Temperature and its control of isotope fractionation by a sulfate-reducing bacterium     

Donald E. Canfield  Claus A. Olesen  Raymond P. Cox 《Geochimica et cosmochimica acta》2006,70(3):548-561

A synthesis of previous results, which we dub the “standard model,” provides a prediction as to how isotope fractionation during sulfate reduction should respond to physiological variables such as specific rate of sulfate reduction and environmental variables such as substrate availability and temperature. The standard model suggests that isotope fractionation should decrease with increasing specific rates of sulfate reduction (rate per cell). Furthermore, the standard model predicts that low fractionations should be found at both high and low temperatures whereas the highest fractionations should be found in the intermediate temperature range. These fractionation trends are controlled, as a function of temperature, by the balance between the transfer rates of sulfate into and out of the cell and the exchange between the sulfur pools internal to the organism. We test this standard model by conducting experiments on the growth physiology and isotope fractionation, as a function of temperature, by the sulfate-reducing bacterium Desulfovibrio desulfuricans (DSMZ 642). Our results contrast with the “standard model” by showing a positive correlation between specific rates of sulfate reduction and fractionation. Also by contrast with the standard model, we found the highest fractionations at low and high temperatures and the lowest fractionations in the intermediate temperature range. We develop a fractionation model which can be used to explain both our results as well as the results of the “standard model.” Differences in fractionation with temperature relate to differences in the specific temperature response of internal enzyme kinetics as well as the exchange rates of sulfate in and out of the cell. It is expected that the kinetics of these processes will show strain-specific differences.  相似文献   

Thermal and isotopic profiling of the Pipeline hydrothermal system: Application to exploration for Carlin-type gold deposits     

Greg B. Arehart  Raymond A. Donelick 《Journal of Geochemical Exploration》2006,91(1-3):27-40

New exploration techniques are vital to the search for new orebodies in mature terranes, as well as for extensions of existing orebodies. This research focused on application of low-temperature dating techniques (primarily apatite fission-tracks) and stable isotope measurements (carbon and oxygen in carbonate rocks) in and around the Pipeline deposit, a Carlin-type gold system. The primary purpose of the project was to assess whether these techniques could provide exploration vectors that might be used in conjunction with other geologic, geochemical, and geophysical techniques to determine the locus of fossil hydrothermal fluid flow, and the attendant possibility of finding economic mineral deposits.At Pipeline, measurements of apatite fission-tracks and (U − Th) / He geochronometry yield a clear indication of the elevated temperatures associated with the fossil hydrothermal system. The pattern is one of a central target (Pipeline deposit) with decreasing thermal effects as far as several kilometers laterally from the known ore zone. Because of the irregular nature of fluid flow through fractures, a significant number of samples are required to discern this pattern, but the pattern is quite clear from the 32 samples in and around the Pipeline pit.Stable isotope measurements of carbonate rocks yield patterns centered on the Pipeline pit area. Oxygen isotopes in particular are shifted toward lower values as the result of interaction between the hydrothermal fluids and carbonate rocks. Carbon isotopes show a pattern, but it is somewhat more difficult to interpret than the oxygen isotope pattern. As with the geochronometric patterns, isotopic indications of fluid flow are present several kilometers from the ore zone at Pipeline. Also as with the geochronometric data, a relatively large sample set is required to see the pattern. At Pipeline, the patterns are evident in approximately 45 surface samples and very clearly in the cross-sections containing approximately 100 samples.From these data, it is clear that thermal and stable isotopic measurements on rocks at a significant distance from the known Pipeline hydrothermal system record the passage of hot fluids through the rock. Both techniques provide a footprint of the Pipeline system that is several diameters larger than the ore zone (as presently known). Therefore, thermochronologic and stable isotopic measurements can be utilized in conjunction with other techniques as part of an overall exploration strategy for Carlin-type deposits. Although these techniques do not provide a direct indication of the metal content of the fossil hydrothermal fluids, they do provide an indication of the robustness of fluid flow and the potential size of a hydrothermal system.  相似文献   

Geochemistry of silicic magmas in the Macolod Corridor, SW Luzon, Philippines: evidence of distinct, mantle-derived, crustal sources for silicic magmas     

Thomas A. Vogel  Timothy P. Flood  Lina C. Patino  Melissa S. Wilmot  Raymond Patrick R. Maximo  Carmencita B. Arpa  Carlo A. Arcilla  James A. Stimac 《Contributions to Mineralogy and Petrology》2006,151(3):267-281

Silicic volcanic deposits (>65 wt% SiO₂), which occur as domes, lavas and pyroclastic deposits, are relatively abundant in the Macolod Corridor, SW Luzon, Philippines. At Makiling stratovolcano, silicic domes occur along the margins of the volcano and are chemically similar to the silicic lavas that comprise part of the volcano. Pyroclastic flows are associated with the Laguna de Bay Caldera and these are chemically distinct from the domes and lavas at Makiling stratovolcano. As a whole, samples from the Laguna de Bay Caldera contain lower concentrations of MgO and higher concentrations of Fe₂O_3(t) than the samples from domes and lavas. The Laguna de Bay samples are more enriched in incompatible trace elements. The silicic rocks from the domes, Makiling Volcano and Laguna de Bay Caldera all contain high alkalis and high K₂O/Na₂O ratios. Melting experiments of primitive basalts and andesites demonstrate that it is difficult to produce high K₂O/Na₂O silicic magmas by fractional crystallization or partial melting of a low K₂O/Na₂O source. However, recent melting experiments (Sisson et al., Contrib Mineral Petrol 148:635–661, 2005) demonstrate that extreme fractional crystallization or partial melting of K-rich basalts can produce these silicic magmas. Our model for the generation of the silicic magmas in the Macolod Corridor requires partial melting of mantle-derived, evolved, moderate to K-rich, crystallized calc-alkaline magmas that ponded and crystallized in the mid-crust. Major and trace element variations, along with oxygen isotopes and ages of the deposits, are consistent with this model. Electronic Supplementary Material Supplementary material is available for this article at  相似文献   

Editorial     

Raymond Michels  Laurence Mansuy  Marcel Elie  Pierre Faure  Vincent Huault  Luis Martinez  Jacques Pironon 《Organic Geochemistry》2002,33(12)

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The origin of organic matter in the solar system: evidence from the interplanetary dust particles     

G.J Flynn  L.P Keller  S Wirick 《Geochimica et cosmochimica acta》2003,67(24):4791-4806

The detailed examination of meteorites and interplanetary dust particles provides an opportunity to infer the origin of the organic matter found in primitive Solar System materials. If this organic matter were produced by aqueous alteration of elemental (graphitic or amorphous) carbon on an asteroid, then we would expect to see the organic matter occurring preferentially in interplanetary materials that exhibit evidence of aqueous activity, such as the presence of hydrated silicates. On the other hand, if the organic matter were produced either during the nebula phase of Solar System evolution or in the interstellar medium, we might expect this organic matter to be incorporated into the dust as it formed. In that case pre-biotic organic matter would be present in both the anhydrous and the hydrated interplanetary materials. We have performed carbon X-ray absorption near-edge structure spectroscopy and infrared spectroscopy on primitive anhydrous and hydrated interplanetary dust particles (IDPs) collected by NASA from the Earth's stratosphere. We find that organic matter is present in similar types and abundances in both the anhydrous and the hydrated IDPs, and, in the anhydrous IDPs some of this organic matter is the “glue” that holds grains together. These measurements provide the first direct, experimental evidence from the comparison of extraterrestrial samples that the bulk of the pre-biotic organic matter occurs in similar types and abundances in both hydrated and anhydrous samples. This indicates that the bulk of the pre-biotic organic matter in the Solar System did not form by aqueous processing, but, instead, had already formed at the time that primitive, anhydrous dust was being assembled. Thus, the bulk of the pre-biotic organic matter in the Solar System was formed by non-aqueous processing, occurring in either the Solar nebula or in an interstellar environment. Aqueous processing on asteroids may have altered this pre-existing organic matter, but such processing did not affect in any substantial way the C=O content of the organic matter, the aliphatic C-H abundance, or the mean aliphatic chain length.  相似文献   

Contens of Volume 59     

Henry F. Diaz  Jon K. Eischeid  Chris Duncan  Raymond S. Bradley 《Climatic change》2003,59(3):417-418

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Beyond the impasse: the power of political ecology in Third World environmental research   总被引：3，自引：0，他引：3  

Raymond L Bryant 《Area》1997,29(1):5-19

Summary In the context of a deepening impasse in Third World environmental research, this paper suggests that researchers should adopt a political ecology perspective to ensure that research addresses the political and economic issues that underlie the Third World's environmental problems. Since an understanding of unequal power relations is central to political ecology, the paper considers how questions of power influence human-environmental interaction, before assessing briefly how research of this kind might contribute to a resolution of the Third World's environmental problems.  相似文献   

Invariants in toroidal and tangentially geostrophic frozen-flux velocity fields     

Andrew Jackson  Raymond Hide 《Geophysical Journal International》1996,125(3):925-927

We derive two new types of invariant that must be obeyed by the radial magnetic field at the core-mantle boundary if the hypothesis of frozen flux is valid and the fluid motion is either toroidal or tangentially geostrophic there. These general invariants incorporate specific invariants that are already known and can, in principle, be tested using magnetic data that cover an interval of time.  相似文献   

Measurement of natural stresses in a Provence mine (Southern France)     

Patrick Gaviglio  Pascal Bigarre  Hafid Baroudi  Jack-Pierre Piguet  Raymond Monteau 《Engineering Geology》1996,44(1-4):77-92

Stress measurements were carried out in the Arc syncline using drifs in a lignite mine. Eleven sites were investigated using the flat jack and hydraulic fracturing (or stimulating) methods. Two stress states were found to coexist, one isotropic, the other highly anisotropic. The orientations of the principal stresses are not homogeneous and an orientation ranging from E-W to NE-SW predominates locally. This does not accord with the regional stress field. The vertical stresses are systematically underestimated.  相似文献   

A brief comparison of lava flows from the Deccan Volcanic Province and the Columbia-Oregon Plateau Flood Basalts: Implications for models of flood basalt emplacement   总被引：1，自引：0，他引：1  

Ninad R. Bondre  Raymond A. Duraiswami  Gauri Dole 《Journal of Earth System Science》2004,113(4):809-817

The nature and style of emplacement of Continental Flood Basalt (CFB) lava flows has been a matter of great interest as well as considerable controversy in the recent past. However, even a cursory review of published literature reveals that the Columbia River Basalt Group (CRBG) and Hawaiian volcanoes provide most of the data relevant to this topic. It is interesting to note, however, that the CRBG lava flows and their palaeotopographic control is atypical of other CFB provinces in the world. In this paper, we first present a short overview of important studies pertaining to the emplacement of flood basalt flows. We then briefly review the morphology of lava flows from the Deccan Volcanic Province (DVP) and the Columbia-Oregon Plateau flood basalts. The review underscores the existence of significant variations in lava flow morphology between different provinces, and even within the same province. It is quite likely that there were more than one way of emplacing the voluminous and extensive CFB lava flows. We argue that the establishment of general models of emplacement must be based on a comprehensive documentation of lava flow morphology from all CFB provinces.  相似文献