We present new experimental data on Mg tracer diffusion in oriented single crystals of forsterite (Fo100) and San Carlos olivine (Fo92) between 1000–1300° C. The activation energies of diffusion are found to be 400 (±60) kJ/mol (96 kcal/mol) and 275 (±25) kJ/mol (65 kcal/ mol) in forsterite and San Carlos olivine, respectively, along [001] at a fO2 of 10–12 bars. There is no change in activation energy of Mg tracer diffusion within this temperature range. Mg tracer diffusion in a nominally pure forsterite is found to be anisotropic (Dc > Da > D b) and a function of fO2. This fO2 dependence is different from that in olivine containing Fe as a major element, which suggests that the diffusion mechanism of Mg in forsterite is different from that in Fe-bearing olivine at least over some range of fO2. The diffusion mechanism in nominally pure forsterites may involve impurities present below the limits of detection or alternately, Si or Fe3+ interstitial defects, Fe being present as impurity (ppm level) in forsterite. Pressure dependence of Mg tracer diffusivity in forsterite measured to 10 GPa in a multianvil apparatus yields an activation volume of approximately 1–3.5 cm3/ mol. It is found that presence of small amounts of hydrogen bearing species in the atmosphere during diffusion anneal (fH2 0.2 bars, fH20 0.24 bars) do not affect Mg tracer diffusion in forsterite within the resolution of our measurement at a total pressure of 1 bar. The observed diffusion process is shown to be extrinsic; hence extrapolation of the diffusion data to lower temperatures should not be plagued by uncertainties related to change of diffusion mechanism from intrinsic to extrinsic. 相似文献
The Permian Barakar Formation in the Mohpani coalfield, Satpura Gondwana basin, is composed of three broad lithologies that occur repetitively and are iterdigitated: (1) several metres thick coarse- to medium-grained sandstone bodies with scoured bases, (2) 5-20 m thick medium- to fine-grained sandstone bodies and (3) 5-20 m thick mudstone-dominated packages with variable proportions of centimetre- to decimetre-scale, fine- to medium-grained sandstone, carbonaceous shale and coal. The Barakar strata were previously interpreted as deposits of braided rivers and associated inter-channel flood basin in a continental setting. However, this study recognizes signatures of tidal current from the mudstone-dominated packages implying marine influence during Barakar sedimentation.
The mudstone-dominated sediment bodies are the focus of this paper and comprise of three lithofacies that bear imprints of tidal processes during Barakar sedimentation: (1) heterolith, (2) sandstone, and (3) coal-carbonaceous shale, which alternate with one another within individual bodies. The heterolithic facies show interlayering of sandstone and claystone resembling flaser, wavy and lenticular bedding, as well as pinstripe stratification. Successive sandstone-mudstone couplets indicate periodic waxing and waning of flows. Within individual heterolithic packages, the sandstone:claystone ratio along with the bedding style, varies cyclically upwards giving rise to alternate sandstone-dominated and claystone-dominated intervals suggesting tidal velocity fluctuation reflective of spring-neap lunar cycle. Thickness plots of successive sand-mud couplets also reveal cyclic variation with a conspicuous periodicity of around 12 couplets per cycle, which corroborates the spring-neap-spring (or neap-spring-neap) lunar cycle. Presence of abundant desiccation cracks indicates periodic emergence and points towards an intertidal setting. The sandstone facies is characterized by a variety of wave-generated features such as bundled and chevron upbuilding of lamina, bi-directional foreset orientations, offshooting and draping laminae, scour-and-drape feature, swollen lens-like geometries suggesting their emplacement under storm-induced combined-flow on the tidal-flat. The coal-carbonaceous shale facies represent supratidal marsh environment. 相似文献
Banded iron-formations (BIF) form an important part of the Archean supracrustal belts of the Jharkhand-Orissa region, India.
Major, trace and REE chemistry of the banded iron-formation of the Gandhamardan, Deo Nala, Gorumahisani and Noamundi sections
of the Jharkhand-Orissa region are utilized to explore the source of metals and to address the thermal regime of the basin
floor and the redox conditions of the archean sea. Hydrothermal fluids of variable temperatures might have contributed the
major part of the Fe and other trace elements to the studied banded iron-formations. Diagenetic fluids from the sea floor
sediments and river water might have played a subdued role in supplying the Fe and other elements for the banded iron-formations. 相似文献
Radar sensors can be used for large-scale vegetation mapping and monitoring using backscattering coefficients in different polarizations and wavelength bands. C-band space borne SAR is widely used for the classification of agricultural crops, but can only perform a limited discrimination of various tree species. This paper presents the results of discrimination between mustard crop and babul plantation (Prosopis sp.) using quad polarisation Radarsat 2 and ALOS PALSAR data. Study area is comprised of dense babul plantation along the canal, mustard crop on one side of the canal and Fallow land near to Ramgarh village of Jaisalmer district. Three bands of Radarsat (HH, HV and VV) acquired during peak mustard crop growth stage were integrated with four polarizations (HH, HV, VH and VV) of ALOS PALSAR acquired when crop cover was absent. Using only Radarsat data Jefferies-Matusita (JM) separability between mustard crop and babul plantation was found to be poor (710). Where as in the seven band combination the separability was observed to be high (1374). Among the different polarizations three layer combination, highest separability was observed using cross polarizations (HV and VH) of L-band with any one of the Radarsat Polarisation (HH/HV/VV). This combination of C- and L-band resulted in easy separation of mustard and babul plantation which was otherwise difficult using only Radarsat data. 相似文献
Based upon our characterization of three separate stones by electron and X‐ray beam analyses, computed X‐ray microtomography, Raman microspectrometry, and visible‐IR spectrometry, Sutter's Mill is a unique regolith breccia consisting mainly of various CM lithologies. Most samples resemble existing available CM2 chondrites, consisting of chondrules and calcium‐aluminum‐rich inclusion (CAI) set within phyllosilicate‐dominated matrix (mainly serpentine), pyrrhotite, pentlandite, tochilinite, and variable amounts of Ca‐Mg‐Fe carbonates. Some lithologies have witnessed sufficient thermal metamorphism to transform phyllosilicates into fine‐grained olivine, tochilinite into troilite, and destroy carbonates. One finely comminuted lithology contains xenolithic materials (enstatite, Fe‐Cr phosphides) suggesting impact of a reduced asteroid (E or M class) onto the main Sutter's Mill parent asteroid, which was probably a C class asteroid. One can use Sutter's Mill to help predict what will be found on the surfaces of C class asteroids such as Ceres and the target asteroids of the OSIRIS‐REx and Hayabusa 2 sample return missions (which will visit predominantly primitive asteroids). C class asteroid regolith may well contain a mixture of hydrated and thermally dehydrated indigenous materials as well as a significant admixture of exogenous material would be essential to the successful interpretation of mineralogical and bulk compositional data. 相似文献
This is the second paper of the series where we have considered Brans-Dicke (B-D) theory as well as general scalar tensor
theory of gravitation in higher dimensional space-time model in the false vacuum state. We have examined whether inflationary
solutions are possible both for constant or variable coupling parameter ω. Also the nature of the scalar field and the coupling
parameter are discussed in the asymptotic limit.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献