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121.
International Journal of Earth Sciences - The petroleum system of the Upper Rhine Graben (URG) comprises multiple reservoir rocks and four major oil families, which are represented by four distinct...  相似文献   
122.
The spatial distribution of polyfluoroalkyl compounds (PFCs) was investigated in dab (Limanda limanda) bile fluids collected from Iceland and the North Sea. Concentrations of various PFCs, including perfluorinated sulfonates (C4-C6, C8 PFSAs), perfluorinated carboxylic acids (C9-C14 PFCAs) and n-methyl perfluorooctane sulfonamidoethanol (MeFOSE), were quantified. Perfluorooctane sulfonate (PFOS) was the predominant compound with highest concentrations along the Danish and German coast (mean 9.36 ng/g wet weight (ww)). Significantly lower PFOS concentrations were found at the other sampling stations in the North Sea and Iceland (< 0.01, t-test). Conversely, the spatial distribution of the PFCAs in Iceland and the North Sea was more uniform. The most abundant PFCA was perfluorononanoic acid (PFNA), while the mean concentration decreased with increasing chain length from 4.7 ng/g ww for PFNA to 0.04 ng/g ww for perfluorotetradecanoic acid (PFTeDA). Overall, the different spatial distribution of PFCs indicates different origin of sources and different transportation mechanism.  相似文献   
123.
Coal mining in the Saar mine, Germany, is accompanied by mining-induced seismic events. Strong events occur only in certain areas of the mine, other areas exhibit almost no seismicity. Shear events occur simultaneously to non-shear events. The shear events occur in different depths but their epicenters do concentrate in bands. The strike of the bands coincides with the strike of larger regional faults in the area. The seismic events of the Saar mine show some characteristics which distinguish them from seismic events observed in other German coalfields. The Gutenberg–Richter relation, for example, does not hold for these events. Furthermore, radiated seismic energy and extracted coal volume are not correlated. In the Primsmulde field a strong seismic event was observed even before mining in that region started. The event was triggered just by driving roadways into the field. The shear events cannot be explained by the mining process alone. They are presumably induced in certain regions (bands) under tectonic load by an interaction of mining-induced and tectonic stresses. In February 2008, extraction in the Primsmulde field induced a seismic event of magnitude 4, which led to surface vibrations reaching 93 mm/s. After this event, the Primsmulde field had to be abandoned. Future extraction of the Saar mine will be restricted to some small areas not intersected by the event bands found in the Dilsburg Ost and Primsmulde fields. The Saar mine will close in 2011.  相似文献   
124.
Carbonatites are mantle-derived, intraplate magmas that provide a means of documenting isotopic variations of the Earth's mantle through time. To investigate the secular Li isotopic evolution of the mantle and to test whether Li isotopes document systematic recycling of material processed at or near the Earth's surface into the mantle, we analyzed the Li isotopic compositions of carbonatites and spatially associated mafic silicate rocks. The Li isotopic compositions of Archean (2.7 Ga) to Recent carbonatites (δ7Li = 4.1 ± 1.3 (n = 23, 1σ)) overlap the range typical for modern mantle-derived rocks, and do not change with time, despite ongoing crustal recycling. Thus, the average Li isotopic composition of recycled crustal components has not deviated greatly from the mantle value (~ + 4) and/or Li diffusion is sufficiently fast to attenuate significant heterogeneities over timescales of 108 years. Modeling of Li diffusion at mantle temperatures suggests that limited δ7Li variation in the mantle through time reflects the more effective homogenization of Li in the mantle compared to radiogenic isotope systems. The real (but limited) variations in δ7Li that exist in modern mantle-derived magmas as well as carbonatites studied here may reflect isotopic fractionation associated with shallow-level processes, such as crustal assimilation and diffusive isotopic fractionation in magmatic systems, with some of the scatter possibly related to low-temperature alteration.  相似文献   
125.
In diatremes and other volcanic vents, steep bodies of volcaniclastic material having differing properties (particle size distribution, proportion of lithic fragments, etc.) from those of the surrounding vent-filling volcaniclastic material are often found. It has been proposed that cylindrical or cone-shaped bodies result from the passage of “debris jets” generated after phreatomagmatic explosions or other discrete subterranean bursts. To learn more about such phenomena, we model experimentally the injection of gas-particulate dispersions through other particles. Analogue materials (glass beads or sand) and a finite amount of compressed air are used in the laboratory. The gas is made available by rapidly opening a valve—therefore the injection of gas and coloured particles into a granular host is a brief (<1 s), discrete event, comparable to what occurs in nature following subterranean explosions. The injection assumes a bubble shape while expanding and propagating upwards. In reaction, the upper part of the clastic host moves upward and outward above the ‘bubble’, forming a ‘dome’. The doming effect is much more pronounced for shallow injection depths (thin hosts), with dome angles reaching more than 45°. Significant surface doming is also observed for some full-scale subterranean blasts (e.g. buried nuclear explosions), so it is not an artefact of our setup. What happens next in the experiments depends on the depth of injection and the nature of the host material. With shallow injection into a permeable host (glass beads), the compressed air in the “bubble’ is able to diffuse rapidly through the roof. Meanwhile the coloured beads sediment into the transient cavity, which is also closing laterally because of inward-directed granular flow of the host. Depending on the initial gas pressure in the reservoir, the two-phase flow can “erupt” or not; non-erupting injections produce cylindrical bodies of coloured beads whereas erupting runs produce flaring upward or conical deposits. Changing the particle size of the host glass beads does not have a large effect under the size range investigated (100–200 to 300–400 μm). Doubling the host thickness (injection depth) requires a doubling of the initial gas pressure to produce similar phenomena. Such injections—whether erupting or wholly subterranean—provide a compelling explanation for the origin and characteristics of multiple cross-cutting bodies that have been documented for diatreme and other vent deposits.  相似文献   
126.
The discovery of the giant Daqing oil field in the Songliao Basin led to the realisation of the significant petroleum potential of non-marine basins. In order to reconstruct the basin evolution and oil formation, an integrated organic geochemical-basin modelling study along a regional transect across the Songliao Basin was conducted. It provided a regional heat flow evolution model, and revealed post-orogenic or late syn-orogenic maturation in the Central Depression and pre-orogenic maturation in the Southeast Uplift Zone. Kinetic parameters of petroleum generation for the lacustrine source formations are the basis for the simulation of oil generation and migration in the Songliao Basin. Using the principle activation energy peaking at 54 kcal/mol and a pre-exponential factor of about 4.2·1027 Ma−1, the simulation obtained a relatively good match with the measured transformation ratios. The Qingshankou Formation in the West and East Central Depressions constituted the major source in the basin. Major oil generation, migration and accumulation occurred during the Early Tertiary. In the West Central Depression, the generated oils migrated upwards into the Yaojia Formation followed by the updip migration into the Daqing Anticline and towards the local structural high along the West Slope. In contrast, the oil migration in the East Central Depression was dominated by the downward movement from the lower member of the Qingshankou Formation followed by the updip migration towards the Caoyang Anticline. The simulated oil accumulations are in good agreement with discovered oil fields, implying a potential application of the model for prediction and evaluation of new exploration targets in the basin.  相似文献   
127.
Wind gaps in actively growing mountain ranges are unique geomorphological features testifying to the competition between tectonics and fluvial incision. Although it is clear that these landforms reflect the defeat of rivers during sustained rock uplift, the role of climate changes in their formation has never been explored. Here, we use a coupled tectonics–landscape evolution model to show that temporal changes in precipitation rate exert an important control on wind gap formation. In models with a constant precipitation rate, rivers flowing across a growing range are either defeated at an early stage or they abandon their valleys very late, if at all. If precipitation varies, wind gaps form mostly c. 100–200 ka after a transition to drier conditions because of sediment aggradation upstream of the range. Our results suggest that the Pliocene–Quaternary aridification of Central Asia contributed to wind gap formation in active mountain ranges in the foreland of northeastern Tibet.  相似文献   
128.
Violent explosive eruptions occurred between c. 51 and 29 thousand years ago—during the Last Glacial Maximum in East‐Central Europe—at the picturesque volcano of Ciomadul, located at the southernmost tip of the Inner Carpathian Volcanic Range in Romania. Field volcanology, glass geochemistry of tephra, radiocarbon and optically stimulated luminescene dating, along with coring the lacustrine infill of the two explosive craters of Ciomadul (St Ana and Mohos), constrain the last volcanic activity to three subsequent eruptive stages. The explosivity was due to the silicic composition of the magma producing Plinian‐style eruptions, and the interaction of magma with the underlying, water‐rich rocks resulting in violent phreatomagmatic outbursts. Tephra (volcanic ash) from these eruptions are interbedded with contemporaneous loess deposits, which form thick sequences in the vicinity of the volcano. Moreover, tephra layers are also preserved in the older Mohos crater infill, providing an important archive for palaeoclimate studies. Identifying the final phreatomagmatic eruption of Ciomadul at c. 29.6 ka, which shaped the present‐day landform of the 1600‐m‐wide St Ana explosion crater, we were able to correlate related tephra deposits as far as 350 km from the source within a thick loess‐palaeosol sequence at the Dniester Delta in Roxolany, Ukraine. A refined tephrostratigraphy, based on a number of newly found exposures in the Ciomadul surrounding region as well as correlation with the distal terrestrial and marine (e.g. Black Sea) volcano‐sedimentary record, is expected from ongoing studies.  相似文献   
129.
By means of population synthesis models with variable α/Fe ratios we derive average ages, metallicities, and [α/Fe] element enhancements for a sample of 126 field and cluster early-type galaxies. We find a clear positive relation between [α/Fe] and velocity dispersion. Zero-point, slope, and scatter of this correlation are the same for cluster and field galaxies. In particular, the [α/Fe] ratios and mean ages of cluster ellipticals are positively correlated. This strongly reinforces the view that the [α/Fe] element enhancement in ellipticals is produced by star formation timescales rather than by variations of the initial mass function. These results indicate that the more massive the galaxy, the shorter is its star formation timescale, and the higher is the redshift of the bulk of star formation. This finding is not compatible with the predictions from models of hierarchical galaxy formation. The lenticular and field galaxies of the investigated sample do not follow the correlation between age and [α/Fe], but contain a non-negligible fraction of galaxies with young average ages and high [α/Fe] ratios. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   
130.
Supersonic and super-Alfvénic turbulent motions generate an intricate pattern of shock waves through which the turbulence decays. We here illustrate the spatial structure during shock formation and decay. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
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