Al,Si ordering in cordierite using “magic angle spinning” NMR     

Andrew Putnis  Ross J. Angel 《Physics and Chemistry of Minerals》1985,12(4):217-222

A method of determining the number of Al-O-Al bonds per unit cell from ²⁹Si nuclear magnetic resonance (NMR) data of synthetic cordierites with increasing Si, Al order is described. The number of Al-O-Al bonds is found to vary linearly with the logarithm of the annealing time. This may be correlated with previously published heat of solution data on similar samples (Carpenter et al. 1983) to determine the enthalpy change Δh, associated with a single Al?Si interchange in cordierite. Δh is found to be 8.1 kcal/mole. The NMR data show that the short range Al, Si order cannot be described in terms of twin domains of ordered orthorhombic cordierite. An ordering model derived from group theoretical constraints on possible Al, Si distributions within the hexagonal symmetry of the cordierite is found to provide a better fit to the NMR data.  相似文献   

Weighting of Observed Heads for the Inverse Problem     

Benjamin Ross 《Ground water》1984,22(5):569-572

In using least-squares parameter estimation techniques to solve for hydrogeologic parameters, one may use a weighting function to reflect differing reliabilities of head measurements. In studies published to date, the weighting function has been used in an ad boc manner or not at all. The inverse square of the observed hydraulic gradient, adjusted to reflect the modeler's perception of geologic heterogeneity and data reliability, is typically an appropriate weighting function.  相似文献   

Detailed documentation of a Holocene sea-level record in the perth region, southern Western Australia     

D. J. Searle  P. J. Woods 《Quaternary Research》1986,26(3)

Holocene prograded coastal sequences at Becher/Rockingham, southern Western Australia, contain a detailed record of sea level over the last 6400 yr. Radiocarbon dating and use of a distinct stratigraphic indicator as a sea-level marker permit reconstruction of sea-level history and suggest that the sea was at least 2.5 m above present datum about 6400 yr B.P. before falling to its present level. No evidence was found for eustatic fluctuations of the scale proposed by R. W. Fairbridge [1961, in “Physics and Chemistry of the Earth” (L. H. Ahrens, F. Press, K. Rankema, and S. K. Runcorn, Eds.), Vol. 4, pp. 99–185, Pergamon, Oxford]. The sea-level record preserved on this coast can be explained by hydro-isostasy, tectonism, or eustasy, acting individually or in concert. Without a fixed reference point or analogous data from other locations, a firm conclusion on which mechanism(s) has(have) operated could not be reached. Published sea-level data from this and other coasts are often insufficiently detailed to compare with this study. Application of the techniques of this study to analogous sedimentary sequences elsewhere will provide data of comparable accuracy that would contribute to a more precise understanding of relative sea-level movements in the late Quaternary.  相似文献   

Book review     

William D. Stuart  Kacper Rybicki  Brian J. Mitchell  Daniel Moos  Jeanne Sauber  Bernard Vonnegut  Ross J. Salawitch  David S. Gutzler 《Pure and Applied Geophysics》1987,125(5):853-855

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Compositional and thermal convection in magma chambers   总被引：7，自引：1，他引：7  

Daniel Martin  Ross W. Griffiths  Ian H. Campbell 《Contributions to Mineralogy and Petrology》1987,96(4):465-475

Magma chambers cool and crystallize at a rate determined by the heat flux from the chamber. The heat is lost predominantly through the roof, whereas crystallization takes place mainly at the floor. Both processes provide destabilizing buoyancy fluxes which drive highly unsteady, chaotic convection in the magma. Even at the lowest cooling rates the thermal Rayleigh number Ra is found to be extremely large for both mafic and granitic magmas. Since the compositional and thermal buoyancy fluxes are directly related it can be shown that the compositional Rayleigh number Rs (and therefore a total Rayleigh number) is very much greater than Ra. In the case of basaltic melt crystallizing olivine Rs is up to 10⁶ times greater than Ra. However compositional and thermal buoyancy fluxes are roughly equal. Therefore thermal and compositional density gradients contribute equally to convection velocities in the interior of the magma. Effects of thermal buoyancy generated by latent heat release at the floor are included.The latent heat boundary layer at the floor of a basaltic chamber is shown to be of the order of 1 m thick with very low thermal gradients whereas the compositional boundary layer is about 1 cm thick with large compositional gradients. As a consequence, the variation in the degree of supercooling in front of the crystal-liquid interface is dominated by compositional effects. The habit and composition of the growing crystals is also controlled by the nature of the compositional boundary layer. Elongate crystals are predicted to form when the thickness of the compositional boundary layer is small compared with the crystal size (as in laboratory experiments with aqueous solutions). In contrast, equant crystals form when the boundary layer is thicker than the crystals (as in most magma chambers). Instability of the boundary layer in the latter case gives rise to zoning within crystals. Diffusion of compatible trace elements through the boundary layer can also explain an inverse correlation, observed in layered intrusions, between Ni concentration in olivine and the proportion of Ni-bearing phases in the crystallizing assemblage.  相似文献   

Diffusion of dissolved carbonate in magmas: Experimental results and applications     

E. Bruce Watson  Mark A. Sneeringer  Alan Ross 《Earth and Planetary Science Letters》1982,61(2):346-358

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Late Cretaceous genesis of the Kula plate     

Mark T. Woods  Geoffrey F. Davies 《Earth and Planetary Science Letters》1982,58(2):161-166

We propose that the Pacific-Kula ridge began spreading approximately 85 m.y. B.P., during Late Cretaceous time. Extrapolation of the Great Magnetic Bight backwards in time results in an implausible ridge configuration. This implies that plate velocity vectors for the Pacific, Kula, and Farallon plates were not constant during this interval. Evidence for splitting of the Kula plate from the Pacific plate along the Chinook trough is the relationship between the north-striking Amlia and Adak fracture zones, the Chinook and Emperor troughs, and the magnetic lineations south of the Aleutian trench. If this hypothesis is correct, it will require that Mesozoic reconstructions of the Pacific basin and their relation to Cenozoic reconstructions be re-examined. A previously unrecognized Mesozoic plate may be required. We propose calling this the Izanagi plate.  相似文献   

Patterns in seasonal abundance,growth and biomass of the atlantic silverside,Menidia menidia,in a New England estuary     

David O. Conover  Michael R. Ross 《Estuaries and Coasts》1982,5(4):275-286

Patterns in seasonal abundance (no. per m² surface area), growth and biomass (g per m² surface area) of an annual fish, the Atlantic silverside, Menidia menidia (L.) were investigated in a marsh and more seaward bay region of Essex Bay, Massachusetts from August 1976 to May 1978 using a quantitative beach seining technique. Silverside abundance varied greatly by season and year class during the study period. Abundance was high in 1976 but winter mortality (99%) left an adult density of only .01 per m² surface area in the marsh during spring 1977. Resultant 1977 year class density in the marsh was 1.88 per m² by late fall 1977 but winter mortality again produced an adult density of .01 per m² in spring 1978. Abundance was generally higher in the marsh than in the bay region especially during spring and late fall when catches in the bay were negligible. Based on catch rate comparisons, the summer and fall juvenile abundance of the 1976 year class was much higher than the juvenile abundance of the 1977 year class. Coincidentally, mean lengths and condition of the abundant 1976 year class in the late fall were significantly lower than those of the 1977 year class, suggesting density dependent population regulation. In both years, juveniles grew rapidly and reached full adult size by November when an offshore movement to deeper waters outside Essex Bay occurred. Biomass peaked in the marsh region in late fall 1977 at 7.8 g per m² wet weight. Winter mortality was size selective, favoring larger individuals. The annual life history design of M. menidia including an offshore winter movement and high winter mortality suggests that silversides represent an important pathway of energy flow from marsh to offshore trophic systems.  相似文献   

The chemistry of soil processes | D.J. Greenland and M.H.B. Hayes, 1981. Wiley,Chichester, xiii + 714 pp., £stg.36.00     

G.J. Ross 《Earth》1982,18(2):190-191

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Proterozoic aeolian quartz arenites from the Hornby Bay Group, Northwest Territories, Canada: Implications for Precambrian aeolian processes     

Gerald M. Ross 《Precambrian Research》1983,20(2-4)

The Hornby Bay Group is a Middle Proterozoic 2.5 km-thick succession of terrestrial siliciclastics overlain by marine siliciclastics and carbonates. A sequence of conglomeratic and arenaceous rocks at the base of the group contains more than 500 m of mature hematitic quartz arenite interpreted to have been deposited by migrating aeolian bedforms. Bedforms and facies patterns of modern aeolian deposits provided a basis for recognizing two sequences of aeolian arenite. Both sequences interfinger with alluvial—wadi fan conglomerates and arenites deposited by braided streams. Depositional processes, facies patterns and paleotopographic position of the arenites are consistent with modern sand sea dynamics.Distal aeolian facies in both sequences are composed of trough crossbed megasets deposited by climbing, sinuous-crested, transverse dunes. Megasets comprise a gradational assemblage of tabular to wedge-planar cosets formed by deflation/reactivation of dune lee slopes and migration of smaller superposed aeolian bedforms (small dunes and wind ripples). Megasets in the proximal facies are thinner, display composite internal stratification and have a tabular-planar geometry which suggests that they were formed by smaller, straight-crested transverse dunes. Most stratification within the crossbeds is inferred to have formed by the downwind climbing of aeolian ripples across the lee slopes of dunes.Remarkably few Precambrian aeolian deposits have been reported previously. This seems anomalous, because most Precambrian fluvial sediments appear to have been deposited by low sinuosity (braided) streams, the emergent parts of which are prime areas for aeolian deflation. Frequent floods and rapid lateral migration of Precambrian humid climate fluvial systems probably restricted aeolianite deposition to arid paleoclimates. Thus the apparent anomaly may reflect non-recognition and/or non-preservation of aeolianites and/or variations in some aspect of sand sea formation and migration unique to the Precambrian. Reconstruction of the Hornby Bay Group aeolianites using recently developed criteria for their recognition suggests that the latter reason did not exert a strong influence.  相似文献