Comparison of quantitative petrographic, stable isotope and cathodoluminescence data for fingerprinting Czech marbles   总被引：1，自引：1，他引：0  

Aneta Šťastná  Richard Přikryl  Alena Černíková 《Environmental Earth Sciences》2011,63(7-8):1651-1663

Various marbles from both historic quarries and historical artefacts of the Czech Republic were examined in order to make determinations of their provenance. The methodology used was based upon a combination of petrographic image analysis (PIA) of thin sections, stable isotope geochemistry of carbonates, and cathodoluminescence. Multivariate statistical methods (i.e. cluster analysis and discriminant analysis) confirmed the geoscientific relevance of the marble’s different characteristics with a high degree of consistency as well as the enhanced significance of stable C and O isotopes in correlation with the petrographic data. The qualitative cathodoluminescence data provided a useful additional tool to help recognise the fingerprinting of marbles with similar petrographic and/or geochemical characteristics.  相似文献   

Pravčice Rock Arch (Bohemian Switzerland National Park, Czech Republic) deterioration due to natural and anthropogenic weathering     

Zuzana Vařilová  Richard Přikryl  Václav Cílek 《Environmental Earth Sciences》2011,63(7-8):1861-1878

The dominant factors affecting the development of weathering forms on the Prav?ice Rock Arch (PRA) (Bohemian Switzerland National Park, Czech Republic) are discussed, based on the in situ monitoring of weathering forms, as well as on laboratory studies of materials taken from this site. The in situ monitoring shows the progressive development of distinct weathering forms (delamination of case-hardened rock surfaces, cyclic efflorescence, and granular disintegration of exposed weakly cemented rock mass) in specific portions of the PRA, whose location is controlled by lithology, jointing/local hydrodynamics, and exposure to climatic factors. From the analysis of efflorescence, the dominance of sulphates is evident; particularly of gypsum and alums. However, the synergistic effects of the several salt species (that also include minor nitrates and chlorides) upon the mechanical disintegration of sandstone can be expected.  相似文献   

Erratum to: Comparison of quantitative petrographic, stable isotope and cathodoluminescence data for fingerprinting Czech marbles     

Aneta ?t’astná  Richard P?ikryl  Alena ?erníková 《Environmental Earth Sciences》2011,64(4):1195-1196

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Particle fluxes in San Pedro Basin, California: A four-year record of sedimentation and physical forcing     

Lisa E. Collins  William BerelsonDouglas E. Hammond  Angela Knapp  Richard SchwartzDoug Capone 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(8):898-914

Moored sediment traps were deployed from January 2004 through December 2007 at depths of 550 and 800 m in San Pedro Basin (SPB), CA (33°33.0′N, 118°26.5′W). Additionally, floating sediment traps were deployed at 100 and 200 m for periods of 12-24 h during spring 2005, fall 2007, and spring 2008. Average annual fluxes of mass, particulate organic carbon (POC), ??¹³C_org, particulate organic nitrogen (PON), ??¹⁵N-PON, biogenic silica (bSiO₂), calcium carbonate (CaCO₃), and detrital material (non-biogenic) were coupled with climate records and used to examine sedimentation patterns, vertical flux variability, and organic matter sources to this coastal region. Annual average flux values were determined by binning data by month and averaging the monthly averages. The average annual fluxes to 550 m were 516±42 mg/m² d for mass (sdom of the monthly averages, n=117), 3.18±0.26 mmol C/m² d for POC (n=111), 0.70±0.05 mmol/m² d for CaCO₃ (n=110), 1.31±0.21 mmol/m² d for bSiO₂ (n=115), and 0.35±0.03 mmol/m² d for PON (n=111). Fluxes to 800 and to 550 m were similar, within 10%. Annual average values of ??¹³C_org at 550 m were −21.8±0.2‰ (n=108), and ??¹⁵N averages were 8.9±0.2‰ (n=95). The timing of both high and low flux particle collection was synchronous between the two traps. Given the frequency of trap cup rotation (4-11 days), this argues for particle settling rates ≥83 m/d for both high and low flux periods. The moored traps were deployed over one of the wettest (2004-2005, 74.6 cm rainfall) and driest (2006-2007, 6.6 cm) rain years on record. There was poor correlation (Pearson's correlation coefficient, 95% confidence interval) of detrital mass flux with: C_org/N ratio (r=0.10, p=0.16); ??¹⁵N (r=−0.19, p=0.02); and rainfall (r=0.5, p=0.43), suggesting that runoff does not immediately cause increases in particle fluxes 15 km offshore. ??¹³C_org values suggest that most POC falling to the basin floor is marine derived. Coherence between satellite-derived chlorophyll a records from the trap location (±9 km² resolution) and SST data indicates that productivity and export occurs within a few days of upwelling and both of these parameters are reasonable predictors of POC export, with a time lag of a few days to 2 weeks (with no time lag—SeaWiFS chlorophyll a and POC flux, r=0.25, p=0.0014; chlorophyll a and bSiO₂ flux, r=0.28, p=0.0002).  相似文献   

Woodland expansion’s influence on belowground carbon and nitrogen in the Great Basin U.S.     

Benjamin M. Rau  Dale W. Johnson  Bruce A. Roundy  Richard F. Miller  Todd G. Caldwell  Annmarie Lucchesi 《Journal of Arid Environments》2011,75(9):827-835

Vegetation changes associated with climate shifts and anthropogenic disturbance can have major impacts on biogeochemical cycling and soils. Much of the Great Basin, U.S. is currently dominated by sagebrush (Artemisia tridentate (Rydb.) Boivin) ecosystems. Sagebrush ecosystems are increasingly influenced by pinyon (Pinus monophylla Torr. & Frém and Pinus edulis Engelm.) and juniper (Juniperus osteosperma Torr. and Juniperus occidentalis Hook.) expansion. Some scientists and policy makers believe that increasing woodland cover in the intermountain western U.S. offers the possibility of increased organic carbon (OC) storage on the landscape; however, little is currently known about the distribution of OC on these landscapes, or the role that nitrogen (N) plays in OC retention. We quantified the relationship between tree cover, belowground OC, and total below ground N in expansion woodlands at 13 sites in Utah, Oregon, Idaho, California, and Nevada, USA. One hundred and twenty nine soil cores were taken using a mechanically driven diamond tipped core drill to a depth of 90 cm. Soil, coarse fragments, and coarse roots were analyzed for OC and total N. Woodland expansion influenced the vertical distribution of root OC by increasing 15-30 cm root OC by 2.6 Mg ha⁻¹ and root N by 0.04 Mg ha⁻¹. Root OC and N increased through the entire profile by 3.8 and 0.06 Mg ha⁻¹ respectively. Woodland expansion influenced the vertical distribution of soil OC by increasing surface soil (0-15 cm) OC by 2.2 Mg ha⁻¹. Woodland expansion also caused a 1.3 Mg ha⁻¹ decrease in coarse fragment associated OC from 75-90 cm. Our data suggests that woodland expansion into sagebrush ecosystems has limited potential to store additional belowground OC, and must be weighed against the risk of increased wildfire and exotic grass invasion.  相似文献   

Structure and evolution of mass transport deposits in the South Caspian Basin,Azerbaijan     

Steve E. J. Richardson  Richard J. Davies  Mark B. Allen  Simon F. Grant 《Basin Research》2011,23(6):702-719

The Quaternary to late Pliocene sedimentary succession along the margin of the South Caspian Basin contains numerous kilometre‐scale submarine slope failures, which were sourced along the basin slope and from the inclined flanks of contemporaneous anticlines. This study uses three‐dimensional (3D) seismic reflection data to visualise the internal structure of 27 mass transport deposits and catalogues the syndepositional structures contained within them. These are used to interpret emplacement processes occurring during submarine slope failure. The deposits consist of three linked structural domains: extensional, translational and compressive, each containing characteristic structures. Novel features are present within the mass transport deposits: (1) a diverging retrogression of the headwall scarp; (2) the absence of a conventional headwall scarp around growth stratal pinch outs; (3) restraining bends in the lateral margin; (4) a downslope increase in the throw of thrust faults. The results of this study shed light on the deformation that occurred during submarine slope failure, and highlight an important geological process in the evolution of the South Caspian Basin margin.  相似文献   

Microbial mats implicated in the generation of intrastratal shrinkage (‘synaeresis’) cracks     

Dario Harazim  Richard H. T. Callow  Duncan Mcilroy 《Sedimentology》2013,60(7):1621-1638

Intrastratal shrinkage (often termed ‘synaeresis’) cracks are commonly employed as diagnostic environmental indicators for ancient salinity‐stressed, transitional fluvial‐marine or marginal‐marine depositional environments. Despite their abundance and use in facies interpretations, the mechanism of synaeresis crack formation remains controversial, and widely accepted explanations for their formation have hitherto been lacking. Sedimentological, ichnological, petrographic and geochemical study of shallow marine mudstone beds from the Ordovician Beach Formation of Bell Island, Newfoundland, has revealed that crack development (cf. synaeresis cracks) on the upper surface of mudstone beds is correlated with specific organic, geochemical and sedimentological parameters. Contorted, sinuous, sand‐filled cracks are common at contacts between unbioturbated mudstone and overlying sandstone beds. Cracks are absent in highly bioturbated mudstone, and are considered to pre‐date firmground assemblages of trace fossils that include Planolites and Trichophycus. The tops of cracked mudstone beds contain up to 2·1 wt% total organic carbon, relative to underlying mudstone beds that contain around 0·5 wt% total organic carbon. High‐resolution carbon isotope analyses reveal low δ¹³C_org values (?27·6‰) on bed tops compared with sandy intervals lacking cracks (?24·4 to ?24·9‰). Cracked mudstone facies show evidence for microbial matgrounds, including microbially induced sedimentary structures on bedding planes and carbonaceous laminae and tubular carbonaceous microfossils in thin section. Non‐cracked mudstone lacks evidence for development of microbial mats. Microbial mat development is proposed as an important prerequisite for intrastratal shrinkage crack formation. Both microbial mats and intrastratal shrinkage cracks have broad palaeoenvironmental distributions in the Precambrian and early Phanerozoic. In later Phanerozoic strata, matgrounds are restricted to depositional environments that are inhospitable to burrowing and surface‐grazing macrofauna. Unless evidence of synaeresis (i.e. contraction of clay mineral lattices in response to salinity change) can be independently demonstrated, the general term ‘intrastratal shrinkage crack’ is proposed to describe sinuous and tapering cracks in mudstone beds.  相似文献   

Dawn; the Vesta–HED connection; and the geologic context for eucrites,diogenites, and howardites     

Harry Y. McSween Jr.  Richard P. Binzel  M. Cristina De Sanctis  Eleonora Ammannito  Thomas H. Prettyman  Andrew W. Beck  Vishnu Reddy  Lucille Le Corre  Michael J. Gaffey  Thomas B. McCord  Carol A. Raymond  Christopher T. Russell  the Dawn Science Team 《Meteoritics & planetary science》2013,48(11):2090-2104

The Dawn mission has provided new evidence strengthening the identification of asteroid Vesta as the parent body of the howardite, eucrite, and diogenite (HED) meteorites. The evidence includes Vesta's petrologic complexity, detailed spectroscopic characteristics, unique space weathering, diagnostic geochemical abundances and neutron absorption characteristics, chronology of surface units and impact history, occurrence of exogenous carbonaceous chondritic materials in the regolith, and dimensions of the core, all of which are consistent with HED observations and constraints. Global mapping of the distributions of HED lithologies by Dawn cameras and spectrometers provides the missing geologic context for these meteorites, thereby allowing tests of petrogenetic models and increasing their scientific value.  相似文献   

Chemical and structural relations of epitaxial xenotime and zircon substratum in sedimentary and hydrothermal environments: a TEM study     

Kerstin Drost  Richard Wirth  Jan Košler  Hege Fonneland Jørgensen  Theodoros Ntaflos 《Contributions to Mineralogy and Petrology》2013,165(4):737-756

Xenotime overgrowths on detrital zircon in siliciclastic sediments have been reported in numerous studies. However, in natural samples, solid solution of zircon and xenotime is limited to near-end-member compositions. In order to characterize the interface region between both minerals and to draw inferences on the growth mechanisms of authigenic xenotime, we studied xenotime overgrowths on detrital zircon grains from two Phanerozoic sandstone samples with contrasting post-depositional histories. In one sample, the small (≤10 μm), pyramidal xenotime overgrowths are of diagenetic origin and grew without major discontinuity on the detrital zircon grain. The second sample shows up to >50-μm-wide, porous and inclusion-rich, hydrothermal xenotime overgrowths on detrital zircon, whereas the transition zone between both minerals is accompanied by large pore volume. Chemical compositions of the xenotime precipitates from the two samples differ particularly in Y, REE, Th and Sc concentrations, whereas high MREE availability in the diagenetic sample and the presence of Sc in the hydrothermal sample, respectively, appear to have promoted xenotime growth. Transmission electron microscopy on electron-transparent foils cut from the interface region shows that both the diagenetic xenotime and the hydrothermal xenotime are crystalline and grew in optical and crystallographic continuity to their detrital zircon substrata. Only a narrow transition zone (≤90 nm—diagenetic sample, 200–300 nm—hydrothermal sample) between zircon and xenotime is in part made up of nanometre-scale crystalline domains that are slightly distorted and may have formed from dissolution–re-precipitation processes at the zircon rim along with precipitation from the respective fluid.  相似文献   

TiO2 exsolution from garnet by open-system precipitation: evidence from crystallographic and shape preferred orientation of rutile inclusions     

Alexander Proyer  Gerlinde Habler  Rainer Abart  Richard Wirth  Kurt Krenn  Georg Hoinkes 《Contributions to Mineralogy and Petrology》2013,166(1):211-234

We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe²⁺ to Fe³⁺ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies.  相似文献