Evidence for high‐temperature fractionation of lithium isotopes during differentiation of the Moon          下载免费PDF全文

James M. D. Day  Lin Qiu  Richard D. Ash  William F. McDonough  Fang‐Zhen Teng  Roberta L. Rudnick  Lawrence A. Taylor 《Meteoritics & planetary science》2016,51(6):1046-1062

Lithium isotope and abundance data are reported for Apollo 15 and 17 mare basalts and the LaPaz low‐Ti mare basalt meteorites, along with lithium isotope data for carbonaceous, ordinary, and enstatite chondrites, and chondrules from the Allende CV3 meteorite. Apollo 15 low‐Ti mare basalts have lower Li contents and lower δ⁷Li (3.8 ± 1.2‰; all uncertainties are 2 standard deviations) than Apollo 17 high‐Ti mare basalts (δ⁷Li = 5.2 ± 1.2‰), with evolved LaPaz mare basalts having high Li contents, but similar low δ⁷Li (3.7 ± 0.5‰) to Apollo 15 mare basalts. In low‐Ti mare basalt 15555, the highest concentrations of Li occur in late‐stage tridymite (>20 ppm) and plagioclase (11 ± 3 ppm), with olivine (6.1 ± 3.8 ppm), pyroxene (4.2 ± 1.6 ppm), and ilmenite (0.8 ± 0.7 ppm) having lower Li concentrations. Values of δ⁷Li in low‐ and high‐Ti mare basalt sources broadly correlate negatively with ¹⁸O/¹⁶O and positively with ⁵⁶Fe/⁵⁴Fe (low‐Ti: δ⁷Li ≤4‰; δ⁵⁶Fe ≤0.04‰; δ¹⁸O ≥5.7‰; high‐Ti: δ⁷Li >6‰; δ⁵⁶Fe >0.18‰; δ¹⁸O <5.4‰). Lithium does not appear to have acted as a volatile element during planetary formation, with subequal Li contents in mare basalts compared with terrestrial, martian, or vestan basaltic rocks. Observed Li isotopic fractionations in mare basalts can potentially be explained through large‐degree, high‐temperature igneous differentiation of their source regions. Progressive magma ocean crystallization led to enrichment in Li and δ⁷Li in late‐stage liquids, probably as a consequence of preferential retention of ⁷Li and Li in the melt relative to crystallizing solids. Lithium isotopic fractionation has not been observed during extensive differentiation in terrestrial magmatic systems and may only be recognizable during extensive planetary magmatic differentiation under volatile‐poor conditions, as expected for the lunar magma ocean. Our new analyses of chondrites show that they have δ⁷Li ranging between ?2.5‰ and 4‰. The higher δ⁷Li in planetary basalts than in the compilation of chondrites (2.1 ± 1.3‰) demonstrates that differentiated planetary basalts are, on average, isotopically heavier than most chondrites.  相似文献   

Evidence for distinct proportions of subducted oceanic crust and lithosphere in HIMU-type mantle beneath El Hierro and La Palma, Canary Islands     

James M.D. Day  D. Graham Pearson  David Lowry 《Geochimica et cosmochimica acta》2010,74(22):6565-6589

Shield-stage high-MgO alkalic lavas from La Palma and El Hierro (Canary Islands) have been characterized for their O-Sr-Nd-Os-Pb isotope compositions and major-, trace-, and highly siderophile-element (HSE: Os, Ir, Ru, Pt, Pd, Re) abundances. New data are also reported for associated evolved rocks, and entrained xenoliths. Clear differences in Pd/Ir and isotopic ratios for high Os (>50 ppt) lavas from El Hierro (δ¹⁸O_olivine = 5.17 ± 0.08‰; ⁸⁷Sr/⁸⁶Sr = 0.7029 to 0.7031; ε_Nd = +5.7 to +7.1; ¹⁸⁷Os/¹⁸⁸Os = 0.1481 to 0.1750; ²⁰⁶Pb/²⁰⁴Pb = 19.1 to 19.7; Pd/Ir = 6 ± 3) versus those from La Palma (δ¹⁸O_olivine = 4.87 ± 0.18‰; ⁸⁷Sr/⁸⁶Sr = 0.7031 to 0.7032; ε_Nd = +5.0 to +6.4; ¹⁸⁷Os/¹⁸⁸Os = 0.1421 to 0.1460; ²⁰⁶Pb/²⁰⁴Pb = 19.5 to 20.2; Pd/Ir = 11 ± 4) are revealed from the dataset.Crustal or lithospheric assimilation during magma transport cannot explain variations in isotopic ratios or element abundances of the lavas. Shallow-level crystal-liquid fractionation of olivine, clinopyroxene and associated early-crystallizing minerals (e.g., spinel and HSE-rich phases) controlled compatible element and HSE abundances; there is also evidence for sub-aerial degassing of rhenium. High-MgO lavas are enriched in light rare earth elements, Nb, Ta, U, Th, and depleted in K and Pb, relative to primitive mantle abundance estimates, typical of HIMU-type oceanic island basalts. Trace element abundances and ratios are consistent with low degrees (2-6%) of partial melting of an enriched mantle source, commencing in the garnet stability field (?110 km). Western Canary Island lavas were sulphur undersaturated with estimated parental melt HSE abundances (in ppb) of 0.07 ± 0.05 Os, 0.17 ± 0.16 Ir, 0.34 ± 0.32 Ru, 2.6 ± 2.5 Pt, 1.4 ± 1.2 Pd, 0.39 ± 0.30 Re. These estimates indicate that Canary Island alkali basalts have lower Os, Ir and Ru, but similar Pt, Pd and Re contents to Hawai’ian tholeiites.The HIMU affinities of the lavas, in conjunction with the low δ¹⁸O_olivine and high ²⁰⁶Pb/²⁰⁴Pb for La Palma, and elevated ¹⁸⁷Os/¹⁸⁸Os for El Hierro implies melting of different proportions of recycled oceanic crust and lithosphere. Our preferred model to explain isotopic differences between the islands is generation from peridotitic mantle metasomatised by <10% pyroxenite/eclogite made from variable portions of similar aged recycled oceanic crust and lithosphere. The correspondence of radiogenic ²⁰⁶Pb/²⁰⁴Pb, ¹⁸⁷Os/¹⁸⁸Os, elevated Re/Os and Pt/Os, and low-δ¹⁸O in western Canary Island lavas provides powerful support for recycled oceanic crust and lithosphere to generate the spectrum of HIMU-type ocean island basalt signatures. Persistence of geochemical heterogeneities throughout the stratigraphies of El Hierro and La Palma demonstrate long-term preservation of these recycled components in their mantle sources over relatively short-length scales (∼50 km).  相似文献   

Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation     

Y. Thomas He  Arthur G. Fitzmaurice  Azra Bilgin  Sunkyung Choi  Peggy O’Day  John Horst  James Harrington  H. James Reisinger  David R. Burris  Janet G. Hering 《Applied Geochemistry》2010

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.  相似文献   

Low dispersive modeling of Rayleigh waves on partly staggered grids     

O. Rojas  B. Otero  J. E. Castillo  S. M. Day 《Computational Geosciences》2014,18(1):29-43

In elastic media, finite-difference (FD) implementations of free-surface (FS) boundary conditions on partly staggered grid (PSG) use the highly dispersive vacuum formulation (VPSG). The FS boundary is embedded into a “vacuum” grid layer (null Lame’s constants and negligible density values) where the discretized equations of motion allow computing surface displacements. We place a new set of compound (stress-displacement) nodes along a planar FS and use unilateral mimetic FD discretization of the zero-traction conditions for displacement computation (MPSG). At interior nodes, MPSG reduces to standard VPSG methods and applies fourth-order centered FD along cell diagonals for staggered differentiation combined with nodal second-order FD in time. We perform a dispersion analysis of these methods on a Lamb’s problem and estimate dispersion curves from the phase difference of windowed numerical Rayleigh pulses at two FS receivers. For a given grid sampling criterion (e.g., six or ten nodes per reference S wavelength λ ^S), MPSG dispersion errors are only a quarter of the VPSG method. We also quantify root-mean-square (RMS) misfits of numerical time series relative to analytical waveforms. MPSG RMS misfits barely exceed 10 % when nine nodes sample the minimum S wavelength $\lambda _{\text {MIN}}^{\mathrm {S}}$ in transit (along distances $\sim $ 145 $\lambda _{\text {MIN}}^{\mathrm {S}}$ ). In same tests, VPSG RMS misfits exceed 70 %. We additionally compare MPSG to a consistently fourth-order mimetic method designed on a standard staggered grid. The latter equates the former’s dispersion errors on grids twice denser and shows higher RMS precision only on grids with six or less nodes per $\lambda _{\text {MIN}}^{\mathrm {S}}$ .  相似文献   

Discovery of possible mega-thrust earthquake along the Seram Trough from records of 1629 tsunami in eastern Indonesian region   总被引：1，自引：1，他引：0  

Zac Yung-Chun Liu  Ron A. Harris 《Natural Hazards》2014,72(3):1311-1328

Arthur Wichmann’s “Earthquakes of the Indian Archipelago” documents several large earthquakes and tsunami throughout the Banda Arc region that can be interpreted as mega-thrust events. However, the source regions of these events are not known. One of the largest and well-documented events in the catalog is the great earthquake and tsunami affecting the Banda Islands on August 1, 1629. It caused severe damage from a 15-m tsunami that arrived at the Banda Islands about a half hour after violent shaking stopped. The earthquake was also recorded 230 km away in Ambon, but no tsunami is mentioned. This event was followed by at least 9 years of uncommonly frequent seismic activity in the region that tapered off with time, which can be interpreted as aftershocks. The combination of these observations indicates that the earthquake was most likely a mega-thrust event. We use an inverse modeling approach to numerically reconstruct the tsunami, which constrains the likely location and magnitude of the 1629 earthquake. Only, linear numerical models are applied due to the low resolution of bathymetry in the Banda Islands and Ambon. Therefore, we apply various wave amplification factors (1.5–4) derived from simulations of recent, well-constrained tsunami to bracket the upper and lower limits of earthquake moment magnitudes for the event. The closest major earthquake sources to the Banda Islands are the Tanimbar and Seram Troughs of the Banda subduction/collision zone. Other source regions are too far away for such a short arrival time of the tsunami after shaking. Moment magnitudes predicted by the models in order to produce a 15-m tsunami are M_w of 9.8–9.2 on the Tanimbar Trough and M_w 8.8–8.2 on the Seram Trough. The arrival times of these waves are 58 min for Tanimbar Trough and 30 min for Seram Trough. The model also predicts 5-m run-up for Ambon from a Tanimbar Trough source, which is inconsistent with the historical records. Ambon is mostly shielded from a wave generated by a Seram Trough source. We conclude that the most likely source of the 1629 mega-thrust earthquake is the Seram Trough. Only one earthquake >M_w 8.0 is recorded instrumentally from the eastern Indonesia region although high rates of strain (50–80 mm/a) are measured across the Seram section of the Banda subduction zone. Enough strain has already accumulated since the last major historical event to produce an earthquake of similar size to the 1629 event. Due to the rapid population growth in coastal areas in this region, it is imperative that the most vulnerable coastal areas prepare accordingly.  相似文献   

Advancing process‐based watershed hydrological research using near‐surface geophysics: a vision for,and review of,electrical and magnetic geophysical methods     

D. A. Robinson  A. Binley  N. Crook  F. D. Day‐Lewis  T. P. A. Ferré  V. J. S. Grauch  R. Knight  M. Knoll  V. Lakshmi  R. Miller  J. Nyquist  L. Pellerin  K. Singha  L. Slater 《水文研究》2008,22(18):3604-3635

We want to develop a dialogue between geophysicists and hydrologists interested in synergistically advancing process based watershed research. We identify recent advances in geophysical instrumentation, and provide a vision for the use of electrical and magnetic geophysical instrumentation in watershed scale hydrology. The focus of the paper is to identify instrumentation that could significantly advance this vision for geophysics and hydrology during the next 3–5 years. We acknowledge that this is one of a number of possible ways forward and seek only to offer a relatively narrow and achievable vision. The vision focuses on the measurement of geological structure and identification of flow paths using electrical and magnetic methods. The paper identifies instruments, provides examples of their use, and describes how synergy between measurement and modelling could be achieved. Of specific interest are the airborne systems that can cover large areas and are appropriate for watershed studies. Although airborne geophysics has been around for some time, only in the last few years have systems designed exclusively for hydrological applications begun to emerge. These systems, such as airborne electromagnetic (EM) and transient electromagnetic (TEM), could revolutionize hydrogeological interpretations. Our vision centers on developing nested and cross scale electrical and magnetic measurements that can be used to construct a three‐dimensional (3D) electrical or magnetic model of the subsurface in watersheds. The methodological framework assumes a ‘top down’ approach using airborne methods to identify the large scale, dominant architecture of the subsurface. We recognize that the integration of geophysical measurement methods, and data, into watershed process characterization and modelling can only be achieved through dialogue. Especially, through the development of partnerships between geophysicists and hydrologists, partnerships that explore how the application of geophysics can answer critical hydrological science questions, and conversely provide an understanding of the limitations of geophysical measurements and interpretation. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

A search for distant radio galaxies from SUMSS and NVSS – III. Radio spectral energy distributions and the z–α correlation     

Ilana J. Klamer  Ron D. Ekers  Julia J. Bryant  Richard W. Hunstead  Elaine M. Sadler  Carlos De Breuck 《Monthly notices of the Royal Astronomical Society》2006,371(2):852-866

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New interpretation of the Franciscan mélange at San Simeon coast,California: tectonic intrusion into an accretionary prism     

Yujiro Ogawa  Ryota Mori  Toshiaki Tsunogae  Yildirim Dilek  Ron Harris 《International Geology Review》2015,57(5-8):824-842

Many concepts and interpretations on the formation of the Franciscan mélange have been proposed on the basis of exposures at San Simeon, California. In this paper, we show the distribution of chaotic rocks, their internal structures and textures, and the interrelationship between the chaotic rocks and the surrounding sandstones (turbidites). Mélange components, particularly blueschists, oceanic rocks, including greenstone, pillow lava, bedded chert, limestone, sandstone, and conglomerate, have all been brecciated by retrograde deformation. The Cambria Slab, long interpreted as a trench slope basin, is also strongly deformed by fluidization, brecciation, isoclinal folding, and thrusting, leading us to a new interpretation that turbiditic rocks (including the Cambria Slab) represent trench deposits rather than slope basin sediments. These rocks form an accretionary prism above mélanges that were diapirically emplaced into these rocks first along sinistral-thrust faults, and then along dextral-normal faults. Riedel shear systems are observed in several orders of scale in both stages. Although the exhumation of the blueschist blocks is still controversial, the common extensional fractures and brecciation in most of the blocks in the mélanges and further mixture of various lithologies into one block with mélange muddy matrix indicate that once deeply buried blocks were exhumed from considerable depths to the accretionary prism body, before being diapirically intruded with their host mélange along thrust and normal faults, during which retrograde deformation occurred together with retrograde metamorphism. Recent similar examples of high-pressure rock exhumation have been documented along the Sofugan Tectonic Line in the Izu forearc areas, in the Mineoka belt in the Boso Peninsula, and as part of accretionary prism development in the Nankai and Sagami troughs of Japan. These modern analogues provide actively forming examples of the lithological and deformational features that characterize the Franciscan mélange processes.  相似文献   

Deep events in U.K. South Western Approaches     

R.R. Hillis  G.A. Day 《Geophysical Journal International》1987,89(1):243-250

Summary. Apparently planar dipping events are observed in seismic data off south-west Britain within otherwise essentially transparent upper and middle crust. These are believed to represent Variscan thrusts, some of which were re-activated during the post-Carboniferous phase of extension that affected the southern U.K. They can be seen in two extensive commercial seismic surveys recorded to 6 s two-way-time (TWT) and, where laterally persistent, they have been mapped to reveal their essentially planar nature. Commonly these dipping events are associated with deeper, near-horizontal, or gently convex upwards events with which they often appear to converge. Where 'real', these are thought to indicate a complex fault system or possibly the top of the reflective lower crust. The thrusts are seen over the whole area except where granite is known to occur, and commonly exert a major control on the position and subsequent deformation of overlying sedimentary basins.  相似文献   

Water planning priorities and conflicts in The Hunter Valley,NSW     

D. G. Day 《The Australian geographer》1986,17(2):153-167

This paper examines the ability of society to develop and allocate water resources during a time of major drought and industrial growth. Water shortage in the upper Hunter became apparent between 1979 and 1983. Even the well watered Newcastle metropolitan area experienced domestic and commercial restrictions. Strategies to deal with the immediate problems in inland areas included temporary water restrictions, cessation of issue of new irrigation licences, institution of volumetric water allocation to agriculture and appeals for public cooperation. Government was placed under pressure to provide sufficient industrial water, maintain supplies to agriculture and distribute water resource information to private and public sector decision makers. Major regional water planning initiatives were almost as slow to eventuate as those for social infrastructure provision. Such crises are likely to recur. Questions remain as to the desirability and sufficiency of current allocative mechanisms to cope with the future diversity of water needs.  相似文献