Hydrogeochemical exploration for volcanic-hosted massive sulfide deposits in semi-arid Australia     

D. J. Gray  C. J. Yeats  R. R. P. Noble  N. Reid 《Australian Journal of Earth Sciences》2018,65(2):249-274

Research on hydrogeochemistry for mineral exploration for inland Australia includes development of weathering models and extensive mine-scale and regional groundwater data. Mineral saturation indices for groundwater, activity–activity plots and reaction modelling simulate weathering of volcanic-hosted massive sulfide (VHMS) deposits in deeply weathered environments. At 10 m or more below surface, dissolved O₂ is very low and other solutes such as sulfate, carbonate and nitrate are more likely oxidants. Modelling indicates that these processes differ from oxic weathering of highly eroded terrains, and provide the framework to develop robust hydrogeochemical exploration procedures in covered terrains. Sulfide weathering potentially occurs in two or more phases that effect surrounding groundwaters in differing manners. Deeper oxidative alteration of sulfides (e.g. bornite to chalcopyrite), occurring tens to hundreds of metres below surface, uses sulfate and carbonate as oxidants, causing neutral to alkaline conditions. In this zone, only pyritic massive sulfides potentially generate acidic conditions. Thus, deep sulfide-rich rocks are indicated by sulfate-depleted groundwater. Closer to the surface, sulfides are oxidised to soluble sulfates by dissolved nitrate, with much less acid production than if dissolved oxygen was the main oxidant. Thus, in shallow groundwater, sulfides are indicated by sulfate enrichment and nitrate depletion. Elements are released from sulfides and wall rocks by acid or alkaline conditions. The derived FeS (pH–Eh + Fe + Mn) and AcidS (Li + Mo + Ba + Al) indices distinguish sulfide systems through tens of metres of cover. VHMS systems are distinguished from other non-economic sulfide deposits where there is little transported cover, using various dissolved elements, including Zn, Pb and Cu. Elsewhere, ‘patchiness’ and limited aerial extent of metal signals are due to adsorption effects, that intensify with depth. Other elements such as Mn and Co have lesser diminution effects, but are less selective indicators for VHMS. There is exploration potential for elements such as Pt or Ag. These varying sulfide indicators have moderate utility, even for large-scale (～5 km spacing) sampling. Results indicate that hydrogeochemistry can add value to greenfields exploration for VHMS ore deposits in deeply weathered terrains. It is also moderately successful at indicating the presence of sulfide-rich systems (whether magmatic or hydrothermal) under >100 m cover, thus providing a rapid and cost-effective regional prospectivity tool for deeply buried terrains. Such mineral exploration tools will encourage exploration investment for more difficult regions of Australia and in other deeply weathered regions of the world.  相似文献   

Relationships between magmatism and deformation in northern Yorke Peninsula and southeastern Proterozoic Australia     

A. Brotodewo  C. J. Tiddy  A. Reid  C. Wade  C. Conor 《Australian Journal of Earth Sciences》2018,65(5):619-641

The ca 1600–1580 Ma time interval is recognised as a significant period of magmatism, deformation and mineralisation throughout eastern Proterozoic Australia. Within the northern Yorke Peninsula in South Australia, this period was associated with the emplacement of multiple phases of the Tickera Granite, an intensely foliated quartz alkali-feldspar syenite, a leucotonalite and an alkali-feldspar granite. These granites belong to the broader Hiltaba Suite that was emplaced at shallow crustal levels throughout the Gawler Craton. Geochemical and isotopic analysis suggests these granite phases were derived from a heterogeneous source region. The syenite and alkali-feldspar granite were derived from similar source regions, likely the underlying ca 1850 Ma Donington Suite and/or the ca 1750 Ma Wallaroo Group metasediments with some contamination from an Archean basement. The leucotonalite is sourced from a similar but more mafic/lower crustal source. Phases of the Tickera Granite were emplaced synchronously with deformation that resulted in development of a prominent northeast-trending structural grain throughout the Yorke Peninsula region. This fabric is associated with composite events resulting from folding, shearing and faulting within the region. The intense deformation and intrusion of granites within this period resulted in mineralisation throughout the region, as seen in Wheal Hughes and Poona mines. The Yorke Peninsula shares a common geological history with the Curnamona Province, which was deformed during the ca 1600–1585 Ma Olarian Orogeny, and resulted in development of early isoclinal and recumbent folds overprinted by an upright fold generation, a dominant northeast-trending structural grain, mineralisation, and spatially and temporally related intrusions. This suggests correlation of parts of the Gawler Craton with the Curnamona Province, and that the Olarian Orogeny also affected the southeastern Gawler Craton.  相似文献   

Sedimentary basin formation associated with a silicic large igneous province: stratigraphy and provenance of the Mesoproterozoic Roopena Basin,Gawler Range Volcanics     

S. Curtis  C. Wade  A. Reid 《Australian Journal of Earth Sciences》2018,65(4):447-463

The Mesoproterozoic Gawler Silicic Large Igneous Province (SLIP) in the Gawler Craton and Curnamona Province, southern Australia, comprises extensive felsic and lesser mafic volcanic sequences, with only limited sedimentary successions. The Roopena Basin is a rare example of a synvolcanic sedimentary basin that formed within the Gawler SLIP in the eastern Gawler Craton. It is a north–south-trending basin with a preserved area of 75 km², bound by the Roopena and Wizzo Well faults, and contains three units of the lower Gawler Range Volcanics; the Angle Dam Dacite, Fresh Well Formation and Roopena Basalt. The Angle Dam Dacite is a porphyritic lava and the oldest part of the volcanic succession, directly overlying basement. The Fresh Well Formation overlies the Angle Dam Dacite or basement, comprises three coarsening-upwards volcaniclastic packages of claystone, siltstone, fine-grained to coarse-grained lithic sandstone and conglomerate deposited in a fluvio-lacustrine setting, and contains three tuff members. The Roopena Basalt is interlayered with the Fresh Well Formation, and comprises auto-brecciated lavas that exhibit only local interaction with water or wet sediment. Sharp basal contacts of the prograding packages within the Fresh Well Formation provide evidence of rapid flooding events within the basin. New detrital zircon geochronology of a sandstone within the Fresh Well Formation yielded a maximum depositional age of ca 1580 Ma, with provenance dominated by felsic volcanic units of the 1635–1605 Ma St Peter Suite. Sedimentation in the Gawler SLIP appears to have occurred in isolated basins with limited areal extent. It was largely restricted to the eastern Gawler Craton, and as well as the Roopena Basin, and includes similar basins at the Olympic Dam and Prominent Hill iron oxide–copper–gold ± uranium (IOCG ± U) deposits. The coincidence of sedimentation and mafic volcanism in the eastern Gawler Craton suggests that this region underwent extension at this time, although high-temperature metamorphism and compressional deformation occurred in some parts of the Gawler Craton and Curnamona Province synchronous with the Gawler SLIP. The Roopena Basin sedimentary rocks and underlying basement contain hematite–chlorite–sericite–white mica assemblages, permissive of hematite-style IOCG mineral deposits; however, no significant ore deposit has yet been discovered in the Roopena Basin.  相似文献   

An apatite U-Pb thermal history map for the northern Gawler Craton,South Australia     

James W.Hall  Stijn Glorie  Anthony J.Reid  Samuel C.Boone  Alan S.Collins  ANDrew Gleadow 《地学前缘(英文版)》2018,9(5):1293-1308

Apatite U-Pb thermochronology was applied to granitoid basement samples across the northern Gawler Craton to unravel the Proterozoic, post-orogenic, cooling history and to examine the role of major fault zones during cooling. Our observations indicate that cooling following the ~2500 Ma Sleaford Orogeny and ~1700 Ma Kimban Orogeny is restricted to the Christie and Wilgena Domains of the central northern Gawler Craton. The northern Gawler Craton mainly records post-Hiltaba Event(~1590 Ma) U-Pb cooling ages. Cooling following the ~1560 Ma Kararan Orogeny is preserved within the Coober Pedy Ridge,Nawa Domain and along major shear zones within the south-western Fowler Domain. The Nawa Domain samples preserve U-Pb cooling ages that are 150 Ma younger than the samples within the Coober Pedy Ridge and Fowler Domain, indicating that later(~1300 Ma) fault movement within the Nawa Domain facilitated cooling of these samples, caused by arc collision in the Madura Province of eastern Western Australia. When compared to~(40)Ar/~(39) Ar from muscovite, biotite and hornblende, our new apatite U-Pb ages correlate well, particularly in regions of higher data density. Our data also preserve a progressive younging of U-Pb ages from the nucleus of the craton to the periphery with a stark contrast in U-Pb ages across major structures such as the Karari Shear Zone and the Southern Overthrust, which indicates the timing of reactivation of these major crustal structures. Although this interpolation was based solely on thermochronological data and did not take into account structural or other geological data, these maps are consistent with the structural architecture of the Gawler Craton and reveal the thermal footprint of known tectonic and magmatic events in the Gawler Craton.  相似文献   

Effect of changes in fine‐grained matrix on bedload sediment transport in a gravel‐bed river     

Ronel Barzilai  Jonathan B. Laronne  Ian Reid 《地球表面变化过程与地形》2013,38(5):441-448

While clay and silt matrices of gravel‐bed rivers have received attention from ecologists concerned variously with the deteriorating environments of benthic and hyporheic organisms, their impact on sediment entrainment and transport has been explored less. A recent increase of such a matrix in the bed of Nahal Eshtemoa, an ephemeral river of the northern Negev, has more than doubled the boundary shear stress needed to initiate bedload, from 7 N m^‐2 (τ^* = 0.027) during the flash floods of 1991–2001 to 15 N m^‐2 (τ^* = 0.059) during those of 2008–2009. The relation between bedload flux and boundary shear stress continues to be well‐defined, but it is displaced. The matrix now contains a significant amount of silt and clay size material. The reasons for the increased entrainment threshold of bedload are explored. Large‐scale laser scanning of the dry bed reveals a reduction in grain‐scale morphological roughness, while artificial in situ tests of matrix integrity indicate considerable cohesion. The implications for adopting bed material sampling strategies that account for matrix development are assessed. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Sulfide saturation history of the Stillwater Complex, Montana: chemostratigraphic variation in platinum group elements   总被引：1，自引：0，他引：1  

Reid R. Keays  Peter C. Lightfoot  Paul R. Hamlyn 《Mineralium Deposita》2012,47(1-2):151-173

A platinum group element (PGE) investigation of a 5.3?km-thick stratigraphic section of the Stillwater Complex, Montana was undertaken to refine and test a geochemical technique to explore for platiniferous horizons in layered mafic/ultramafic complexes. PGE, Au, major, and trace elements were determined in 92 samples from outcrops along traverses in the Chrome Mountain and Contact Mountain areas in the western part of the Stillwater Complex where the J-M reef occurs ～1,460?m above the floor of the intrusion. A further 29 samples from a drill hole cored in the immediate vicinity of the J-M reef were analyzed to detail compositional variations directly above and below the J-M reef. Below the J-M reef, background concentrations of Pt (10?ppb) and Pd (7?ppb) are features of peridotites with intermediate S concentrations (mostly 100–200?ppm) and rocks from the Bronzitite, Norite I, and Gabbronorite I zones (mostly <100?ppm S). A sustained increase in S abundance commences at the J-M reef and continues to increase and peaks in the center of the 600?m-thick middle banded series. Over this same interval, Pt, Pd, and Au are initially elevated and then decrease in the order Pd?>?Pt?>?Au. Within the middle and upper banded series, S abundances fluctuate considerably, but exhibit an overall upward increase. The behavior of these elements records periodic sulfide saturation during deposition of the Peridotite zone, followed by crystallization under sulfide-undersaturated conditions until saturation is achieved at the base of the J-M reef. Following formation of the reef, sulfide-saturated conditions persisted throughout the deposition of most of the remaining Lower Layered Series. This resulted in a pronounced impoverishment in PGE abundance in the remaining magma, a condition that continued throughout deposition of the remainder of a succession, which is characterized by very low Pt (1.5?ppb) and Pd (0.7?ppb) abundances. Because only unmineralized rock was selected for study in the 5.3?km-thick section, the results provide an unbiased picture of the variation in background PGE levels during crystallization of the Stillwater Complex. In contrast, the variations in the drill core samples through the reef provide a detailed record of ore formation. Plots of Pt, Pd, Pd/S, and Pt?+?Pd as a function of stratigraphic height in the intrusion show that the location of the J-M reef is defined by an abrupt change in these concentrations and ratios. Although this is the most abrupt change, three other anomalies in PGE abundance and ratios are apparent in the profiles and coincide with known laterally extensive sub-economic sulfide concentrations above the J-M reef. The uppermost of these is the PGE-bearing Picket Pin sulfide horizon. The relative ease with which mineralized horizons can be pinpointed in these diagrams indicates that a similar approach could be used in exploration programs in other ultramafic/mafic intrusions. Our observations exclude the possibilities of either magma mixing within the Stillwater chamber or the fluxing of a volatile-rich fluid as the mechanisms responsible for the genesis of the J-M reef. Rather, our data indicate that the J-M reef formed from a parental magma that was strongly enriched in PGE; this magma likely formed at depth below the Stillwater magma chamber by the interaction of the parental magma with S-rich meta-sedimentary rocks, followed by the re-dissolution of these sulfides in the Stillwater magma.  相似文献   

S saturation history of Nain Plutonic Suite mafic intrusions: origin of the Voisey’s Bay Ni–Cu–Co sulfide deposit, Labrador, Canada     

Peter C. Lightfoot  Reid R. Keays  Dawn Evans-Lamswood  Robert Wheeler 《Mineralium Deposita》2012,47(1-2):23-50

The Voisey’s Bay deposit is hosted in a 1.34-Ga intrusion composed of troctolite, olivine gabbro, and ferrogabbro. The sulfide mineralization is associated with magmatic breccias that are enveloped by weakly mineralized olivine gabbros and troctolites, and also occurs as veins along structures in adjacent paragneiss. A dyke is connected to the base of the north wall of the Eastern Deeps Intrusion, and the entry point of this dyke into the chamber is the locus of the Eastern Deeps nickel sulfide deposit. A detailed exploration in the area between the Eastern Deeps and the Ovoid has shown that these intrusions and ore deposits are connected by a splayed dyke. The Eastern Deeps Deposit is surrounded by a halo of moderately to weakly mineralized variable-textured troctolite (VTT) that reaches a maximum thickness above the axis of the Eastern Deeps Deposit along the northern wall of the Eastern Deeps Intrusion. The massive sulfides and breccia sulfides are petrologically and chemically different when compared to the disseminated sulfides in the VTT, and there is a marked break in Ni tenor of sulfide between the two. Sulfides hosted in the dyke tend to have low metal tenors ([Ni]₁₀₀?=?2.5–3.5%), sulfides in Eastern Deeps massive and breccia ores have intermediate Ni tenors ([Ni]₁₀₀?=?3.5–4%), and disseminated sulfides in overlying rocks have high Ni tenors ([Ni]₁₀₀?=?4–8%). Four principal processes control the compositions of the Voisey’s Bay sulfides. Coarse-grained loop-textured ores consisting of pyrrhotite crystals separated by chalcopyrite and pentlandite exhibit a two orders of magnitude variation in the Pd/Ir ratio which is due to mineralogical variations where pentlandite is enriched in Pd and Ir is dispersed throughout the mineral assemblage. A decrease in Ir and Rh from the margin of the Ovoid toward cubanite-rich parts at the central part of the Ovoid is consistent with fractionation of the sulfide from the margins toward the center of the Ovoid. The Ovoid ores have higher Ni and Pd tenor than the Eastern Deeps massive sulfides; this is consistent with both a higher R factor and greater degree of silicate parental magma evolution in the Ovoid than the Eastern Deeps. The disseminated sulfides surrounding the Eastern Deeps deposit have some of the highest Ni and Pd tenors at Voisey’s Bay, which are indicative of not only more primitive magmas but also higher R factors than the Ovoid or the Eastern Deeps. VTT and normal-textured troctolite of the Eastern Deeps that contain trace sulfide have 0.1–3?ppb Pt and 0.1–3?ppb Pd, whereas weakly to heavily mineralized variable troctolites in the same unit have one to two orders of magnitude higher abundances of Pt and Pd. Troctolites and olivine gabbros from other parts of the Voisey’s Bay Intrusion and other Nain Plutonic Suite Intrusions, including the Kiglapait, Newark Bay, Barth Island, Mushua, and Nain Bay South Intrusion, also have low platinum group element abundances. Although it is possible that this is a signature of a widespread sulfide saturation event that pre-dated ore formation at Voisey’s Bay, it is more likely that platinum group element (PGE) depletion is a product of the source melting process where low degrees of melting resulted in the retention of PGE in the mantle source. If so, this indicates that PGE depletion should be used with caution as an exploration tool in the Nain Plutonic Suite.  相似文献   

Relationship between Late Pleistocene sea‐level variations,carbonate platform morphology and aragonite production (Maldives,Indian Ocean)     

ANDREAS PAUL  JOHN J. G. REIJMER  JÖRN FÜRSTENAU  HANNO KINKEL  CHRISTIAN BETZLER 《Sedimentology》2012,59(5):1640-1658

A piston core from the Maldives carbonate platform was investigated for carbonate mineralogy, grain‐size distributions, calcium carbonate content and organic carbon. The sedimentary record was linked to Late Pleistocene sea‐level variations, using an age model based on oxygen isotopes obtained from planktonic foramanifera, nannofossil biostratigraphy and ¹⁴C age determinations. The correlation between the sedimentary record and Late Pleistocene sea‐level showed that variations in aragonite and mud during the past 150 000 years were clearly related to flooding and sea floor exposure of the main lagoons of the atolls of the Maldives carbonate platform. Platform flooding events were characterized by strongly increased deposition of aragonite and mud within the Inner Sea of the Maldives. Exposure events, in contrast, can be recognized by rapid decreases in the values of both proxy records. The results show that sediments on the Maldives carbonate platform contain a continuous record of Pleistocene sea‐level variations. These sediments may, therefore, contribute to a better understanding of regional and even global sea‐level changes, and yield new insights into the interplay between ocean currents and carbonate platform morphology.  相似文献   

Natural formation processes and the archaeological record,D.T. Nash and M.D. Petraglia (Eds.), 1987, BAR International Series 352, 204 p., $28.00 (including exchange charges) (paperbound)     

C. Reid Ferring 《Geoarchaeology》1989,4(2):188-191

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Rates of fluvial sedimentation: Implications for archaeological variability     

C. Reid Ferring 《Geoarchaeology》1986,1(3):259-274

Rates of fluvial sedimentation exhibit spatial and temporal variability that is important with respect to the study of prehistoric archaeological sites. Sedimentation rates within fluvial basins vary in response to internal dynamics, geomorphic controls, and external factors including climate and tectonics. Fluvial rates of sedimentation may be estimated using sedimentary, pedogenic, biogenic, and radiometric evidence. Holocene rates of sedimentation vary by three orders of magnitude, as shown by radiometric data from numerous localities in North America. Sedimentation rates define rates of matrix accumulation in archaeological sites. These act as controls on site construction and site modification. Artifact densities, spatial patterning, and preservation are all conditioned by rates of matrix accumulation. These dimensions of prehistoric sites are critical to the evaluation of variability within and between archaeological sites and to the study of past settlement/subsistence systems.  相似文献