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31.
While the presence of steroid estrogens in the environment has become a major environmental and health concern, their occurrence in coastal sediments remains poorly characterized. In this study, we measured the levels of three natural (estrone, 17β-estradiol, estriol) and one synthetic (17α-ethinylestradiol) estrogens in 54 coastal sediment samples collected from nine locations off central-southern Chile. Steroid estrogens were found in every sample. Remarkably high levels of 17α-ethinylestradiol were detected, reaching up to 48.14 ng/g dry weight. As a result, the global estrogenic loads were estimated to be high at all sites. Interestingly, they were found to correlate with the size of human populations served by sewage plants. Our study indicates that 17α-ethinylestradiol may accumulate in coastal sediments. The possible impact of this highly potent synthetic estrogen on the biota of the marine ecosystem off central-south Chile and on human health remains an open question.  相似文献   
32.
Rodrigo de Freitas Lagoon, located in the Rio de Janeiro City, receives several types of polluted discharges. The knowledge of the sediment microfauna correlated with heavy metal and organic matter concentrations could supply important data about the conditions of the lagoon. The benthic foraminiferal assemblage presented larger diversity and more abundant samples in the lagoon entrance than in the inner area. The Ammonia tepida - Elphidiumexcavatum foraminiferal assemblage is characterized by dwarf, corroded and weak organisms. Agglutinated species were found only near the entrance. Low abundance values and sterility of five samples in the inner area (north/northeast) can be caused by high levels of heavy metals and organic matter. A. tepida shows negative correlation with increasing heavy metals values. PAHs and coprostanol high indexes, and the absence or low presence of microfauna in samples around the lagoon margin confirm illegal flows from gas stations and domestic sewage.  相似文献   
33.
Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ13C values decreased between 0 and 4 m, whereas δ15N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.  相似文献   
34.
The explosive behavior and the rheology of lavas in basaltic volcanoes, usually driven by differentiation, can also be significantly affected by the kinetics of magma degassing in the upper portion of the feeding system. The complex eruption of 2001 at Mt. Etna, Italy, was marked by two crucial phenomena that occurred at the Laghetto vent on the southern flank of the volcano: 1) intense explosive activity and 2) at the end of the eruption, emission of a lava flow with higher viscosity than flows previously emitted from the same vent. Here, we investigate the hypothesis that these events were driven by the injection of volatile-rich magma into the feeding system. The input and mixing of this magma into a reservoir containing more evolved magma had the twofold effect of increasing 1) the overall concentration of volatiles and 2) their exsolution with consequent efficient vesiculation and degassing. This led to an explosive stage of the eruption, which produced a ~75-m-high cinder cone. Efficient volatile loss and the consequent increase of the liquidus temperature brought about the nucleation of Fe-oxides and other anhydrous crystalline phases, which significantly increased the magma viscosity in the upper part of the conduit, leading to the emission of a high viscosity lava flow that ended the eruption. The 2001 eruption has offered the opportunity to investigate the important role that input of volatile-rich magma may exert in controlling not only the geochemical features of erupted lavas but also the eruption dynamics. These results present a new idea for interpreting similar eruptions in other basaltic volcanoes and explaining eruptions with uncommonly high explosivity when only basic magmas are involved.  相似文献   
35.
We examine a model for the expected contributions to the soft X-ray background (SXRB) due to bremsstrahlung and re-combination radiation of gas, enriched with heavy elements, located in groups of galaxies taken from Tully'sCatalog of Nearby Groups of Galaxies. It is shown that the contribution to the SXRB of groups of galaxies can explain up to 20% of the observed flux depending on the chemical composition and ratio of emitting mass to assumed virial mass.  相似文献   
36.
The 2/1 mean motion resonance with Jupiter, intersecting the main asteroid belt at ≈3.27  au, contains a small population of objects. Numerical investigations have classified three groups within this population: asteroids residing on stable orbits (i.e. Zhongguos), those on marginally stable orbits with dynamical lifetimes of the order of 100 Myr (i.e. Griquas), and those on unstable orbits. In this paper, we reexamine the origin, evolution and survivability of objects in the 2/1 population. Using recent asteroid survey data, we have identified 100 new members since the last search, which increases the resonant population to 153. The most interesting new asteroids are those located in the theoretically predicted stable island A, which until now had been thought to be empty. We also investigate whether the population of objects residing on the unstable orbits could be resupplied by material from the edges of the 2/1 resonance by the thermal drag force known as the Yarkovsky effect (and by the YORP effect, which is related to the rotational dynamics). Using N -body simulations, we show that test particles pushed into the 2/1 resonance by the Yarkovsky effect visit the regions occupied by the unstable asteroids. We also find that our test bodies have dynamical lifetimes consistent with the integrated orbits of the unstable population. Using a semi-analytical Monte Carlo model, we compute the steady-state size distribution of magnitude   H < 14  asteroids on unstable orbits within the resonance. Our results provide a good match with the available observational data. Finally, we discuss whether some 2/1 objects may be temporarily captured Jupiter-family comets or near-Earth asteroids.  相似文献   
37.
Repeated time-variable redshifted absorption features in the spectrum of β Pictoris (β Pic) have been attributed to comet-like bodies falling toward the star, when evaporating in its immediate vicinity. This model explains now a large number of observational characteristics, but the exact mechanism that could generate these numerous star-grazers is still controversial, even if planetary perturbations are thought to be the basic process. The different models proposed up to now are here reviewed, and we discuss in particular a recent one, involving the effect of secular resonances in the β Pic system. We stress that it seems highly improbable that such a mechanism could apply to the β Pic case, because the extremely strong power of secular resonances is connected to the very specific structure of the Solar System. Therefore, the secular resonance mechanism is highly non-generic. Conversely, we propose a model involving the eccentricity-pumping effect of mean-motion resonances with a massive planet on a moderately eccentric orbit. We show in particular that the 4:1 mean-motion resonance is a very active source of star-grazers as soon as the eccentricity of the perturbing planet is ?0.05, while the 3:1 mean-motion resonance is less efficient. We stress that this mechanism is very generic. These theoretical predictions are confirmed by numerical integrations using the Extended Schubart Integrator. The time-scale of the process is discussed, and we show that if the eccentricity of the perturbing planet fluctuates, due to secular perturbations, this time-scale is compatible with the age of β Pic's system.  相似文献   
38.
On the basis of the general theory of Hamiltonian systems, we consider the relationship between Lyapunov times and macroscopic diffusion times. We find out that there are two regimes: the Nekhoroshev regime and the resonant overlapping regime. In the first case the diffusion time is exponentially long with respect to Lyapunov times. In the second case, the relationship is polynomial although we do not find any theoretical reason for the existence of a universal power law. We show numerical evidences which confirm our theoretical considerations.  相似文献   
39.
The sea star Asterina stellifera has declined during the last decade and is currently abundant only in the southern limit of its former range. We surveyed this population over 5 years to model individual growth and explore the relationship of changes in local abundance with variation in environmental factors and the reproductive status of individuals. Our results show that A. stellifera is a species with slow growth and a relatively long lifespan. Contrary to expectations for temperate species, growth rates were fairly constant through the year and therefore models including seasonal oscillations were inappropriate. The abundance of this species increased significantly from early spring to early summer, likely due to augmented activity and small‐scale aggregation during the reproductive season that affected our estimates of abundance. No significant recruitment occurred during the 5 years studied. The lack of recruitment during long periods and the slow individual growth rates make A. stellifera particularly vulnerable to local extinction. This study was performed prior to the arrival in the study area of the invasive kelp Undaria pinnatifida and side‐gilled sea slug Pleurobranchaea maculata, species that threaten the community structure where A. stellifera lives. Therefore, the information reported here will be essential to assessing the impacts of these exotic species on this sea star population.  相似文献   
40.
Although failures and successes in fisheries management are related to decision making processes, these are rarely analyzed in detail and even less often following quantitative or semi-quantitative approaches. Herein, we study the decision making process for Chile's most important fisheries using a binary decision model. This model evaluates the probability that an annual total allowable catch (TAC) will or will not be modified by the National Fisheries Council (NFC) based on biological, economic, and social factors. We also analyze some aspects of individual voting, particularly whether the members vote against or abstain from voting on the proposed TAC and if they prioritize resource conservation objectives. Our results indicate that the risk of over exploitation for many important stocks in Chile is aggravated by failures at the decision making level: the scientifically recommended TACs for those fisheries that generate higher levels of employment and have greater economic value are normally increased. This analysis shows that the NFC has clearly prioritized short-term economic and social objectives over resource conservation goals. We discuss the need to adjust the composition and functioning of the NFC in order to ensure long-term sustainability of the fisheries.  相似文献   
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