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891.
Radiocarbon dating of soils and sediments is notoriously problematic for the purposes of dating a specific event due to their heterogeneous mix of multiple organic fractions, each of which may have a different radiocarbon age. Numerous studies have failed to agree on which sedimentary fraction or radiocarbon pre-treatment method, if any, provides the closest agreement between the age of a sedimentary fraction and that of associated plant macrofossils or charcoal. We tested the stepped-combustion method of McGeehin et al. (2001), as well as standard radiocarbon humin and humic extraction techniques, using samples from a chronologically well-constrained perennially-frozen site at Quartz Creek, Yukon Territory, Canada. The ages in closest agreement with associated radiocarbon-dated plant macrofossils and with the overlying Dawson tephra were given by the humic and humin fractions, but even these were still older than the macrofossil ages by up to 4195 ± 260 radiocarbon years. The low temperature (LT) humin method recommended by McGeehin et al. (2001) yielded ages older than the macrofossils by up to nearly 4425 ± 240 radiocarbon years. These fractions, while still providing information on the mobility and potential residence times of carbon in soils and sediments, should not be relied upon to provide consistently accurate site chronologies.  相似文献   
892.
We evaluated tools and methods for in situ freezing of cores in unconsolidated subsurface media. Our approach, referred to as cryogenic core collection (C3), has key aspects that include downhole circulation of liquid nitrogen (LN) via a cooling system, strategic use of thermal insulation to focus cooling into the core, and controlling LN back pressure to optimize cooling. Two cooling systems (copper coil and dual‐wall cylinder) are described. For both systems, the time to freeze a single 2.5‐foot (76‐cm) long by 2.5‐inch (63‐mm) diameter core is 5 to 7 min. Frozen core collection rates of about 30 feet/day (10 m/day) were achieved at two field sites, one impacted by petroleum‐based light nonaqueous phase liquids (LNAPLs) and the other by chlorinated solvents. Merits of C3 include (1) improved core recovery, (2) potential control of flowing sand, and (3) improved preservation of critical sediment attributes. Development of the C3 method creates novel opportunities to characterize sediment with respect to physical, chemical, and biological properties. For example, we were able to resolve water, LNAPL, and gas saturations above and below the water table. By eliminating drainage of water, gas and LNAPL saturations in the range of 6 to 23% and 1 to 3% of pore space, respectively, were measured in LNAPL‐impacted intervals below the water table.  相似文献   
893.
894.
Active thermal areas are concentrated in three areas on Mauna Loa and three areas on Kilauea. High-temperature fumaroles (115–362° C) on Mauna Loa are restricted to the summit caldera, whereas high-temperature fumaroles on Kilauea are found in the upper East Rift Zone (Mauna Ulu summit fumaroles, 562° C), middle East Rift Zone (1977 eruptive fissure fumaroles), and in the summit caldera. Solfataric activity that has continued for several decades occurs along border faults of Kilauea caldera and at Sulphur Cone on the southwest rift zone of Mauna Loa. Solfataras that are only a few years old occur along recently active eruptive fissures in the summit caldera and along the rift zones of Kilauea. Steam vents and hot-air cracks also occur at the edges of cooling lava ponds, on the summits of lava shields, along faults and graben fractures, and in diffuse patches that may reflect shallow magmatic intrusions.  相似文献   
895.
Fine-grained æolian sediments are an important component of many loessic soil–landscape systems across south-eastern Australia. These loessic soils are commonly related to the deposition of ‘parna’, a red, clayey, calcareous material proposed to have been transported predominantly as silt-sized pellets and companion silt grains. However, it is apparent that loessic soils of south-eastern Australia do not necessarily exhibit or retain the morphological features regarded as typical of parna. This may be due to variations in post-depositional pedogenic processes operating over long periods of time. It is important to understand this inconsistency in loessic soil expression because the physico-chemical and structural attributes of these profiles may significantly affect catchment-wide processes such as salinisation and erosion. In this paper, the pedological features of a range of previously identified loessic profiles occurring across south-eastern Australia are examined to assess the relative importance of climate and local landscape processes on profile characteristics. Most of the sampling sites occur in mid- to upper-slope positions, while the annual average rainfall of the sites ranges from 440 mm to 650 mm. The deepest profiles in the driest locations tend to yield whole-coloured, slightly alkaline, slightly saline and sodic subsoils with moderate cation exchange capacities. Profiles in the wettest locations are generally characterised by smaller cation exchange capacities, are acidic, non-saline and non-sodic, and feature prominent mottling and sesquioxide nodules. Measurements and predictions of the structural attributes of the profiles indicate that all topsoils are quite stable to wetting, whereas subsoils exhibit variable stabilities, depending on physico-chemical properties. These results appear to demonstrate a broad climosequence effect on loessic soil attributes. The climosequence effect was compared to the changes in loessic profile characteristics down a case study toposequence in southern New South Wales. The toposequence indicates that local landscape features such as slope and drainage have also been important in determining the properties of these materials, as has re-working by colluvial processes. We conclude that to explain adequately the current characteristics of profiles containing fine-grained æolian sediments, particularly their salinisation potential and stability to erosion, it is critical to consider both the past and present climate and the local soil-forming processes.  相似文献   
896.
We investigated the accumulation and influence of bioavailable P (BAP) in sediments of a stream located in an agricultural area of the Lake Mendota watershed in Wisconsin, USA. During hydrologic events, the stream carried high concentrations of suspended sediment (up to 250 mg/l) and BAP (up to 2.5 mg/l). Bed sediments were highly enriched in BAP, as inventories of BAP in the top 10 cm of sediment ranged from 143 to 14,500 μg P/cm2. Space variations in BAP inventories were related to site-specific hydrodynamics and geochemical factors, including iron (Fe; r 2 = 0.71) and aluminum (Al; r 2 = 0.54) concentrations. Most sites behaved as potential sinks for dissolved reactive phosphate during hydrologic events and potential sources during base-flow periods. Through the combination of site-specific factors and geochemical controls, Dorn Creek modifies the amount, timing, and composition of P delivered from the watershed to downstream sites and water bodies.  相似文献   
897.
Multiple streamflow measurements were made at coupled discharge measurement stations to quantify rates of aquifer recharge and discharge on two reaches of the Souhegan River, New Hampshire, USA, flowing within a glacial-drift river-valley aquifer. The reaches included a predominantly losing (aquifer recharge) reach and a variable (aquifer recharge and discharge) reach located downstream of the former reach. River leakage, the differential between coupled upstream and downstream streamflow measurements along a reach, varied by almost 30 cubic feet per second (ft3/s) (0.85 m3/s) along the two reaches. The upper reach averaged 3.94 ft3/s (0.11 m3/s) loss whereas the lower reach averaged 4.85 ft3/s (0.14 m3/s) gain. At the upper reach, 13 losses were measured out of 19 coupled measurements. At the lower reach, ten out of 13 coupled measurements indicated gains in flow and suggest that this reach is primarily a gaining river reach. An important factor in river leakage appears to be antecedent trends in river stage. At the upper reach, gains were measured only during periods of declining river stage. Conversely, at the lower reach, streamflow loss was measured primarily during periods of rising river stage. Although some tendencies exist, several factors complicate the analysis of river leakage, most notably the inaccuracies in computed stream discharge.  相似文献   
898.
The growing ethnic and racial diversity of the United States is evident at all spatial scales. One of the striking features of this new mixture of peoples, however, is that this new diversity often occurs in tandem with racial concentration. This article surveys these new geographies from four points of view: the nation as a whole, states, large metropolitan areas, and neighborhoods. The analysis at each scale relies on a new taxonomy of racial composition that simultaneously appraises both diversity and the lack thereof (Holloway, Wright, and Ellis 2012). Urban analysis often posits neighborhood racial segregation and diversity as either endpoints on a continuum of racial dominance or mirror images of one another. We disturb that perspective and stress that segregation and diversity must be jointly understood—they are necessarily related, although not as inevitable binary opposites. Using census data from 1990, 2000, and 2010, the research points to how patterns of racial diversity and dominance interact across varying spatial scales. This investigation helps answer some basic questions about the changing geographies of racialized groups, setting the stage for the following articles that explore the relationship between geography and the participation of underrepresented groups in higher education.  相似文献   
899.
Gendered Spaces of Informal Entrepreneurship in Soweto,South Africa   总被引:1,自引:1,他引:0  
Abstract

The full diversity of economic activities in the informal economy is not well understood. The apartheid legacy of limiting informal entrepreneurship explains the most obvious geographical patterns in South Africa. After a decade and a half since the end of apartheid, however, knowledge about the places from which informal entrepreneurs operate is incomplete. Retailing is overemphasized and production firm entrepreneurs, both male and female, remain a neglected spatiality. This study reports on a survey of 100 firms in Soweto and in-depth interviews with 30 firm owners. The findings challenge the representations of isolated urban entrepreneurs dependent on inherited social capital and of women's exclusive engagement in retail. Entrepreneurs create their own social capital in work-related realms, but there are important gender differences. More finely tuned conceptualizations of entrepreneurs and of gendered working spaces need to be developed so that policy does not perpetuate unitary myths and incomplete spatial representations. [Key words: entrepreneurship, Soweto, informal economy, gender.]  相似文献   
900.
Quantifying spatial and temporal dynamics of organic matter (OM) is critical both for understanding ecosystem functioning and for predicting impacts of landscape change. To determine the influence of different habitats and coarse particulate OM (CPOM) types upon floodplain OM dynamics, we quantified aerial input, lateral surface transfer, and surface storage of CPOM over an annual cycle on the near-natural floodplain of the River Tagliamento in NE-Italy. Using these data, we modelled floodplain leaf dynamics, taking account of the spatial distribution and hydrologic connectivity of habitats, and using leaf storage as a response variable. Mean aerial CPOM input to the floodplain was similar from riparian forest and islands, but surface transfer was greater from islands, supporting the suggestion that these habitats act as “islands of fertility” along braided rivers. Leaves were the lateral conveyor of energy to more open parts of the floodplain, whereas CPOM was mainly stored as small wood in vegetated islands and riparian forest. Simulating the loss of habitat diversity (islands, ponds) decreased leaf storage on the whole floodplain, on exposed gravel and in large wood accumulations. In contrast, damming (loss of islands, ponds and floods plus floodplain overgrowth) greatly increased storage on exposed gravel. A random shuffle of habitats led to a storage increase on exposed gravel, while that in large wood accumulations and ponds declined. These results disentangle some of the complexities of CPOM dynamics in floodplain ecosystems, illustrate the value of models in understanding ecosystem functioning at a landscape level, and directly inform river management practice.  相似文献   
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