Determination of Partition Coefficients of Metals in Natural Tropical Water     

Sonia Regina Giancoli Barreto  Wagner José Barreto  Elisangela Manjurma Deduch 《洁净——土壤、空气、水》2011,39(4):362-367

The values for the partition coefficient (K_d) were calculated for Ca, Mg, Cd, Cr, Cu, Fe, Mn, Pb, Ni, and Zn at 19 sites in the Capivara hydroelectric reservoir in Brazil. It was found that the relative values of K_d follow the order: Cr > Mn > Fe > Cu > Zn > Ni > Pb > Ca > Cd, differing from the values reported for K_d in aquatic systems in the northern hemisphere. A hierarchical cluster analysis and linear correlations showed that Cr is strongly associated with Fe and Cu, and that Cd is the only metal found in complexation with organic matter, explaining its higher solubility.  相似文献   

GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination     

Klaus Peter Jochum  Steven A. Wilson  Wafa Abouchami  Marghaleray Amini  Jérome Chmeleff  Anton Eisenhauer  Ernst Hegner  Linda M. Iaccheri  Bruno Kieffer  Joachim Krause  William F. McDonough  Regina Mertz‐Kraus  Ingrid Raczek  Roberta L. Rudnick  Denis Scholz  Grit Steinhoefel  Brigitte Stoll  Andreas Stracke  Sonia Tonarini  Dominique Weis  Ulrike Weis  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2011,35(2):193-226

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.  相似文献   

Spectroscopic Observations of the 2011 Draconids Meteor Shower     

Regina Rudawska  Joe Zender  Peter Jenniskens  Jeremie Vaubaillon  Pavel Koten  Anastasios Margonis  Juraj Tóth  Jonathan McAuliffe  Detlef Koschny 《Earth, Moon, and Planets》2014,112(1-4):45-57

Some past October Draconid shower meteoroids fell apart in a spray of fragments at the end of their trajectory before slowing down, from which it was concluded that these were among the most fragile meteoroids known. In those instances, the dust could not be reliably traced to a particular return of the parent comet 21P/Giaconini-Zinner. On October 8th, 2011, Earth was predicted to transverse the 1900 A.D. dust ejecta of the comet. In 1900, the comet’s perihelion distance first moved significantly inwards to the Sun and ejection conditions could have been unusual. An airborne observing campaign was organized, with several teams contributing imaging and spectrographic cameras to study the manner in which these meteoroids released the volatile element sodium during the ablation process in the Earth’s atmosphere. IMCCE, ESA, and the SETI Institute contributed spectrographic cameras based on low-light WATEC 902H2 Ultimate, low-light LCC1, and GenII XX1332 image intensified cameras. An outburst was observed, much as predicted. Despite a lack of bright meteors, a total of 15 Draconid spectra were recorded. All show evidence of an early release of sodium. The loss of sodium was observed to coincide with the formation of a distinct wake of fragments. The observations show that 21P/Giacobini-Zinner ejected fragile meteoroids during the return in 1900. Those grains may have lost some sodium even before impacting Earth.  相似文献   

Millennial-scale variations in western Sierra Nevada precipitation during the last glacial cycle MIS 4/3 transition     

Jessica L. Oster  Isabel P. Montañez  Regina Mertz-Kraus  Warren D. Sharp  Greg M. Stock  Howard J. Spero  John Tinsley  James C. Zachos 《Quaternary Research》2014

Dansgaard–Oeschger (D–O) cycles had far-reaching effects on Northern Hemisphere and tropical climate systems during the last glacial period, yet the climatic response to D–O cycles in western North America is controversial, especially prior to 55 ka. We document changes in precipitation along the western slope of the central Sierra Nevada during early Marine Oxygen Isotope Stages (MIS) 3 and 4 (55–67 ka) from a U-series dated speleothem record from McLean's Cave. The timing of our multi-proxy geochemical dataset is coeval with D–O interstadials (15–18) and stadials, including Heinrich Event 6. The McLean's Cave stalagmite indicates warmer and drier conditions during Greenland interstadials (GISs 15–18), signified by elevated δ¹⁸O, δ¹³C, reflectance, and trace element concentrations, and less radiogenic ⁸⁷Sr/⁸⁶Sr. Our record extends evidence of a strong linkage between high-latitude warming and reduced precipitation in western North America to early MIS 3 and MIS 4. This record shows that the linkage persists in diverse global climate states, and documents the nature of the climatic response in central California to Heinrich Event 6.  相似文献   

Initial Calibration of the Atmospheric Imaging Assembly (AIA) on the Solar Dynamics Observatory (SDO)     

Paul Boerner  Christopher Edwards  James Lemen  Adam Rausch  Carolus Schrijver  Richard Shine  Lawrence Shing  Robert Stern  Theodore Tarbell  Alan Title  C. Jacob Wolfson  Regina Soufli  Eberhard Spiller  Eric Gullikson  David McKenzie  David Windt  Leon Golub  William Podgorski  Paola Testa  Mark Weber 《Solar physics》2012,275(1-2):41-66

The Atmospheric Imaging Assembly (AIA) instrument onboard the Solar Dynamics Observatory (SDO) is an array of four normal-incidence reflecting telescopes that image the Sun in ten EUV and UV wavelength channels. We present the initial photometric calibration of AIA, based on preflight measurements of the response of the telescope components. The estimated accuracy is of order 25%, which is consistent with the results of comparisons with full-disk irradiance measurements and spectral models. We also describe the characterization of the instrument performance, including image resolution, alignment, camera-system gain, flat-fielding, and data compression.  相似文献   

Does Pumping Volume Affect the Concentration of Micropollutants in Groundwater Samples?          下载免费PDF全文

Inge H. van Driezum  Julia Derx  Ernis Saracevic  Alexander K.T. Kirschner  Regina Sommer  Andreas H. Farnleitner  Alfred Paul Blaschke 《Ground Water Monitoring & Remediation》2017,37(4):82-88

Information on concentrations of micropollutants (such as pharmaceuticals, pesticides, and industrial chemicals) in most highly dynamic riverbank filtration (RBF) systems is lacking, in contrast to data on standard chemical parameters. Sampling protocols have thus far been based on the stabilization of standard chemical parameters in relatively pristine environments. To determine whether groundwater samples for micropollutant analysis can be taken at a similar pumping volume as samples for testing standard chemical parameters in both environments, three groundwater monitoring wells in an RBF system were sampled at two points in time (after pumping of 3 well volumes and after pumping of 15 well volumes). Micropollutant concentrations were not significantly different between the two sampling points; therefore, appropriate samples can be drawn after pumping 3 well volumes. For a specific microbiological parameter (leucin incorporation), a statistically significant difference was found.  相似文献   

NanoSr – A New Carbonate Microanalytical Reference Material for In Situ Strontium Isotope Analysis     

Michael Weber  Federico Lugli  Bodo Hattendorf  Denis Scholz  Regina Mertz‐Kraus  Damien Guinoiseau  Klaus Peter Jochum 《Geostandards and Geoanalytical Research》2020,44(1):69-83

The in situ measurement of Sr isotopes in carbonates by MC‐ICP‐MS is limited by the availability of suitable microanalytical reference materials (RMs), which match the samples of interest. Whereas several well‐characterised carbonate reference materials for Sr mass fractions > 1000 µg g^?1 are available, there is a lack of well‐characterised carbonate microanalytical RMs with lower Sr mass fractions. Here, we present a new synthetic carbonate nanopowder RM with a Sr mass fraction of ca. 500 µg g^?1 suitable for microanalytical Sr isotope research (‘NanoSr’). NanoSr was analysed by both solution‐based and in situ techniques. Element mass fractions were determined using EPMA (Ca mass fraction), as well as laser ablation and solution ICP‐MS in different laboratories. The ⁸⁷Sr/⁸⁶Sr ratio was determined by well‐established bulk methods for Sr isotope measurements and is 0.70756 ± 0.00003 (2s). The Sr isotope microhomogeneity of the material was determined by LA‐MC‐ICP‐MS, which resulted in ⁸⁷Sr/⁸⁶Sr ratios of 0.70753 ± 0.00007 (2s) and 0.70757 ± 0.00006 (2s), respectively, in agreement with the solution data within uncertainties. Thus, this new reference material is well suited to monitor and correct microanalytical Sr isotope measurements of low‐Sr, low‐REE carbonate samples. NanoSr is available from the corresponding author.  相似文献   

The resolved red giant branches of E/S0 galaxies     

Regina E. Schulte-Ladbeck  Igor O. Drozdovsky  Michèle Belfort  Ulrich Hopp 《Astrophysics and Space Science》2003,284(2):909-912

Formation paradigms for massive galaxies have long centered around two antipodal hypotheses – the monolithic-collapse and the accretion/merger scenarios. Empirical data on the stellar contents of galaxy halos is crucial in order to develop galaxy formation and assembly scenarios which have their root in observations, rather than in numerical simulations. The Hubble Space Telescope (HST) has enabled us to study directly individual stars in the nearby E/S0 galaxies Cen A, NGC 3115, NGC 5102, and NGC 404. We here present and discuss HST single-star photometry in V and I bands. Using color-magnitude diagrams and stellar luminosity functions, we gauge the galaxies' stellar contents. This can be done at more than one position in the halo, but data with deeper limiting magnitudes are desired to quantify the variation of metallicity with galactocentric radius. We here compare the color distributions of red giant stars with stellar isochrones, and we intercompare the galaxies' halo populations, noting that their total absolute V magnitudes cover the range from about –21.5 to –17.5. In the future, we plan to model the stellar metallicity distributions with the aim to constrain chemical enrichment scenarios, a step towards unravelling the evolutionary history of elliptical and lenticular galaxies. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Digitization and Scientific Exploitation of the Italian and Vatican Astronomical Plate Archives     

Cesare Barbieri  Carlo Blanco  Beatrice Bucciarelli  Regina Coluzzi  Andrea Di Paola  Luciano Lanteri  Gian Luca Li Causi  Ettore Marilli  Piero Massimino  Vincenzo Mezzalira  Stefano Mottola  Roberto Nesci  Alessandro Omizzolo  Fernando Pedichini  Francesca Rampazzi  Corinne Rossi  Ruggero Stagni  Milcho Tsvetkov  Roberto Viotti 《Experimental Astronomy》2003,15(1):29-43

There is a widespread interest to digitize the precious information contained in the astronomical plate archives, both for the preservation of their content and for its fast distribution to all interested researchers in order to achieve their better scientific exploitation. This paper presents the first results of our large-scale project to digitize the archive of plates of the Italian Astronomical Observatories and of the Specola Vaticana. Similar systems, composed by commercial flat-bed retro-illuminated scanners plus dedicated personal computers and acquisition and analysis software, have been installed in all participating Institutes. Ad-hoc codes have been developed to acquire the data, to test the suitability of the machines to our scientific needs, and to reduce the digital data in order to extract the astrometric, photometric and spectroscopic content. Two more elements complete the overall project: the provision of high quality BVRI CCD sequences in selected fields with the Campo Imperatore telescopes, and the distribution of the digitized information to all interested researchers via the Web. The methods we have derived in the course of this project have been already applied successfully to plates taken by other Observatories, for instance at Byurakan and at Hamburg.  相似文献   

The ionic strength dependence of lead (II) carbonate complexation in perchlorate media     

Regina A. Easley 《Geochimica et cosmochimica acta》2011,75(19):5638-5647

Lead speciation in many aqueous geochemical systems is dominated by carbonate complexation. However, direct observations of Pb²⁺ complexation by carbonate ions are few in number. This work represents the first investigation of the equilibrium over a range of ionic strength. Through spectrophotometric observations of formation at 25 °C in NaHCO₃-NaClO₄ solutions, formation constants of the form were determined between 0.001 and 5.0 molal ionic strength. Formation constant results were well represented by the equation: