Application of Non-Ionic Solid Sorbents (XAD Resins) for the Isolation and Fractionation of Water-Soluble Organic Compounds from Atmospheric Aerosols     

Regina?M.?B.?O.?DuarteEmail author  Armando?C.?Duarte 《Journal of Atmospheric Chemistry》2005,51(1):79-93

A detailed procedure using non-ionic macropourous XAD-8 and XAD-4 resins is presented for the isolation and fractionation of aerosol water-soluble organic compounds (WSOC) from aerosol samples. The procedure entails adsorption of WSOC fraction onto XAD-8 and XAD-4 resins, desalting of the adsorbed organic material with ultra-pure water, elution of the retained organic matter with 40% MeOH solution and freeze-drying. Due to resin’s different properties and to certain hydrophobic/hydrophilic interactions between the resin polymers and the organic matter, two major fractions were obtained; namely the XAD-8 and the XAD-4 eluates. The XAD-8 eluate, which accounts for 55–60% of total aerosol WSOC, is represented by partially acidic compounds with significant hydrophobic moieties. The XAD-4 fraction holds few conjugated systems and a higher content of hydrophilic structures with low molecular size, and accounts for 9% of total WSOC. The isolated WSOC sub-fractions were nearly free from inorganic species, and successful recoveries of organic matter from the resins were accomplished. With this procedure the XAD-8 eluate yields a mixture representative of those WSOC that are highly conjugated compounds in atmospheric aerosols. It also allows a successful characterisation of the organic material by advanced analytical techniques without the interference of inorganic species present in the original sample of atmospheric particles.  相似文献   

Intense drought and flooding events in the Rio Negro and relation with the tropical Pacific and Atlantic variability modes     

Andreoli  Rita Valéria  da Silva  Simone Nazaré Rodriguez  de Souza  Rodrigo Augusto Ferreira  Kayano  Mary Toshie  Garcia  Sâmia Regina  Capistrano  Vinícius Buscioli  Armijos  Elisa 《Theoretical and Applied Climatology》2017,129(1-2):551-576

The relationship of the hydrological variability of the Rio Negro in Manaus and the dominant large-scale climate variability patterns for the 1902–2007 period is investigated using the quantile method and composite analyses. Variations of the Rio Negro Level (RNL) during its 3-month high (May to July—MJJ) and low (October to December—OND) phases are examined separately. The El Niño (La Niña) related maximum warming (cooling) in the central tropical Pacific during its mature and decaying stages modulates the atmospheric circulation in the tropics and displaces the Walker circulation cell eastward (westward), so that its sinking (rising) branch occurs over western Amazon and causes negative (positive) precipitation anomalies in this region. These anomalous climate conditions occur before the Rio Negro high phase (MJJ) and contribute to reduce (increase) the RNL and lead to a very low (very high) event in the river. On the other hand, the SST variability modes in the tropical Atlantic mainly during the transition from wet to dry season modulate the precipitation variations over western Amazon in OND. The very high events are more frequent after the 1960’s decade and the very low events, before the 1930’s decade. Therefore, the occurrence of these events contains a multidecadal scale variability. The results also indicate that the variations in the rainfall in western Amazon occur up to 9 months in advance and modulate the RNL in Manaus. The results presented here might be useful for monitoring purposes of the RNL.

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Age and geotectonic setting of Late Neoproterozoic juvenile mafic gneisses and associated paragneisses from the Ribeira belt (SE Brazil) based on geochemistry and Sm–Nd data — Implications on Gondwana assembly     

Renata da Silva Schmitt  Rudolph Allard Johannes Trouw  Silvia Regina Medeiros  Elton Luiz Dantas   《Gondwana Research》2008,13(4):502-515

Mafic gneisses and associated paragneisses from the Cabo Frio Tectonic Domain in the southeastern part of the Ribeira Belt, along the coast of Rio de Janeiro State in southeast Brazil, were subjected to a geochemical and Sm–Nd isotope study. Four lithotypes are distinguished: aluminous paragneisses (mainly sillimanite–kyanite–garnet–biotite gneiss), calcsilicate lenses, quartzo–feldspathic metasedimentary gneisses and mafic–ultramafic lenses. The whole-rock major and trace, including rare earth element distributions in the mafic–ultramafic intercalations indicate that derivation from subalkaline basalt/gabbro of tholeiitic affinity with E-MORB signature from a non-subduction environment. These mafic rocks have positive ε_Nd(t) and T_DM of 1.1 Ga. The metasedimentary rocks have negative ε_Nd(t) and T_DM of 1.7 Ga. A Sm–Nd whole rock isochron of mafic rocks yielded an age of 604 ± 38 Ma for the crystallization. This matches with the age of some detrital zircon grains from the paragneisses. The depositional basin, named Buzios–Palmital, was active at least until 620 Ma (age of the youngest detrital zircon) and was subsequently deformed and metamorphosed at ca. 525 Ma (age of metamorphic zircons) during the Buzios Orogeny. It is interpreted as a back arc basin with relation to the 630 Ma magmatic arc of the Oriental Terrane in the Ribeira Belt to the NW. However, after 600 Ma, the Buzios–Palmital basin changed to an active margin setting because the arc collided with the continental margin and the subduction shifted to the back arc environment. By 610 Ma, most of the Brasiliano belts registered collisional events related to multiple convergent blocks. The stress fields and paleocontinent shapes would have allowed the occurrence of extensional areas with not only sedimentary deposition but also ocean floor spreading. Its remnants are preserved in this Brazilian coastal region as an ancient suture, reworked intensively during the Mesozoic rifting events. The reconnaissance of Late Neoproterozoic basins in the Brasiliano–Pan-African belts is of major importance to partially unravel the final amalgamation events of SW Gondwana. Considering that the Buzios–Palmital basin rock units are mostly covered by the marginal Atlantic basins, it is possible that other evidence could be preserved in the coastal regions of SW-Africa and SE-South America.  相似文献   

Transfer patterns in Phase I of the EU Emissions Trading System: a first reality check based on cluster analysis   总被引：1，自引：0，他引：1  

Regina A. Betz  Tobias S. Schmidt 《Climate Policy》2016,16(4):474-495

In 2005, the world's largest Emissions Trading System (ETS) was introduced in the EU. Economic theory assumes high efficiency of such market-based instruments since companies have the flexibility to trade allowances. However, to date there is a lack of understanding on how companies have participated in the allowance markets. This article uses data on transfers of allowances between 2005 and the end of 2007, published by the EU in the Community Independent Transaction Log (CITL) after a five-year delay. We use cluster analysis to detect patterns in the data and differentiate transfer behaviour. We find that the vast majority of participants (7212 accounts) are rather passive in terms of transfers. Of these, more than half are hardly participating in the market at all, whereas one-third are accounts managed by another account belonging to the parent company. Opposed to that, 143 accounts show more active, but relatively diverse transfer behaviour. We also identify differences in sectoral representations, account types, and primary allocation across the seven clusters. While the passive accounts mostly belong to installations regulated under the EU ETS, the most active accounts are classified as ‘non-regulated account type'.  相似文献   

Petrographic and seismic evidence for the depositional setting of giant turbidite reservoirs and the paleogeographic evolution of Campos Basin,offshore Brazil     

Marcos Fetter  Luiz F. De Ros  Carlos H.L. Bruhn 《Marine and Petroleum Geology》2009

The paleogeographic evolution of Campos Basin, a major oil province of Brazil, during the deposition of its giant turbidite reservoirs, was reinterpreted based on the integration of quantitative sandstone petrography and structural analysis of regional 3D seismic data. The major detrital compositional trends indicate that the geodynamic evolution of the continental margin, rather than global eustatic sea-level fluctuations, has exerted the main control on sand supply to the deepwater systems. This control was imposed by the interaction of three geodynamic processes: (i) escarpment retreat of the coastal mountain ridges, (ii) mantle plume-related dynamic uplift and magmatic activity, and (iii) tectonic reactivation of major basement fault-zones. The pattern of distribution of compositional and textural parameters within the turbidite sequences indicated that the sand supply to deepwater was also constrained by high-frequency stratigraphic processes of the climate Milankovitch band. This new approach to the controls on the formation of the sand-rich, deepwater systems in Campos Basin has a key importance for the generation of realistic models for the exploration of new turbidite reservoirs and for the optimized development of producing turbidite oilfields in such a world-class hydrocarbon province. The proposed integrated methodology can help to unravel the controls on the deposition of deepwater sand-rich, deepwater reservoirs in other divergent margin settings.  相似文献   

GGR Critical Review of Analytical Developments in 2008–2009: An Introduction     

Janet M. Hergt  Ricardo Arevalo Jr  L. Paul Bèdard  Jeremy Bellucci  Jacinta Enzweiler  Klaus Peter Jochum  Kathryn L. Linge  William F. McDonough  Regina Mertz-Kraus  Michael Wiedenbeck  Xiaohong Wang  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2010,34(4):325-326

This collection of articles represents the fourth in a series of reviews in which authors have aimed at capturing the key advances in a range of analytical fields ( Hergt et al. 2005, 2006, 2008 ). The publication period under review is 2008–2009 and the intention here is to provide readers with a summary of the most influential developments published during this period, across a broad range of topics appropriate to the Earth and environmental sciences. Most authors comment on the ways in which the emphases of research in their specific fields of examination have changed over time. All note an increase in rigour and focus on data quality. Whether advances have taken place in instrumentation, sample manipulation or data deconvolution, there are a large number of dedicated scientists out there contributing to the high quality of geochemical data employed in geological and environmental research.  相似文献   

Employing turbulent and meandering time scales to modeling the contaminants enhanced horizontal dispersion     

Andra Ucker Timm  Gervsio Annes Degrazia  Dbora Regina Roberti  Domenico Anfossi 《Atmospheric Research》2009,93(4):811-817

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Attitude stability of artificial satellites subject to gravity gradient torque     

Rodolpho Vilhena de Moraes  Regina Elaine Santos Cabette  Maria Cecília Zanardi  Teresinha J. Stuchi  Jorge Kennety Formiga 《Celestial Mechanics and Dynamical Astronomy》2009,104(4):337-353

The stability of the rotational motion of artificial satellites is analyzed considering perturbations due to the gravity gradient torque, using a canonical formulation, and Andoyer’s variables to describe the rotational motion. The stability criteria employed requires the reduction of the Hamiltonian to a normal form around the stable equilibrium points. These points are determined through a numerical study of the Hamilton’s equations of motion and linear study of their stability. Subsequently a canonical linear transformation is used to diagonalize the matrix associated to the linear part of the system resulting in a normalized quadratic Hamiltonian. A semi-analytic process of normalization based on Lie–Hori algorithm is applied to obtain the Hamiltonian normalized up to the fourth order. Lyapunov stability of the equilibrium point is performed using Kovalev and Savchenko’s theorem. This semi-analytical approach was applied considering some data sets of hypothetical satellites, and only a few cases of stable motion were observed. This work can directly be useful for the satellite maintenance under the attitude stability requirements scenario.  相似文献   

Pliocene volcano-tectonics and paleogeography of the Turkana Basin,Kenya and Ethiopia     

Ronald L. Bruhn  Francis H. Brown  Patrick N. Gathogo  Bereket Haileab 《Journal of African Earth Sciences》2011,59(2-3):295-312

The distribution of hominin fossil sites in the Turkana Basin, Kenya is intimately linked to the history of the Omo River, which affected the paleogeography and ecology of the basin since the dawn of the Pliocene. We report new geological data concerning the outlet channel of the Omo River between earliest Pliocene and final closure of the Turkana Basin drainage system in the latest Pliocene to earliest Quaternary. Throughout most of the Pliocene the Omo River entered the Turkana Basin from its source in the highlands of Ethiopia and exited the eastern margin of the basin to discharge into the Lamu embayment along the coast of the Indian Ocean. During the earliest Pliocene the river’s outlet was located in the northern part of the basin, where a remnant outlet channel is preserved in basalts that pre-date eruption of the Gombe flood basalt between 4.05 and 3.95 Ma. The outlet channel was faulted down to the west prior to 4.05 Ma, forming a natural dam behind which Lake Lonyumun developed. Lake Lonyumun was drained between 3.95 and 3.9 Ma when a new outlet channel formed north of Loiyangalani in the southeastern margin of the Turkana Basin. That outlet was blocked by Lenderit Basalt lava flows between 2.2 and 2.0 Ma. Faulting that initiated either during or shortly after eruption of the Lenderit Basalt closed the depression that is occupied by modern Lake Turkana to sediment and water.Several large shield volcanoes formed east of the Turkana Basin beginning by 2.5–3.0 Ma, volcanism overlapping in time, but probably migrating eastward from Mount Kulal on the eastern edge of the basin to Mount Marsabit located at the eastern edge of the Chalbi Desert. The mass of the volcanic rocks loaded and depressed the lithosphere, enhancing subsidence in a shallow southeast trending depression that overlay the Cretaceous and Paleogene (?) Anza Rift. Subsidence in this flexural depression guided the course of the Omo River towards the Indian Ocean, and also localized accumulations of lava along the margins of the shield volcanoes. Lava flows at Mount Marsabit extended across the Omo River Valley after 1.8–2.0 Ma based on estimated ages of fossils in lacustrine and terrestrial deposits, and possibly by as early as 2.5 ± 0.3 Ma based on dating of a lava flow. During the enhanced precipitation in latest Pleistocene and earliest Holocene (11–9.5 ka) this flexural depression became the site of Lake Chalbi, which was separated from Lake Turkana by a tectonically controlled drainage divide.  相似文献   

Non‐Matrix‐Matched Calibration for the Multi‐Element Analysis of Geological and Environmental Samples Using 200 nm Femtosecond LA‐ICP‐MS: A Comparison with Nanosecond Lasers     

Klaus Peter Jochum  Brigitte Stoll  Ulrike Weis  Dorrit E. Jacob  Regina Mertz‐Kraus  Meinrat O. Andreae 《Geostandards and Geoanalytical Research》2014,38(3):265-292

LA‐ICP‐MS is one of the most promising techniques for in situ analysis of geological and environmental samples. However, there are some limitations with respect to measurement accuracy, in particular for volatile and siderophile/chalcophile elements, when using non‐matrix‐matched calibration. We therefore investigated matrix‐related effects with a new 200 nm femtosecond (fs) laser ablation system (NWRFemto200) using reference materials with different matrices and spot sizes from 10 to 55 μm. We also performed similar experiments with two nanosecond (ns) lasers, a 193 nm excimer (ESI NWR 193) and a 213 nm Nd:YAG (NWR UP‐213) laser. The ion intensity of the 200 nm fs laser ablation was much lower than that of the 213 nm Nd:YAG laser, because the ablation rate was a factor of about 30 lower. Our experiments did not show significant matrix dependency with the 200 nm fs laser. Therefore, a non‐matrix‐matched calibration for the multi‐element analysis of quite different matrices could be performed. This is demonstrated with analytical results from twenty‐two international synthetic silicate glass, geological glass, mineral, phosphate and carbonate reference materials. Calibration was performed with the certified NIST SRM 610 glass, exclusively. Within overall analytical uncertainties, the 200 nm fs LA‐ICP‐MS data agreed with available reference values.  相似文献