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Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].  相似文献   
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"Debates concerning the origins and development of the late nineteenth- to early twentieth-century declines in marital fertility and infant mortality in England and Wales have been centred largely on the material provided by answers to the ?special' questions in the 1911 census. In their published form these figures have restricted researchers to an examination of large scale geographic and social class differences in the levels and rates of decline of the two phenomena. This paper outlines research conducted on a sample of individual census returns from the 1911 census. From this data it becomes clear that for Victorian and Edwardian England ?where one lived' was rather more important than ?who one was' in determining both family building strategies and the survival of those children born."  相似文献   
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Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS 14C and 210Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO4 addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the 210Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.  相似文献   
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Shallow seismic data and vibrocore information, sequence stratigraphic and faunal evidence have been used for documentation of Late Weichselian reactivation of faulting in the south central Kattegat, southern Scandinavia. The study area is situated on the Fennoscandian Border Zone, where tectonic activity has been recurrent since Early Palaeozoic time and still occurs, as shown by present earthquake activity. New data from the area south of the island of Anholt show that after deglaciation fast isostatic rebound resulted in reactivation of a NW-SE striking normal fault system. This tectonic episode is dated to a period starting shortly before 15.0 cal. ka BP and ending around 13.5 cal. ka BP, after regression had already reached a level of about 30 m b.s.l. The vertical displacement associated with the faulting was in the order of 20 m. More generally, the results support the previously reported late Weichselian sea-level highstand, which was followed by forced regression until the eustatic sea-level rise surpassed the rate of glacio-isostatic rebound in early Preboreal. Our findings further imply that drainage of the Baltic Ice Lake through the Øresund at c. 15 cal. ka BP (Bergsten & Nordberg 1992) may have been triggered by tectonic activity in this region.  相似文献   
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Tertiary continental flood basalts on Qeqertarssuaq and Nuussuaq in West Greenland contain ~3?km of picrites and variably contaminated tholeiites. The picrites are in the Naujánguit member of the Vaïgat Formation and they have 7–29?wt% MgO, La/Sm?=?0.9–2.1, and 143Nd/144Nd?=?0.51263–0.51307. They appear to have crystallised from high-Mg parental magmas (14.4–16.4?wt% MgO) with isotope and trace element ratios similar to recent Icelandic picrites. Discrete horizons of tholeiites, including the Asûk and?Kûgánguaq, have elevated SiO2 (50–58 wt%), La/Sm?=?3–7, 87Sr/86Sr?=?0.70550–0.71224, and low 143Nd/144Nd?=?0.51234–0.51174. These lavas have low Cu and Ni abundances (typically 10–50?ppm Ni or Cu), and in the case of the Asûk on Qeqertarssuaq, they contain droplets of native iron. The low Cu and Ni contents are attributed to scavenging by magmatic sulphides formed in response to crustal contamination of picritic magmas. Two contamination trends are recognised, one to a sediment end-member with high Th/Nb and Archaean model Nd ages, and the other to a meta-igneous component with high La/Sm, low Th/Nb and Rb/Nb, and Proterozoic source ages. Overall, 206Pb/204Pb varies from 16.47–21.68. Both contamination trends are associated with low Cu and Ni, and high SiO2, and it is argued that the magmatic sulphides were triggered by the increases in silica, rather than simply by the introduction of additional crustal-derived sulphur. Geochemically, the Asûk and Kûgánguaq rocks resemble the most contaminated Nadezhdinsky lavas of the Siberian Trap, which are widely regarded as the source of the Ni and Cu mineralisation in the giant Noril'sk deposits. Mass balance considerations indicate that the parental liquids to the contaminated magmas contained sufficient Ni, Cu, S and platinum group elements to form substantial magmatic sulphide deposits. However, unlike the lavas at Noril'sk, the contaminated (low Cu and Ni) West Greenland basalts are in isolated units with no evidence for a gradual recovery in Ni and Cu abundances with height in the lava column. Comparison with Noril'sk suggests that although significant quantities of metals were scavenged by sulphides in West Greenland, the metal contents of the sulphides may not have been upgraded by continued interaction with subsequent magma batches.  相似文献   
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Late- and postglacial history of the Great Belt, Denmark   总被引:3,自引:0,他引:3  
On the basis of shallow seismic records, vibrocoring, macrofossil analyses and AMS radiocarbon-dating, five stratigraphical units have been distinguished from the deepest parts of the central Great Belt (Storebælt) in southern Scandinavia. Widespread glacial deposits are followed by two lateglacial units confined to deeply incised channels and separated by an erosional boundary. Lateglacial Unit I dates from the time interval from the last deglaciation to the Allerød; lateglacial Unit II is of Younger Dryas age. Early Holocene deposits show a development from river deposits and lake-shore deposits to large lake deposits, corresponding to a rising shore level. Lake deposits are found up to 20 m below the sea floor, and the lake extended over some 200–300 km2. The early Holocene freshwater deposits are dated to the time interval c. 10900 to c. 8800 cal. yr BP and the oldest shells of marine molluscs from the Great Belt are dated to c. 8100 cal. yr BP.  相似文献   
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