Contrasting stable isotope behavior between calcite and dolomite marbles,Lone Mountain,Nevada     

I. J. Richards  Theodore C. Labotka  Robert T. Gregory 《Contributions to Mineralogy and Petrology》1996,123(2):202-221

 Late Proterozoic to Cambrian carbonate rocks from Lone Mountain, west central Nevada, record multiple post-depositional events including: (1) diagenesis, (2) Mesozoic regional metamorphism, (3) Late Cretaceous contact metamorphism, related to the emplacement of the Lone Mountain granitic pluton and (4) Tertiary hydrothermal alteration associated with extension, uplift and intrusion of silicic porphyry and lamprophyre dikes. Essentially pure calcite and dolomite marbles have stable isotopic compositions that can be divided into two groups, one with positive δ¹³C values from+3.1 to +1.4 ‰ (PDB) and high δ¹⁸O values from +21.5 to +15.8 ‰ (SMOW), and the other with negative δ¹³C values from –3.3 to –3.6‰ and low δ¹⁸O values from +16.9 to +11.1‰. Marbles also contain minor amounts of quartz, muscovite and phlogopite. Brown and blue luminescent, clear, smooth textured quartz grains from orange luminescent calcite marbles have high δ¹⁸O values from +23.9 to +18.1‰, while brown luminescent, opaque, rough textured quartz grains from red luminescent dolomite marbles typically have low δ¹⁸O values from +2.0 to +9.3‰. The δ¹⁸O values of muscovite and phlogopite from marbles are typical of micas in metamorphic rocks, with values between +10.4 and +14.4‰, whereas mica δD values are very depleted, varying from −102 to −156‰. No significant lowering of the δ¹⁸O values of Lone Mountain carbonates is inferred to have occurred during metamorphism as a result of devolatilization reactions because of the essentially pure nature of the marbles. Bright luminescence along the edges of fractures, quartz cements and quartz overgrowths in dolomite marbles, low δD values of micas, negative δ¹³C values and low δ¹⁸O values of calcite and dolomite, and depleted δ¹⁸O values of quartz from dolomite marbles all indicate that meteoric fluids interacted with Lone Mountain marbles during the Tertiary. Partial oxygen isotopic exchange between calcite and low ¹⁸O meteoric fluids lowered the δ¹⁸O values of calcite, resulting in uniform quartz-calcite fractionations that define an apparent pseudoisotherm. These quartz-calcite fractionations significantly underestimate both the temperature of metamorphism and the temperature of post-metamorphic alteration. Partial oxygen isotopic exchange between quartz and meteoric fluids also resulted in ¹⁸O depletion of quartz from dolomite marbles. This partial exchange was facilitated by an increase in the surface area of the quartz as a result of its dissolution by meteoric fluids. The negative δ¹³C values in carbonates result from the oxidation of organic material by meteoric fluids following metamorphism. Stable isotopic data from Lone Mountain marbles are consistent with the extensive circulation of meteoric hydrothermal fluids throughout western Nevada in Tertiary time. Received: 1 February 1994/Accepted: 12 September 1995  相似文献   

Evaluating the influence of landform, surficial geology, and land use on streams using hydrologic simulation modeling   总被引：1，自引：0，他引：1  

Jesse D. Schomberg  George Host  Lucinda B. Johnson  Carl Richards 《Aquatic Sciences - Research Across Boundaries》2005,67(4):528-540

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Challenges for Sustainable Mineral Resources Development in the 21st Century*     

Jeremy P. Richards 《Resource Geology》2005,55(2):131-137

Abstract. The modern minerals industry is more environmentally responsible and socially aware than at any time in the past, and yet faces increasing challenges to improve its performance in these areas still further. Some of these expectations are reasonable and achievable, but others are unrealistic (e.g., “zero impact”) if real development is to continue. Moreover, because society is the ultimate beneficiary of the industry's products, it should be prepared to pay for the improvements it demands. Currently externalized costs, such as many environmental and social impacts, should be internalized into prices, and higher royalties should be charged on gross revenue to ensure effective capture of value of non‐renewable resources by host countries. Such costs to consumers could be offset by higher recycling value, leasing, or deposit‐return schemes. NGOs have an important role to play in working with industry to convince society to accept such changes.  相似文献   

The influence of ENSO on the equatorial Atlantic precipitation through the Walker circulation in a CGCM     

Wataru Sasaki  Takeshi Doi  Kelvin J. Richards  Yukio Masumoto 《Climate Dynamics》2015,44(1-2):191-202

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On the modelling of sand bedforms using the semivariogram     

Andr Robert  Keith S. Richards 《地球表面变化过程与地形》1988,13(5):459-473

This study shows the usefulness of the semivariogram for modelling sand ripples created by water flows of varied flow intensity. A combination of two mathematical functions is fitted to each sample semivariogram, that is an exponential (or stochastic) component and a periodic component. The parameters of each of these components have direct physical meaning. A non-dimensional ratio combining the two parameters of the exponential model is interpreted as a regularity index (which increases with the degree of regularity of bedform arrangement). This regularity index is inversely related to the Froude number of the flow. The non-dimensional wavelength, estimated from the dominant periodic function, is also inversely and closely related to the Froude number. The wave height, accurately estimated from properties of the two fitted components, is a direct function of flow velocity and is also proportional to the standard deviation of bed elevations. The bedform shape introduces a considerable discrepancy between the generally assumed normal frequency distribution and the empirical distributions of bed height. The series of bed elevations are generally characterized by a mixture of normal distributions having the same variance but different means. The calculation of a covariance assuming a constant and single mean (as in spectral analysis) can therefore be misleading and the problem may be avoided by using the semivariogram.  相似文献   

Nonlinear Topics In Ocean Physics, A. R. Osborne (Ed), Elsevier, Amsterdam & New York, 1991, 945 Pp, Isbn 0-444-89017-3, Dfl. 420, Use 240.     

K. J. Richards 《Geophysical Journal International》1993,112(2):301-301

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Mechanics and performance of a tied-back wall under seismic loads     

G. Neelakantan  Muniram Budhu  R. Richards 《地震工程与结构动力学》1990,19(3):315-331

In this paper the stability of a tied-back wall subjected to seismic loads is analysed for a predetermined mode of failure (rotation about the top of the wall) and the analysis is compared with data from tests on this type of wall using the seismic simulator at the State University of New York at Buffalo. We carried out a pseudo-static analysis of the problem using the Mononobe-Okabe earth pressure coefficients, wherein the dynamic effects due to the seismic loading are converted into equivalent static loads. The acceleration ratio at which the wall fails by rotation about the top was obtained by considering the moments due to the various lateral earth pressure resultants and the inertial forces induced in the soil due to the seismic loading. We found that the presence of wall friction on the passive side significantly enhances the stability of the flexible retaining wall under seismic loads. Thus, flexible retaining walls supporting dry cohesionless soil can be very efficient during earthquakes. Under moderate earthquakes, an increase in the depth of embedment increases the dynamic factor of safety significantly. However, beyond a certain acceleration ratio for a soil with a particular value of ø, any increase in the depth of emdedment has no effect in impeding failure, irrespective of any change in the geometry of the system. Seismic design charts are presented to evaluate the stability of, and to design, flexible retaining walls embedded in dry cohesionless soils under seismic loading.  相似文献   

Oceanography: The past | Mary Sears and Daniel Merriman (Editors), 1980. Springer-Verlag,New York,N.Y., 812 pp., DM 70     

K.J. Richards 《Earth》1982,18(1):81-82

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The Llullaillaco volcano, northwest Argentina: construction by Pleistocene volcanism and destruction by sector collapse     

J. P. Richards  M. Villeneuve 《Journal of Volcanology and Geothermal Research》2001,105(1-2)

Llullaillaco is one of a chain of Quaternary stratovolcanoes that defines the present Andean Central Volcanic Zone (CVZ), and marks the border between Chile and Argentina/Bolivia. The current edifice is constructed from a series of thick dacitic lava flows, forming the second tallest active volcano in the world (6739 m). K–Ar and new biotite laser ⁴⁰Ar/³⁹Ar step-heating dates indicate that the volcano was constructed during the Pleistocene (≤1.5 Ma), with a youngest date of 0.048±0.012 Ma being recorded for a fresh dacite flow that descends the southern flank. Additional ⁴⁰Ar/³⁹Ar measurements for andesitic and dacitic lava flows from the surrounding volcanic terrain yield dates of between 11.94±0.13 Ma and 5.48±0.07 Ma, corresponding to an extended period of Miocene volcanism which defines much of the landscape in this region. Major- and trace-element compositions of lavas from Llullaillaco are typical of Miocene–Pleistocene volcanic rocks from the western margin of the CVZ, and are related to relatively shallow-dipping subduction of the Nazca plate beneath northern Chile and Argentina.Oversteepening of the edifice by stacking of thick, viscous, dacitic lava flows resulted in collapse of its southeastern flank to form a large volcanic debris avalanche. Biotite ⁴⁰Ar/³⁹Ar dating of lava blocks from the avalanche deposit indicate that collapse occurred at or after 0.15 Ma, and may have been triggered by extrusion of a dacitic flow similar to the one dated at 0.048±0.012 Ma. The avalanche deposits are exceptionally well preserved due to the arid climate, and prominent levées, longitudinal ridges, and megablocks up to 20-m diameter are observed.The avalanche descended 2.8 km vertically, and bifurcated around an older volcano, Cerro Rosado, before debouching onto the salt flats of Salina de Llullaillaco. The north and south limbs of the avalanche traveled 25 and 23 km, respectively, and together cover an area of approximately 165 km². Estimates of deposit volume are hampered by a lack of thickness information except at the edges, but it is likely to be between 1 and 2 km³. Equivalent coefficients of friction of 0.11 and 0.12, and excess travel distances of 20.5 and 18.5 km, are calculated for the north and south limbs, respectively. The avalanche ascended 400 m where it broke against the western flank of Cerro Rosado, and a minimum flow velocity of 90 m s⁻¹ can be calculated at this point; lower velocities of 45 m s⁻¹ are calculated where distal toes ascend 200 m slopes.It is suggested that the remaining precipitous edifice has a high probability for further avalanche collapse in the event of renewed volcanism.  相似文献   

Petroleum Hydrocarbon Bioventing Kinetics Determined in Soil Core, Microcosm, and Tubing Cluster Studies   总被引：2，自引：0，他引：2  

Ellen E. Moyer  David W. Ostendorf  Robin J. Richards  Steve Goodwin 《Ground Water Monitoring & Remediation》1996,16(1):141-153

Aerobic biodegradation of vapor-phase petroleum hydrocarbons was evaluated in an intact soil core from the site of an aviation gasoline release. An unsaturated zone soil core was subjected to a flow of nitrogen gas, oxygen, water vapor, and vapor-phase hydrocarbons in a configuration analogous to a biofilter or an in situ bioventing or sparging situation. The vertical profiles of vapor-phase hydrocarbon concentration in the soil core were determined by gas chromatography of vapor samples. Biodegradation reduced low influent hydrocarbon concentrations by 45 to 92 percent over a 0.6-m interval of an intact soil core. The estimated total hydrocarbon concentration was reduced by 75 percent from 26 to 7 parts per million. Steady-state concentrations were input to a simple analytical model balancing advection and first-order biodegradation of hydrocarbons. First-order rate constants for the major hydrocarbon compounds were used to calibrate the model to the concentration profiles. Rate constants for the seven individual hydrocarbon compounds varied by a factor of 4. Compounds with lower molecular weights, fewer methyl groups, and no quaternary carbons tended to have higher rate constants. The first-order rate constants were consistent with kinetic parameters determined from both microcosm and tubing cluster studies at the field site.  相似文献