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451.
Aurélia Mouret Pierre Anschutz Pascal Lecroart Gwénaëlle Chaillou Christelle Hyacinthe Jonathan Deborde Frans J. Jorissen Bruno Deflandre Sabine Schmidt Jean-Marie Jouanneau 《Geo-Marine Letters》2009,29(3):133-149
Manganese is a major redox reactive element of benthic metabolism. We have built a database of existing knowledge on the benthic
geochemistry of Mn in the Bay of Biscay, in order to comprehensively assess the behaviour of Mn in a variety of environments
during early diagenesis. The database contains vertical profiles of particulate and dissolved Mn species of 59 cores collected
during 17 cruises between 1997 and 2006 at nine stations positioned between 140 and 4,800 m water depths. At all studied stations,
Mn species follow the conventional distribution, where Mn(III,IV) species are enriched in the oxic layer, and dissolved Mn
is present in the anoxic sediments. A minor part of Mn-oxides originates from sedimenting particles. The major part is of
diagenetic origin, and derives from the oxidation of upward-diffusing dissolved Mn(II). Mn-oxide inventories are higher at
the deeper stations than at the shallower ones. This difference cannot be attributed to different sources of sedimenting particles,
but it must depend on sedimentation rate and diagenetic processes. At depth, dissolved Mn(II) concentrations are constant.
This probably reflects equilibrium with an authigenic Mn(II) phase, which is the ultimate phase into which Mn is fossilized.
The Mn content of deeper anoxic sediments is similarly low in all the cores studied, associated with corresponding trends
of Mn content in sedimenting particles of the Bay of Biscay. Bioturbation, rather than redox oscillations, can convey Mn(III,IV)
species downwards into the anoxic sediments where they are reduced, associated with a peak of dissolved Mn. Because dissolved
Mn(II) is re-oxidized when it diffuses towards the oxic layer, the inventory of the diagenetic Mn(III,IV) phase remains at
steady state, especially at stations where the oxic layer is thick. It then becomes possible to calculate the residence time
of diagenetic Mn(III,IV) particles within the oxic layer, using the upward-directed flux of pore water Mn(II). By applying
this residence time to the accumulation of sediments within the oxic layer, we obtain the sediment mass accumulation rate.
The values calculated for the sediments of the Bay of Biscay fit well with accumulation rates obtained from radionuclides
or sediment traps. The method has also been validated with data collected in other marine sedimentary environments.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
452.
Ondréas Hélène Fouquet Yves Voisset Michel Radford-Knoery Joël 《Marine Geophysical Researches》1997,19(3):231-255
Using a new tool of seafloor characterisation (sonar images from FARA-SIGMA cruise; Needham et al., 1992), coupled with submersible observations (DIVA1 cruise) we compare, at different scales of observation, three contiguous segments of the Mid-Atlantic Ridge, South of the Azores Triple Junction, between 37° N and 38°30 N.The two northernmost segments (38°20 N and Menez-Gwen) show unusual morphological features for the MAR; the rift valley is absent and the present-day magmatism is focused on shallow axial volcanoes. On the third segment (Lucky Strike), the morphology is the one usually found on the MAR. On the Menez-Gwen and 38°20 N segments, volcanic constructional activity can obliterate, during periods of high magmatic supply, the morphology inherited from tectonic activity. The dive results constrain the recent evolution of each segment and show that a temporal variability in volcanic dynamics exists. On the three segments, outcrops of eruptive lavas alternate with large areas of explosive volcanic ejecta. This cycle in volcanic activity is influenced by changes in water depth, both spatially (i.e. between segments) and temporally (i.e. for the same segment through time).Each segment has known a specific history in its accretionary processes with a succession of tectonic and volcanic predominance and changes in its volcanic phases between volcanic ejecta and effusive dynamics.The hydrothermal activity is focused at the central part of each segment and is controlled by the presence of fresh lava and major tectonic features. 相似文献