Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment          下载免费PDF全文

Zanist Q. Hama‐Aziz  Kevin M. Hiscock  Richard J. Cooper 《水文研究》2017,31(6):1371-1381

Indirect nitrous oxide (N₂O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N₂O emissions from soils. In this study, dissolved N₂O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N₂O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N₂O emissions to the atmosphere. Soil texture was found to significantly influence field drain N₂O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L^?1) being greater than drains in sandy loam soils (4.0 μg N L^?1). Soil texture also impacted upon the relationships between field drain N₂O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO₃) and nitrite (NO₂) concentrations), highlighting possible differences in N₂O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N₂O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N₂O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N₂O concentrations, whereas higher N₂O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N₂O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.  相似文献   

Geochemical Characterization of Bolivian Formative Earthen Architecture by Wavelength‐Dispersive X‐ray Fluorescence     

Melissa A. Goodman‐Elgar  Nichole S. Bettencourt  Richard Conrey 《Geoarchaeology》2015,30(1):32-58

In this study, we employ wavelength‐dispersive X‐ray fluorescence (WDXRF) to characterize construction materials from Formative civic architecture (1000 B.C.E.–C.E. 400), ethnographic mudbricks, and off‐site controls from the Taraco Peninsula, Bolivia. The preparation of earthen construction materials for civic buildings can shed light on aspects of community development such as labor organization, resource management, and architectural technologies. We apply geochemical results to reconstructing how public buildings were made as communities moved toward socio‐political complexity in this region. However, there are few geochemical studies in the Andes, and little prior scientific analysis of earthen architecture. We therefore tested the efficacy of WDXRF for this region, and developed control materials. Our archaeological samples were selected from two Formative villages, Chiripa and Kala Uyuni. In this study, we performed WDXRF analyses on 63 archaeological and control samples including archaeological floors, walling, plasters, and mortars, as well as contemporary ethnographic walling and topsoils. Elemental signatures for 28 elements clearly distinguished the archaeological flooring, walling, plaster, and mortars from ethnographic and off‐site controls. More subtle variations were detected that distinguish study sites and the different material types. Laboratory‐calibrated multi‐element XRF effectively supports efforts to reconstruct the pathways to social complexity in the Titicaca Basin.  相似文献   

Building a sustained climate assessment process     

James L. Buizer  Kirstin Dow  Mary E. Black  Katharine L. Jacobs  Anne Waple  Richard H. Moss  Susanne Moser  Amy Luers  David I. Gustafson  T.C. Richmond  Sharon L. Hays  Christopher B. Field 《Climatic change》2016,136(1):23-37

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Sulfur isotope and trace element systematics of zoned pyrite crystals from the El Indio Au–Cu–Ag deposit,Chile     

Dominique Tanner  Richard W. Henley  John A. Mavrogenes  Peter Holden 《Contributions to Mineralogy and Petrology》2016,171(4):33

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Metal-rich fluid inclusions provide new insights into unconformity-related U deposits (Athabasca Basin and Basement,Canada)     

Antonin Richard  Michel Cathelineau  Marie-Christine Boiron  Julien Mercadier  David A. Banks  Michel Cuney 《Mineralium Deposita》2016,51(2):249-270

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Back Analysis of Rock Mass Displacements Around a Deep Shaft Using Two- and Three-Dimensional Continuum Modeling     

Hossein Rafiei Renani  C. Derek Martin  Richard Hudson 《Rock Mechanics and Rock Engineering》2016,49(4):1313-1327

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A comprehensive approach from the raw and normalized anomalies to the analysis and prediction of the Beijing extreme rainfall on July 21, 2012     

Ning Jiang  Weihong Qian  Jun Du  Richard H. Grumm  Jiaolan Fu 《Natural Hazards》2016,84(3):1551-1567

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Spatial and temporal constraints on regional-scale groundwater flow in the Pampa del Tamarugal Basin,Atacama Desert,Chile   总被引：1，自引：0，他引：1  

Richard S. Jayne  Ryan M. Pollyea  Justin P. Dodd  Elizabeth J. Olson  Susan K. Swanson 《Hydrogeology Journal》2016,24(8):1921-1937

Aquifers within the Pampa del Tamarugal Basin (Atacama Desert, northern Chile) are the sole source of water for the coastal city of Iquique and the economically important mining industry. Despite this, the regional groundwater system remains poorly understood. Although it is widely accepted that aquifer recharge originates as precipitation in the Altiplano and Andean Cordillera to the east, there remains debate on whether recharge is driven primarily by near-surface groundwater flow in response to periodic flood events or by basal groundwater flux through deep-seated basin fractures. In addressing this debate, the present study quantifies spatial and temporal variability in regional-scale groundwater flow paths at 20.5°S latitude by combining a two-dimensional model of groundwater and heat flow with field observations and δ¹⁸O isotope values in surface water and groundwater. Results suggest that both previously proposed aquifer recharge mechanisms are likely influencing aquifers within the Pampa del Tamarugal Basin; however, each mechanism is operating on different spatial and temporal scales. Storm-driven flood events in the Altiplano readily transmit groundwater to the eastern Pampa del Tamarugal Basin through near-surface groundwater flow on short time scales, e.g., 10⁰–10¹ years, but these effects are likely isolated to aquifers in the eastern third of the basin. In addition, this study illustrates a physical mechanism for groundwater originating in the eastern highlands to recharge aquifers and salars in the western Pampa del Tamarugal Basin over timescales of 10⁴–10⁵ years.  相似文献   

Why GPS makes distances bigger than they are   总被引：1，自引：0，他引：1  

Peter Ranacher  Richard Brunauer  Wolfgang Trutschnig  Stefan Van der Spek  Siegfried Reich 《International journal of geographical information science》2016,30(2):316-333

Global navigation satellite systems such as the Global Positioning System (GPS) is one of the most important sensors for movement analysis. GPS is widely used to record the trajectories of vehicles, animals and human beings. However, all GPS movement data are affected by both measurement and interpolation errors. In this article we show that measurement error causes a systematic bias in distances recorded with a GPS; the distance between two points recorded with a GPS is – on average – bigger than the true distance between these points. This systematic ‘overestimation of distance’ becomes relevant if the influence of interpolation error can be neglected, which in practice is the case for movement sampled at high frequencies. We provide a mathematical explanation of this phenomenon and illustrate that it functionally depends on the autocorrelation of GPS measurement error (C). We argue that C can be interpreted as a quality measure for movement data recorded with a GPS. If there is a strong autocorrelation between any two consecutive position estimates, they have very similar error. This error cancels out when average speed, distance or direction is calculated along the trajectory. Based on our theoretical findings we introduce a novel approach to determine C in real-world GPS movement data sampled at high frequencies. We apply our approach to pedestrian trajectories and car trajectories. We found that the measurement error in the data was strongly spatially and temporally autocorrelated and give a quality estimate of the data. Most importantly, our findings are not limited to GPS alone. The systematic bias and its implications are bound to occur in any movement data collected with absolute positioning if interpolation error can be neglected.  相似文献   

Estimating spatial efficiency using cyber search,GIS, and spatial optimization: a case study of fire service deployment in Los Angeles County     

Richard L. Church 《International journal of geographical information science》2016,30(3):535-553

ABSTRACT

The efficiency of public investments and services has been of interest to geographic researchers for several decades. While in the private sector inefficiency often leads to higher prices, loss of competitiveness, and loss of business, in the public sector inefficiency in service provision does not necessarily lead to immediate changes. In many cases, it is not an entirely easy task to analyze a particular service as appropriate data may be difficult to obtain and hidden in detailed budgets. In this paper, we develop an integrative approach that uses cyber search, Geographic Information System (GIS), and spatial optimization to estimate the spatial efficiency of fire protection services in Los Angeles (LA) County. We develop a cyber-search process to identify current deployment patterns of fire stations across the major urban region of LA County. We compare the results of our search to existing databases. Using spatial optimization, we estimate the level of deployment that is needed to meet desired coverage levels based upon the location of an ideal fire station pattern, and then compare this ideal level of deployment to the existing system as a means of estimating spatial efficiency. GIS is adopted throughout the paper to simulate the demand locations, to conduct location-based spatial analysis, to visualize fire station data, and to map model simulation results. Finally, we show that the existing system in LA County has considerable room for improvement. The methodology presented in this paper is both novel and groundbreaking, and the automated assessments are readily transferable to other counties and jurisdictions.  相似文献