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31.
The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S2 generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S2 generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S2 generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen. 相似文献
32.
Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which
makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization
of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary
to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms
for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model
appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the
random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions
correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they
are layer specific and include uncertainty caused by using variance estimates. 相似文献
33.
The seasonality of physical, chemical, and biological water variables is a major characteristic of temperate, dimictic lakes.
Yet, few investigations have considered the potential information that is encoded in seasonal dynamics with respect to the
paleolimnological record. We used a one-year sequence of diatoms obtained from sediment traps and water samples, as well as
the sedimentary diatom record covering the past ca. 1000 years in Bates Pond, Connecticut (USA), to investigate which variables
influence the seasonal distribution of diatoms and how this can be used for the interpretation of the fossil record. The seasonal
patterns in diatom assemblages were related to stratification and, to a lesser extent, to nitrate, silica, and phosphorus.
During mixing periods in spring and autumn, both planktonic and benthic species were collected in the traps, while few lightly
silicified, spindle-shaped planktonic diatoms dominated during thermal stratification in summer. Changes in fossil diatom
assemblages reflected human activity in the watershed after European settlement and subsequent recovery in the 20th century.
A long-term trend in diatom assemblage change initiated before European settlement was probably related to increased length
of mixing periods during the Little Ice Age, indicated by the increase of taxa that presently grow during mixing periods and
by application of a preliminary seasonal temperature model. We argue that the analysis of seasonal diatom dynamics in temperate
lakes may provide important information for the refinement of paleolimnological interpretations. However, investigations of
several lakes and years would be desirable in order to establish a more robust seasonal data set for the enhancement of paleolimnological
interpretations. 相似文献
34.
35.
韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例 总被引:6,自引:0,他引:6
韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例,通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比,确定等比线斜率,探讨韧性变形对岩石体积和成分变异的影响。计算结果表明,在糜棱岩化过程中,糜棱岩化花岗岩体积亏损21%,花岗质糜棱岩体积亏损31%。质量平衡计算结果和等比线图表明,韧;陛剪切作用导致SiO2,流失量最大,A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失,显示出较强的活动性,MnO、P2O5、Sc位于等比线上或附近,表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的,不活动组分的变异是体.积亏损造成的。 相似文献
36.
Evidence for compressionally induced high subsidence rates in the Kurile Basin (Okhotsk Sea) 总被引:1,自引:0,他引:1
Boris V. Baranov Reinhard Werner Kaj A. Hoernle Ira B. Tsoy Paul van den Bogaard Igor A. Tararin 《Tectonophysics》2002,350(1)
A combined volcanological, geochemical, paleo-oceanological, geochronological and geophysical study was undertaken on the Kurile Basin, in order to constrain the origin and evolution of this basin. Very high rates of subsidence were determined for the northeastern floor and margin of the Kurile Basin. Dredged volcanic samples from the Geophysicist Seamount, which were formed under subaerial or shallow water conditions but are presently located at depths in excess of 2300 m, were dated at 0.84±0.06 and 1.07±0.04 Ma with the laser 40Ar/39Ar single crystal method, yielding a minimum average subsidence rate of 1.6 mm/year for the northeast basin floor in the Quaternary. Trace element and Sr–Nd–Pb isotope data from the volcanic rocks show evidence for contamination within lower continental crust and/or the subcontinental lithospheric mantle, indicating that the basement presently at 6-km depth is likely to represent thinned continental crust. Average subsidence rates of 0.5–2.0 mm/year were estimated for the northeastern slope of the Kurile Basin during the Pliocene and Quaternary through the determination of the age and paleo-environment (depth) of formation of sediments from a canyon wall. Taken together, the data from the northeastern part of the Kurile Basin indicate that subsidence began in or prior to the Early Pliocene and that subsidence rates have increased in the Quaternary. Similar rates of subsidence have been obtained from published studies on the Sakhalin Shelf and Slope and from volcanoes in the rear of the Kurile Arc. The recent stress field of the Kurile Basin is inferred from the analysis of seismic activity, focal mechanism solutions and from the structure of the sedimentary cover and of the Alaid back-arc volcano. Integration of these results suggests that compression is responsible for the rapid subsidence of the Kurile Basin and that subsidence may be an important step in the transition from basin formation to its destruction. The compression of the Kurile Basin results from squeezing of the Okhotsk Plate between four major plates: the Pacific, North American, Eurasian and Amur. We predict that continued compression could lead to subduction of the Kurile Basin floor beneath Hokkaido and the Kurile Arc in the future and thus to basin closure. 相似文献
37.
新时期我国区域经济地理学发展问题初探 总被引:4,自引:0,他引:4
我国新时期的区域经济地理学在取得全面发展的同时,在理论体系,研究方法和实践领域等方面还需要进一步的发展,文章根据学习和实践区域经济地理学的体会,初步提出基础理论和应用理论,思维方法和技术方法等方面发展见解,并指出区域创新系统和国际经济技术合作等学科应注意拓展的重要实践领域,最后提出我国区域经济地理学科发展的建议。 相似文献
38.
39.
成都市民消费结构与休闲活动关系研究 总被引:6,自引:0,他引:6
城市居民消费水平,消费结构会影响其休闲消费能力,消费意愿,消费方式,消费态度和休闲时空结构,文章以成都市7个城区歌舞,茶棋牌,电影及城市公园休闲活动调查为基础,探讨了城市居民消费结构及其变化与休闲活动特征的关系。研究结果表明,城市居民消费结构的改变对歌舞,茶棋牌娱乐活动影响最大。 相似文献
40.