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101.
Net ecosystem metabolism (NEM) was measured in the Piauí River estuary, NE Brazil. A mass balance of C, N, and P was used to infer its sources and sinks. Dissolved inorganic carbon (DIC) concentrations and fluxes were measured over a year along this mangrove dominated estuary. DIC concentrations were high in all estuarine sections, particularly at the fluvial end member at the beginning of the rainy season. Carbon dioxide concentrations in the entire estuary were supersaturated throughout the year and highest in the upper estuarine compartment and freshwater, particularly at the rainy season, due to washout effects of carbonaceous soils and different organic anthropogenic effluents. The estuary served as a source of DIC to the atmosphere with an estimated flux of 13 mol CO2 m?2 year?1. Input from the river was 46 mol CO2 m?2 year?1. The metabolism of the system was heterotrophic, but short periods of autotrophy occurred in the lower more marine portions of the estuary. The pelagic system was more or less balanced between auto- and heterotrophy, whereas the benthic and intertidal mangrove region was heterotrophic. Estimated annual NEM yielded a total DIC production in the order of 18 mol CO2 m?2 year?1. The anthropogenic inputs of particulate C, N, and P, dissolved inorganic P (DIP), and DIC were significant. The fluvial loading of particulate organic carbon and dissolved inorganic nitrogen (DIN) was largely retained in two flow regulation and hydroelectric reservoirs, promoting a reduction of C:N and C:P particulate ratios in the estuary. The net nonconservative fluxes obtained by a mass balance approach revealed that the estuary acts as a source of DIP, DIN, and DIC, the latter one being almost equivalent to the losses to the atmosphere. Mangrove forests and tidal mudflats were responsible for most of NEM rates and are the main sites of organic decomposition to sustain net heterotrophy. The main sources for this organic matter are the fluvial and anthropogenic inputs. The mangrove areas are the highest estuarine sources of DIP, DIC, and DIN.  相似文献   
102.
激光剥蚀-等离子体质谱(LA-ICPMS)已成为地球化学、宇宙化学和环境研究领域元素和同位素原位分析最重要的技术之一。文章介绍了多种类型的质谱仪及其使用的激光器。用途最广的LA-ICPMS仪器之一是单接收器扇形磁场质谱仪,配有Nd:YAG激光剥蚀系统(激光波长分为193 nm和213 nm两种),MPI Mainz实验室使用的就是这套系统,文章对此作一详细介绍。文中阐述了数据优化技术及其多种校正过程;介绍LA-ICPMS在痕量元素和同位素分析领域的一些应用,包括参考物质的研制,Hawaiian玄武岩、Martian陨石、生物骨针和珊瑚虫中痕量元素分析及熔融包裹体和富钙-铝碳质球粒陨石中的铅和锶同位素测量。  相似文献   
103.
Abstract

Conflicts in the management of renewable natural resources are situations in which actors have diverging opinions on issues of natural resource use. In the literature, among the causal factors for conflicts discussed are resource wealth or scarcity and the role of governance. The evidence, however, is contradictory. In order to analyze the role of governance in more detail, we propose a combined analysis of property rights and conflicts. In this way, an improved understanding of the causes of local conflicts over renewable natural resources can be achieved. We use comparative case study data from pasture management in the Caucasus region, first, to classify conflicts according to the bundle of property rights approach and, second, to explore how the causal factors resource scarcity and current governance contribute to those conflicts.  相似文献   
104.
Fracturing and hydrothermal alteration in normal fault zones   总被引:9,自引:0,他引:9  
Large normal fault zones are characterized by intense fracturing and hydrothermal alteration. Displacement is localized in a slip zone of cataclasite, breccia and phyllonite surrounding corrugated and striated fault surfaces. Slip zone rock grades into fractured, but less comminuted and hydrothermally altered rock in the transition zone, which in turn grades abruptly into the wall rock. Fracturing and fluid flow is episodic, because permeability generated during earthquakes is destroyed by hydrothermal processes during the time between earthquakes.Fracture networks are described by a fracture fabric tensor (F). The permeability tensor (k) is used to estimate fluid transport properties if the trace of F is sufficiently large. Variations in elastic moduli and seismic velocities between fault zone and wall rock are estimated as a function of fracture density (). Fracturing decreases elastic moduli in the transition zone by 50–100% relative to the country rock, and similar or even greater changes presumably occur in the slip zone.P-andS-wave velocity decrease, andV p /V s increases in the fault zone relative to the wall rock. Fracture permeability is highly variable, ranging between 10–13 m2 and 10–19 m2 at depths near 10 km. Changes in permeability arise from variations in effective stress and fracture sealing and healing.Hydrothermal alteration of quartzo-feldspathic rock atT>300°C creates mica, chlorite, epidote and alters the quartz content. Alteration changes elastic moduli, but the changes are much less than those caused by fracturing.P-andS-wave velocities also decrease in the hydrothermally altered fault rock relative to the country rock, and there is a slight decrease inV p /V s , which partially offsets the increase inV p /V s caused by fracturing.Fracturing and hydrothermal alteration affect fault mechanics. Low modulus rock surrounding fault surfaces increases the probability of exceeding the critical slip distance required for the onset of unstable slip during rupture initiation. Boundaries between low modulus fault rock and higher modulus wall rock also act as rupture guides and enhance rupture acceleration to dynamic velocity. Hydrothermal alteration at temperatures in excess of 300°C weakens the deeper parts of the fault zone by producingphyllitic mineral assemblages. Sealing of fracture in time periods between large earthquakes generates pods of abnormally pressured fluid which may play a fundamental role in the initiation of large earthquakes.  相似文献   
105.
106.
In this paper the results of an experimental investigation of the spectra of submicrometersized silicon carbide grains are presented. The grains manufactured from two types of commercial -SiC were prepared according to the Jena IR spectroscopy program for particulates of cosmic importance. From the spectral records mass absorption coefficients have been derived. These data have been used to make a comparison of the laboratory spectra with the well-known 11.5 m emission band observed in the spectra of carbon stars, which is probably due to a transition in circumstellar SiC grains. For this aim, a simple model of an optically thin circumstellar envelope containing SiC grains has been calculated. The theoretical profile of the 11.5 m band derived by means of this model and based on the experimental mass absorption coefficients of SiC grains shows a striking similarity with the observed profile in the spectrum of the carbon star Y CVn. The total amount of SiC dust in the envelope of this star has been estimated at about 1024 g.  相似文献   
107.
108.
The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ11B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution.  相似文献   
109.
Narrow-band CCD images of 209 axially symmetrical planetary nebulae (PNe) have been examined in order to determine the orientation of their axes within the disc of the Galaxy. The nebulae have been divided into the bipolar (B) and elliptical (E) PNe morphological types, according to the scheme of Corradi &38; Schwarz. In both classes, contrary to the results of Melnick &38; Harwit and Phillips we do not find any strong evidence for non-random orientations of the nebulae in the Galaxy. Compared with previous work in this field, the present study takes advantage of the use of larger and morphologically more homogeneous samples and offers a more rigorous statistical analysis.  相似文献   
110.
There are many arguments supporting the need for a reduction of large scale logging and mining activities in Pacific Island countries. In addition to ecological and economic concerns, logging and mining have had significant social impacts, including gendered impacts. Women tend to be excluded from decision-making processes, and they have limited access to royalty payments and business and employment opportunities which emerge. Women also bear a disproportionate share of the responsibility for dealing with the social and environmental mess which accumulates. However, women are not simply passive victims of logging and mining activities, as this discussion of the Solomon Islands and Papua New Guinea will argue. They are often the first to feel dissatisfaction with logging and mining and it is such dissatisfaction which has fuelled civil unrest, from family break-ups to sabotage of machinery to civil war, in some communities. It may thus be useful for companies to more carefully monitor the effects of their activities on women and involve women more actively in decision-making bodies if they wish to avoid such unrest in the future.  相似文献   
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