Analysis of some aromatic hydrocarbons in a benzene-soluble bitumen from Green River shale     

D.E. Anders  F.G. Doolittle  W.E. Robinson 《Geochimica et cosmochimica acta》1973,37(5):1213-1228

The hydrocarbon content of an aromatic fraction, isolated from the bitumen of Green River shale, was studied by mass spectrometry, infra-red spectrometry, gas chromatography and a dehydrogenation technique. The hydrocarbon types and their distribution in this aromatic fraction, as determined by mass spectrometry, include the following: C_nH_2n?6(10%), C_nH_{2n?8 (31 %)}, C_nH_2n?10(18%), C_nH_2n?12(12%), C_nH_2n?14(8%) and a series of alkenylbenzenes (20%). The carbon-number range, empirical formulae and quantity of each compound in the major types are reported. Mass spectra of several compounds and homologous mixtures of compounds isolated from the aromatic fraction are also given.  相似文献   

Partitioning of manganese,iron, copper,zinc, lead,cobalt, and nickel in black coatings on stream boulders in the vicinity of the Magruder mine,Lincoln Co., Georgia     

Robert H. Carpenter  Gene D. Robinson  Willis B. Hayes 《Journal of Geochemical Exploration》1978,10(1):75-89

Sequential digestions of Fe-Mn oxide coated boulders collected upstream and downstream from the Magruder mine, Lincoln Co., Georgia, indicate probable partitioning relationships for Zn, Cu, Pb, Co, and Ni with respect to Mn and Fe. Initial digestion with 0.1M hydroxylamine hydrochloride (Hxl) in 0.01M HNO₃ selectively dissolyes Mn oxides, whereas subsequent digestion with 1:4 HCl dissolves remaining Fe oxides.The results indicate that partitioning is not constant, but varies systematically with respect to the location of metal-rich waters derived from sulfide mineralization. Upstream from the mineralized zone Zn and Ni are distinctly partitioned to the Fe oxide component and Co and Cu are partitioned to the Mn oxide component. Immediately downstream from the mineralized zone, Mn oxides become relatively more enriched in Zn, whereas Fe oxides are relatively more enriched in Cu, Co, and Ni. Analytical precision for Pb is poor, but available data suggests it is more closely associated with Fe oxides.For routine geochemical surveys utilizing coated surfaces, a one-step digestion method is probably adequate. Parameters useful for detecting sulfide mineralization are metal concentrations normalized to surface area or various ratios (e.g. Zn/(Mn + Fe), Cu/Mn, Pb/Fe). Ratios can be obtained much faster, and at lower analytical costs than conventional analysis of stream sediment.  相似文献   

Reviews     

R. H. Wimble  J. E. Robinson  R. A. Reyment  F. Demirmen  D. F. Merriam 《Mathematical Geology》1976,8(5):589-596

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Coronal disturbances     

H. L. Demastus  W. J. Wagner  R. D. Robinson 《Solar physics》1973,31(2):449-459

Time lapse movies acquired with the Sacramento Peak Observatory 6-in filter coronagraph very infrequently show dramatic transient events. Many of these events (at 1.04 < r/r < 1.20) are correlated with H activity at the limb, especially with large surges and eruptive prominences. Metric or centrimetric radio bursts are found associated with certain types of 5303 coronal events. The heights to which such disturbances will propagate can often be estimated from the green line movie data. We report the results of a study of all the examples of such transients observed during the last 16 years.  相似文献   

Inflight Calibration of the NEAR Multispectral Imager: II. Results from Eros Approach and Orbit     

Scott MurchieMark Robinson  Deborah DomingueHan Li  Louise ProckterS.Edward Hawkins III  William OwenBeth Clark  Noam Izenberg 《Icarus》2002,155(1):229-243

During the Near-Earth Asteroid Rendezvous (NEAR) spacecraft's investigation of asteroid 433 Eros, inflight calibration measurements from the multispectral imager (MSI) have provided refined knowledge of the camera's radiometric performance, pointing, and light-scattering characteristics. Measurements while at Eros corroborate most earlier calibration results, although there appears to be a small, gradual change in instrument dark current and flat field due to effects of aging in the space environment. The most pronounced change in instrument behavior, however, is a dramatic increase in scattered light due to contaminants accumulated on the optics during unscheduled fuel usage in December 1998. Procedures to accurately quantify and to remediate the scattered light are described in a companion paper (Li et al. 2002, Icarus155, 00-00). Acquisition of Eros measurements has clarified the relative, filter-to-filter, radiometric performance of the MSI. Absolute radiometric calibration appears very well constrained from flight measurements, with an accuracy of ∼5%. Pointing relative to the spacecraft coordinate system can be determined from the temperature of the spacecraft deck with an accuracy of ∼1 pixel.  相似文献   

Ground water flow analysis of a mid-Atlantic outer coastal plain watershed, Virginia, U.S.A     

Robinson MA  Reay WG 《Ground water》2002,40(2):123-131

Models for ground water flow (MODFLOW) and particle tracking (MODPATH) were used to determine ground water flow patterns, principal ground water discharge and recharge zones, and estimates of ground water travel times in an unconfined ground water system of an outer coastal plain watershed on the Delmarva Peninsula, Virginia. By coupling recharge and discharge zones within the watershed, flowpath analysis can provide a method to locate and implement specific management strategies within a watershed to reduce ground water nitrogen loading to surface water. A monitoring well network was installed in Eyreville Creek watershed, a first-order creek, to determine hydraulic conductivities and spatial and temporal variations in hydraulic heads for use in model calibration. Ground water flow patterns indicated the convergence of flow along the four surface water features of the watershed; primary discharge areas were in the nontidal portions of the watershed. Ground water recharge zones corresponded to the surface water features with minimal development of a regional ground water system. Predicted ground water velocities varied between < 0.01 to 0.24 m/day, with elevated values associated with discharge areas and areas of convergence along surface water features. Some ground water residence times exceeded 100 years, although average residence times ranged between 16 and 21 years; approximately 95% of the ground water resource would reflect land use activities within the last 50 years.  相似文献   

Studies of ultracompact H ii regions — II. High-resolution radio continuum and methanol maser survey     

A. J. Walsh    M. G. Burton    A. R. Hyland  & G. Robinson 《Monthly notices of the Royal Astronomical Society》1998,301(3):640-698

High spatial resolution radio continuum and 6.67-GHz methanol spectral line data are presented for methanol masers previously detected by Walsh et al. (1997). Methanol maser and/or radio continuum emission is found in 364 cases towards IRAS -selected regions. For those sources with methanol maser emission, relative positions have been obtained to an accuracy of typically 0.05 arcsec, with absolute positions accurate to around 1 arcsec. Maps of selected sources are provided. The intensity of the maser emission does not seem to depend on the presence of a continuum source. The coincidence of water and methanol maser positions in some regions suggests there is overlap in the requirements for methanol and water maser emission to be observable. However, there is a striking difference between the general proximity of methanol and water masers to both cometary and irregularly shaped ultracompact (UC) H  ii regions, indicating that, in other cases, there must be differing environments conducive to stimulating their emission. We show that the methanol maser is most likely present before an observable UC H  ii region is formed around a massive star and is quickly destroyed as the UC H  ii region evolves. There are 36 out of 97 maser sites that are linearly extended. The hypothesis that the maser emission is found in a circumstellar disc is not inconsistent with these 36 maser sites, but is unlikely. It cannot, however, account for all other maser sites. An alternative model which uses shocks to create the masing spots can more readily reproduce the maser spot distributions.  相似文献   

Grain-size trends, basin subsidence and sediment supply in the Campanian Castlegate Sandstone and equivalent conglomerates of central Utah   总被引：2，自引：1，他引：1  

Ruth A. J. Robinson  & Rudy L. Slingerl 《Basin Research》1998,10(1):109-127

Reconstructions of grain-size trends in alluvial deposits can be used to understand the dominant controls on stratal architecture in a foreland basin. Different initial values of sediment supply, tectonic subsidence and base-level rise are investigated to constrain their influence on stratal geometry using the observed grain-size trends as a proxy of the goodness of fit of the numerical results to the observed data. Detailed measurements of grain-size trends, palaeocurrent indicators, facies and thickness trends, channel geometries and palynological analyses were compiled for the middle Campanian Castlegate Sandstone of the Book Cliffs and its conglomerate units in the Gunnison and Wasatch plateaus of central Utah. They define the initial conditions for a numerical study of the interactions between large-scale foreland basin and small-scale sediment transport processes. From previous studies, the proximal foreland deposits are interpreted as recording a middle Campanian thrusting event along the Sevier orogenic belt, while the stratal architecture in the Book Cliffs region is interpreted to be controlled by eustatic fluctuation with local tectonic influence. Model results of stratal geometry, using a subsidence curve with a maximum rate of ≈45 m Myr^?1 for the northern Wasatch Plateau region predict the observed grain-size trends through the northern Book Cliffs. A subsidence curve with a maximum rate of ≈30 m Myr^?1 in the Gunnison–Wasatch Plateaus best reproduces the observed grain-size trends in the southern transect through the southern Wasatch Plateau. Eustasy is commonly cited as controlling Castlegate deposition east of the Book Cliffs region. A eustatic rise of 45 m Myr^?1 produces grain-size patterns that are similar to the observed, but a rate of eustatic rise based on Haq et al. (1988) will not produce the observed stratal architecture or grain-size trends. Tectonic subsidence alone, or a combined rate of tectonic subsidence and a Haq et al. (1988) eustatic rise, can explain the stratal and grain-size variations in the proximal and downstream regions.  相似文献   

Implications of rock structure on the performance in the near field of a nuclear waste repository   总被引：1，自引：0，他引：1  

Johan Andersson  Peter Robinson  Michael Impey 《Engineering Geology》1998,49(3-4):195-200

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Reviews     

J. E. Robinson  John H. Doveton  D. F. Merriam 《Mathematical Geosciences》1975,7(2):185-189

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