for traditional tillage practices or larger channel systems. Our results identify the need for future research when EG form within conservation tillage systems, in particular to study gully headcut, soil erodibility, and width functions specific to these practices.  相似文献   

Sediment transport at the network scale and its link to channel morphology in the braided Vjosa River system     

Simone Bizzi  Marco Tangi  Rafael J. P. Schmitt  John Pitlick  Hervé Piégay  Andrea Francesco Castelletti 《地球表面变化过程与地形》2021,46(14):2946-2962

In this article we apply the CASCADE network-scale sediment connectivity model to the Vjosa River in Albania. The Vjosa is one of the last unimpaired braided rivers in Europe and, at the same time, a data scarce environment, which limits our ability to model how this pristine river might respond to future human disturbance. To initialize the model, we use remotely sensed data and modeled hydrology from a regional model. We perform a reach-by-reach optimization of surface grain size distribution (GSD) and bedload transport capacity to ensure equilibrium conditions throughout the network. In order to account for the various sources of uncertainty in the calculation of transport capacity, we performed a global sensitivity analysis. The modeled GSD distributions generated by the sensitivity analysis generally match the six GSDs measured at different locations within the network. The modeled bedload sediment fluxes increase systematically downstream, and annual fluxes at the outlet of the Vjosa are well within an order of magnitude of fluxes derived from previous estimates of the annual suspended sediment load. We then use the modeled sediment fluxes as input to a set of theoretically derived functions that successfully discriminate between multi-thread and single-thread channel patterns. This finding provides additional validation of the model results by showing a clear connection between modeled sediment concentrations and observed river morphology. Finally, we observe that a reduction in sediment flux of about 50% (e.g., due to dams) would likely cause existing braided reaches to shift toward single thread morphology. The proposed method is widely applicable and opens a new avenue for application of network-scale sediment models that aid in the exploration of river stability to changes in water and sediment fluxes.  相似文献   

New snow metrics for a warming world     

Anne W. Nolin  Eric A. Sproles  David E. Rupp  Ryan L. Crumley  Mariana J. Webb  Ross T. Palomaki  Eugene Mar 《水文研究》2021,35(6):e14262

Snow is Earth's most climatically sensitive land cover type. Traditional snow metrics may not be able to adequately capture the changing nature of snow cover. For example, April 1 snow water equivalent (SWE) has been an effective index for streamflow forecasting, but it cannot express the effects of midwinter melt events, now expected in warming snow climates, nor can we assume that station-based measurements will be representative of snow conditions in future decades. Remote sensing and climate model data provide capacity for a suite of multi-use snow metrics from local to global scales. Such indicators need to be simple enough to “tell the story” of snowpack changes over space and time, but not overly simplistic or overly complicated in their interpretation. We describe a suite of spatially explicit, multi-temporal snow metrics based on global satellite data from NASA's Moderate Resolution Imaging Spectroradiometer (MODIS) and downscaled climate model output for the U.S. We describe and provide examples for Snow Cover Frequency (SCF), Snow Disappearance Date (SDD), At-Risk Snow (ARS), and Frequency of a Warm Winter (FWW). Using these retrospective and prospective snow metrics, we assess the current and future snow-related conditions in three hydroclimatically different U.S. watersheds: the Truckee, Colorado Headwaters, and Upper Connecticut. In the two western U.S. watersheds, SCF and SDD show greater sensitivity to annual differences in snow cover compared with data from the ground-based Snow Telemetry (SNOTEL) network. The eastern U.S. watershed does not have a ground-based network of data, so these MODIS-derived metrics provide uniquely valuable snow information. The ARS and FWW metrics show that the Truckee Watershed is highly vulnerable to conversion from snowfall to rainfall (ARS) and midwinter melt events (FWW) throughout the seasonal snow zone. In comparison, the Colorado Headwaters and Upper Connecticut Watersheds are colder and much less vulnerable through mid- and late-century.  相似文献   

Three-dimensional tomographic inversion of the seismic velocity structure of the crust and upper mantle of northwestern Nicaragua     

Domínguez  Jaime  Suárez  Gerardo  Gorbatov  Alexei  Segura  Fabio 《Journal of Seismology》2021,25(6):1427-1439

Journal of Seismology - A three-dimensional tomographic image of the seismic velocity structure in the crust and upper mantle of northwestern Nicaragua was performed using the back-projection...  相似文献   

Scalar field theory and energy-momentum problem of Yilmaz-Rosen metric in general relativity and teleparallel gravity     

Sezgin Aygün  İsmail Tarhan  Hüsnü Baysal 《Astrophysics and Space Science》2008,314(4):323-330

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Molecular lines from protoplanetary nebulae: observations with ALMA     

Valentín Bujarrabal 《Astrophysics and Space Science》2008,313(1-3):209-214

Planetary nebulae (PNe) are formed in a very fast process. In just about 1000 years, the nebula evolves from a spherical and slowly expanding AGB envelope to a PN, with usually axial symmetry and high axial velocities. Molecular lines are known to probe most of the nebular material in young PNe and protoplanetary nebulae (PPNe), and are therefore very useful to study such an impressive evolution. Many quantitative results on these objects have been so obtained, including general structure, total mass and density distribution, kinetic temperatures, velocity fields, etc. Existing observations probe both the gas accelerated by post-AGB shocks and the quiescent components. But the study of crucial regions to understand PN formation (recently shocked shells, regions heated by the stellar UV and inner rotating disks) requires observations at higher frequency and with better spatial resolution.   相似文献   

CoRoT/ESTA–TASK 1 and TASK 3 comparison of the internal structure and seismic properties of representative stellar models     

Yveline Lebreton  Josefina Montalbán  Jørgen Christensen-Dalsgaard  Ian W. Roxburgh  Achim Weiss 《Astrophysics and Space Science》2008,316(1-4):187-213

We compare stellar models produced by different stellar evolution codes for the CoRoT/ESTA project, comparing their global quantities, their physical structure, and their oscillation properties. We discuss the differences between models and identify the underlying reasons for these differences. The stellar models are representative of potential CoRoT targets. Overall we find very good agreement between the five different codes, but with some significant deviations. We find noticeable discrepancies (though still at the per cent level) that result from the handling of the equation of state, of the opacities and of the convective boundaries. The results of our work will be helpful in interpreting future asteroseismology results from CoRoT.  相似文献