The effects of sub-blocking temperature metamorphism on the K/Ar systematics of hornblendes: 40Ar/39Ar dating of polymetamorphic garnet amphibolite from the Franciscan Complex,California     

J. A. Ross  W. D. Sharp 《Contributions to Mineralogy and Petrology》1988,100(2):213-221

The effects of sub-blocking temperature metamorphism on the K/Ar system in hornblende, as revealed by ⁴⁰Ar/³⁹Ar release spectra, have been studied in a polymetamorphic knocker from the Franciscan Complex (FC), California. A primary amphibolite assemblage of horn-blende +rutile+epidote+apatite±garnet±sphene is variably overprinted by a blueschist facies assemblage of blue amphibole +lawsonite+chlorite+white mica+pumpellyite±sphene. The secondary assemblage formed at a temperature of 370° C, below that at which rapid Ar diffusion is expected in hornblende. Hornblendes from three, variably-altered samples of garnet amphibolite yield total gas ages of 147 to 161 Ma, but the corresponding plateau ages of 163.0±2.8, 160.6±2.2, and 161.8±2.2 Ma are identical within error. Hornblende separates with lower total gas ages come from more highly overprinted rocks, have excess K compared to that expected on the basis of electron probe analyses, and exhibit anomalously high K/Ca ratios in the low-temperature fractions of their incremental heating spectra. The reduced total gas ages result from the presence of thin (2 m) sheets of younger white mica in hornblendes from the moderately and highly altered amphibolites. The secondary micas are difficult to detect because of their small size and low abundance (2%), but because their K content is 50 to 100 times that of the host hornblende, they contribute significantly to the K and Ar budgets of the sample. The mica intergrowths are not removed by normal sample preparation, but because the mica inclusions degas at lower temperatures than hornblende during vacuum extraction, incremental heating analyses can provide precise cooling ages for the hornblendes as well as useful estimates of the age of the mica inclusions. The hornblende separate from the most altered sample contained 20±10% younger blue amphibole replacing hornblende, but its plateau age was not significantly affected. This is consistent with a replacement process in which K and Ar loss from the hornblende are coupled, leaving the K/Ar system undisturbed in relict primary grains. The K and Ar budgets of the sample are not strongly affected by the blue amphibole because of its very low K content. Because partial replacement of primary amphibole by high-K phyllosilicates occurs in many geological environments, effects like those described here could be widespread.  相似文献   

Geostatistical Estimation of Hydraulic Head Gradients     

Ross D. Philip  Peter K. Kitanidis 《Ground water》1989,27(6):855-865

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Subsurface transport in water and gas     

Benjamin Ross  Steven Amter 《Engineering Geology》1989,26(4):373-403

Current designs for nuclear-waste repositories rely primarily upon subsurface geologic barriers for long-term containment. Because water and air are generally considered to be the mechanisms most likely to transport radioactivity to the surface environment, flow and transport models are important tools in repository assessment. Most models assume that the geologic medium can be treated as a continuum. A substantial body of recent work has focused on applying these models to difficult-to-solve problems, such as the simulation of variably dense or variably saturated flow and transport, large and complex flow systems, sharp solute concentration fronts, and fractured rock systems. The complex chemical interactions between the transport fluid and solid particles within the system have been analyzed using geochemical flow models, most of which assume that the system is at chemical equilibrium. The role of colloids in contaminant transport is a relatively new area of research. The large-scale effects of small-scale variability within the geologic system have been the subject of intense investigation. Inherent limitations of the continuum approach have prompted the design of models in which the flow occurs in discrete fractures. The difficulty and complexity of simulating transport has led to the development of network transport models, which represent the flow field as a series of 1-D path segments. The widespread use of models for prediction and analysis has prompted investigations of their reliability and relative merits.  相似文献   

Early accretional history of the Earth and the Moon-forming event     

Stuart Ross Taylor 《Lithos》1993,30(3-4):207-221

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Strike-angle determination from the magnetotelluric impedance tensor in the presence of noise and local distortion: rotate at your peril!   总被引：2，自引：0，他引：2  

Alan G. Jones  Ross W. Groom 《Geophysical Journal International》1993,113(2):524-534

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Time-scale calibration by high-precision UPb zircon dating of interstratified volcanic ashes in the Ordovician and Lower Silurian stratotypes of Britain     

R.D. Tucker  T.E. Krogh  R.J. Ross Jr.  S.H. Williams 《Earth and Planetary Science Letters》1990,100(1-3)

High initial parent/daughter element ratios and a unique dual decay scheme make UPb zicron ages more precise and reliable than most isotopic ages, and thus inherently superior for time-scale calibration. Employing improved techniques to the conventional method of UPb dating, we have analyzed microgram-size (2–12 × 10⁻⁸ g) zircon fractions from biostratigraphically controlled volcanic ashes and dated key Paleozoic time-markers with a precision better than 1% (±2Ma). Four of the stratotype samples from Britain for which fission-track ages [1] were previously reported have yielded improved ages of:438.7 ± 2.0Ma for the lower Silurian zone of Coronograptus cyphus from Llandovery strata at Dob's Linn, southern Scotland;457.5 ± 2.2 Ma for a Middle Ordovician Caradoc (Longvillian) ash near Bala, North Wales, and;465.7 ± 2.1and464.6 ± 1.8 Ma for the Didymograptus artus Zone and the type Didymograptus Murchisoni Zone, respectively, of the Llanvirn Series at Arenig Fawr and Abereiddi Bay, Wales. Another sample from the zone of Dicellograptus anceps (P. pacificus Subzone) of the Ashgill Series at Dob's Linn has been dated at445.7 ± 2.4Ma, suggesting placement of the Ordovician-Silurian time boundary at approximately 441 Ma. A sixth bentonite from Caradocian age strata of North America (Spechts Ferry Shale, Decorah Formation, Missouri) is453.7 ± 1.8Ma old, indicating that the Rocklandian Stage of the Mohawkian Series is only slightly younger than the Longvillian Stage of the Caradoc Series in Britain.  相似文献   

An examination of the use of the logratio transformation for the testing of endmember hypotheses     

Ross M. Renner 《Mathematical Geology》1991,23(4):549-563

Given a compositional dataset in the absence of any prior information on any mixing process which may have formed it, a complete analysis of mixtures determines three distinct types of estimates in order. These are: (i) the estimate of the number of endmembers or fixed source compositions, of which all the sample compositions of the dataset must be approximate mixtures; (ii) the estimated compositions for each of these chosen number of endmembers; and (iii) the estimated contributions of each of these endmember estimates to each sample. Traditionally, the estimate for the number of endmembers has been assessed either by mapping or by inspection of the coefficients of determination between the observed and estimated variables. Mapping entails the plotting on a map of the region from which the samples were taken, either the contours of the contributions of each endmember to each sample, or some other portrayal of the distribution of endmember abundances. Because it requires the complete analysis, assessment by this method is too elaborate except for final confirmation and display. Alternatively, choosing a number of endmembers, which result in suitability high coefficients of determination for all or most variables, may account for elements which are not part of the conjectured mixing process or, worse, may result in the identification of endmembers which may never in fact have existed. Such an error is similar to overspecifying a multiple regression model. So, the obvious starting point from which to assess the validity, or otherwise choice of endmember numbers, is to examine the matrix of residuals. The differences between the logratio-transformed observed and estimated data form an array of residual logratios. A linear combination of these may be formed for each sample, which, under a random perturbation assumption, should follow a univariate normal distribution. Whether or not this scalar is normal can be readily tested. It can also be examined graphically for such desirable qualities as symmetry when the test for normality may be too severe. This procedure is employed to assess the decompositions of the U.S.G.S. Mid-Pacific data and the Nazca Plate Surface sediments.This paper was presented at the 18th Geochautauqua, Newark, Delaware, 13–14 October 1989.  相似文献   

Temperature dependence of the cation distribution in nickel aluminate (NiAl2O4) spinel: a powder XRD study     

H. St. C. O'Neill  W. A. Dollase  C. R. Ross II 《Physics and Chemistry of Minerals》1991,18(5):302-319

NiAl₂O₄ is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl₂O₄ quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a₀, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).  相似文献   

Sediment budgeting: A case study in the Katiorin drainage basin,Kenya     

Ross A. Sutherland  Rorke B. Bryan 《地球表面变化过程与地形》1991,16(5):383-398

The primary objective of this study was to compute a detailed budget for a small semiarid tropical drainage basin in Kenya. Results indicated that transfer of sediments (‘inputs’) from primary source areas was minor in comparison to changes in storage. The major sediment source area within the Katiorin drainage basin was the colluvial hillslope zone. The net change in storage within this zone was approximately 2100 Mg yr^?1. Surface wash and rilling were the dominant transport processes responsible for the remobilization of colluvial sediments. Sediment storage within the in-channel reservoir increased by 60 Mg yr^?1, which was minor when compared to the total store of sediment in this reservoir. During 1986, the channel network stored only a small fraction ( < 3 per cent) of the sediment delivered from the hillslope subsystem. Therefore, the in-channel reservoir had limited influence on sediment conveyance to the basin outlet. These data indicate that a static equilibrium condition cannot be assumed within the Katiorin drainage basin. Such an assumption would result in erosion estimates of approximately 5.5 mm yr^?1 for the entire basin (based on a sediment output of 7430 Mg km^?2 yr^?1 and a measured bulk density of 1.35 Mg m^?3). However, this masked the actual rates of 1.2 to 7.1 mm yr^?1 in subbasin primary source areas, and rates of 0.6 to 17 mm yr^?1 for colluvial material in the various subbasins. The extreme accelerated erosion rates resulted from minimal ground vegetation, steep slopes, soil crust formation, an erodible substrate, and a well-integrated drainage network for rapid conveyance of sediments from the hillslope subsystem to the basin outlet.  相似文献   

Geometry of a convergent zone, Central British Columbia, Canada     

J.V. Ross  J. Fillipone  J.R. Montgomery  D.C. Elsby  M. Bloodgood 《Tectonophysics》1985,119(1-4)

The Canadian Cordillera is separable into two major northerly trending tectonic units—the Pacific Orogen and the Columbian Orogen, with the latter further separated into the Omineca Crystalline Belt and the easterly Rocky Mountain Fold and Thrust Belt. Synkinematic metamorphism of Jurassic age within the Omineca Belt is thought to be associated with accretion of westerly terranes of the Pacific Orogen—more specifically the Quesnellia terrane—that was thrust easterly over the Omineca Belt towards the craton. Mylonitic rocks mark the margin between these two belts and this margin is well-exposed near Crooked Lake, central British Columbia.Structural analysis across the zone of convergence between these two terranes indicates that the cratonic basement and the accreted cover sequences have several phases of deformation and metamorphism in common. The initial common phase of deformation, wherein convergence is accomplished, is characterized by easterly verging folds that are superposed by a second common phase having westerly verging folds that deform the zone of convergence and control the present regional map pattern. A final common phase of deformation produced easterly verging folds.Change in vergence direction is interpreted as resulting from change in direction of transport related to subduction process: first obduction of Quesnellia onto the Omineca craton, followed later by easterly subduction of an oceanic Quesnellia below the craton.All evidence of transport direction(s) points to convergence occurring at very high angles to the zone of convergence. There appears to be no evidence of transport parallel with the strike of the zone. If transport has taken place parallel to the strike of the zone, then this transport occurred before convergence or evidence of this motion has been destroyed during the convergence.  相似文献