Persistent organic pollutants (POPs) in killer whales (Orcinus orca) from the Crozet Archipelago, southern Indian Ocean     

Marie Noël  Lance Barrett-Lennard  Christophe Guinet  Neil Dangerfield  Peter S. Ross   《Marine environmental research》2009,68(4):196-202

Persistent organic pollutants (POPs), including polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), and dibenzofurans (PCDFs), are ubiquitous environmental contaminants of which significant concentrations are reported in upper trophic level animals. In 1998, we collected blubber biopsy samples (n = 11) from killer whales (Orcinus orca) inhabiting the coastal waters around Possession Island, Crozet Archipelago, southern Indian Ocean, for contaminant analyses. Despite inhabiting an isolated region far removed from industrial activities, these killer whales can presently be considered among the most PCB-contaminated cetaceans in the southern hemisphere, with concentrations ranging from 4.4 to 20.5 mg/kg lipid weight (lw). PCDD levels ranged from below the detection limit (5 ng/kg) to 77.1 ng/kg lw and PCDF levels from below the detection limit (7 ng/kg) to 36.1 ng/kg lw. Over 70% of our study animals had PCB concentrations which exceeded a 1.3 mg/kg PCB threshold established for endocrine disruption and immunotoxicity in free-ranging harbour seals, suggesting that organic contaminants cannot be ruled out as an additional threat to this declining population.  相似文献   

The importance of shale composition and pore structure upon gas storage potential of shale gas reservoirs   总被引：14，自引：0，他引：14  

Daniel J.K. Ross  R. Marc Bustin 《Marine and Petroleum Geology》2009

The effect of shale composition and fabric upon pore structure and CH₄ sorption is investigated for potential shale gas reservoirs in the Western Canadian Sedimentary Basin (WCSB). Devonian–Mississippian (D–M) and Jurassic shales have complex, heterogeneous pore volume distributions as identified by low pressure CO₂ and N₂ sorption, and high pressure Hg porosimetry. Thermally mature D–M shales (1.6–2.5% VRo) have Dubinin–Radushkevich (D–R) CO₂ micropore volumes ranging between 0.3 and 1.2 cc/100 g and N₂ BET surface areas of 5–31 m²/g. Jurassic shales, which are invariably of lower thermal maturity ranging from 0.9 to 1.3% VRo, than D–M shales have smaller D–R CO₂ micropore volumes and N₂ BET surface areas, typically in the range of 0.23–0.63 cc/100 g (CO₂) and 1–9 m²/g (N₂).  相似文献   

Preface     

Benjamin Ross  Editor 《Engineering Geology》1989,26(4):III

  相似文献   

The Ensemble Kalman Filter for Groundwater Plume Characterization: A Case Study          下载免费PDF全文

James L. Ross  Peter F. Andersen 《Ground water》2018,56(4):571-579

The Kalman filter is an efficient data assimilation tool to refine an estimate of a state variable using measured data and the variable's correlations in space and/or time. The ensemble Kalman filter (EnKF) (Evensen 2004, 2009) is a Kalman filter variant that employs Monte Carlo analysis to define the correlations that help to refine the updated state. While use of EnKF in hydrology is somewhat limited, it has been successfully applied in other fields of engineering (e.g., oil reservoir modeling, weather forecasting). Here, EnKF is used to refine a simulated groundwater tetrachloroethylene (TCE) plume that underlies the Tooele Army Depot‐North (TEAD‐N) in Utah, based on observations of TCE in the aquifer. The resulting EnKF‐based assimilated plume is simulated forward in time to predict future plume migration. The correlations that underpin EnKF updating implicitly contain information about how the plume developed over time under the influence of complex site hydrology and variable source history, as they are predicated on multiple realizations of a well‐calibrated numerical groundwater flow and transport model. The EnKF methodology is compared to an ordinary kriging‐based assimilation method with respect to the accurate representation of plume concentrations in order to determine the relative efficacy of EnKF for water quality data assimilation.  相似文献   

Identifying the spatial pattern and importance of hydro‐geomorphic drainage impairments on unpaved roads in the northeastern USA          下载免费PDF全文

Beverley C. Wemple  Gordon E. Clark  Donald S. Ross  Donna M. Rizzo 《地球表面变化过程与地形》2017,42(11):1652-1665

Roads have been widely studied as sources of runoff and sediment and identified as pollutant production sources to receiving waters. Despite the wealth of research on logging roads in forested, upland settings, little work has been conducted to examine the role of extensive networks of rural, low‐volume, unpaved roads on water quality degradation at the catchment scale. We studied a network of municipal unpaved roads in the northeastern US to identify the type and spatial extent of ‘hydro‐geomorphic impairments’ to water quality. We mapped erosional and depositional features on roads to develop an estimate of pollutant production. We also mapped the type and location of design interventions or best management practices (BMPs) used to improve road drainage and mitigate water quality impairment. We used statistical analyses to identify key controls on the frequency and magnitude of erosional features on the road network, and GIS to scale up from the survey results to the catchment scale to identify the likely importance of unpaved roads as a pollutant source in this setting. An average of 21 hydro‐geomorphic impairments were mapped per kilometer of road, averaging 0.3 m³ in volume. Road gradient and slope position were key controls on the occurrence of these features. The presence of BMPs effectively reduced erosion frequency. Scaled up to the watershed and using a conservative estimate of road–stream connectivity, our results for the Winooski River watershed in the northeastern US suggest that roughly 16% and 6% of the average annual sediment and phosphorus flux, respectively, of the Winooski River may be derived from unpaved roads. Our study identifies an under‐appreciated source of water quality degradation in rural watersheds, provides insights into identifying ‘hot spots’ of pollutant production associated with these networks, and points to effectiveness of design interventions in mitigating these adverse impacts on water quality. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Interstorm surface preparation and sediment detachment by vehicle traffic on unpaved mountain roads     

Alan D. Ziegler  Ross A. Sutherland  Thomas W. Giambelluca 《地球表面变化过程与地形》2001,26(3):235-250

Road survey and field rainfall simulation experiments have shown that the erodibility of a road surface is dynamic. In the absence of extreme runoff events, dynamic erodibility results from the generation and removal of easily entrained surface material by human road surface maintenance activities, vehicular detachment and overland flow events. Maintenance activities introduce easily transportable material to the road surface where it can be entrained by overland flow. Traffic in dry conditions detaches material that is quickly removed during subsequent overland flow events. The pre‐storm erodibility of a road is therefore largely a function of maintenance and vehicle activity since the last overland flow event. During rainstorms, vehicle passes increase sediment production by detaching/redistributing surface material and creating efficient overland flow pathways for sediment transport. However, if incision of tracks by overland flow does not occur, post‐pass sediment transport quickly returns to pre‐pass rates. Field rainfall simulation data suggest that sediment transport resulting from during‐storm vehicle passes is greatly influenced by the presence of existing loose material, which again is a function of prior road usage and maintenance activities. Incorporation of vehicular effects into physically based road erosion models may be possible by parameterizing both during‐storm and inter‐storm changes in the supply of loose surface material as changes in surface erodibility. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Runoff generation and sediment production on unpaved roads,footpaths and agricultural land surfaces in northern Thailand     

Alan D. Ziegler  Ross A. Sutherland  Thomas W. Giambelluca 《地球表面变化过程与地形》2000,25(5):519-534

Rainfall simulation was used to examine runoff generation and sediment transport on roads, paths and three types of agricultural fields in Pang Khum Experimental Watershed (PKEW), in mountainous northern Thailand. Because interception of subsurface flow by the road prism is rare in PKEW, work focused on Horton overland flow (HOF). Under dry antecedent soil moisture conditions, roads generated HOF in c. 1 min and have event runoff coefficients (ROCs) of 80 per cent, during 45 min, c. 105 mm h⁻¹ simulations. Runoff generation on agricultural fields required greater rainfall depths to initiate HOF; these surfaces had total ROCs ranging from 0 to 20 per cent. Footpaths are capable of generating erosion‐producing overland flow within agricultural surfaces where HOF generation is otherwise rare. Paths had saturated hydraulic conductivity (K_s) values 80–120 mm h⁻¹ lower than those of adjacent agricultural surfaces. Sediment production on roads exceeded that of footpaths and agricultural lands by more than eight times (1·23 versus < 0·15 g J⁻¹). Typically, high road runoff volumes (owing to low K_s, c. 15 mm h⁻¹) transported relatively high sediment loads. Initial road sediment concentrations exceeded 100 g l⁻¹, but decayed with time as loose surface material was removed. Compared with the loose surface layer, the compacted, underlying road surface was resistant to detachment forces. Sediment concentration values for the road simulations were slightly higher than data obtained from a 165 m road section during a comparable natural event. Initial simulation concentration values were substantially higher, but were nearly equivalent to those of the natural event after 20 min simulation time. Higher sediment concentration in the simulations was related to differences in the availability of loose surface material, which was more abundant during the dry‐season simulations than during the rainy season natural event. Sediment production on PKEW roads is sensitive to surface preparation processes affecting the supply of surface sediment, including vehicle detachment, maintenance activities, and mass wasting. The simulation data represent a foundation from which to begin parameterizing a physically based runoff/erosion model to study erosional impacts of roads in the study area. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

IFSAR-DEM在岩溶洼地探测中的应用——以薄荷省旁劳市沉降灾害评估为例     

Kevin L. Garas  Madonna Feliz B. Madrigal  Ross Dominic D. Agot  Mark Carlo M. Canlas  Liza Socorro J. Manzano 《中国岩溶》2020,39(6):928-936

岩溶研究中,通常会使用高分辨率卫星图像和地理空间数据识别、描绘岩溶发育及相关地质灾害发生的地貌特征。本文旨在利用ArcGIS10.0确定干涉合成孔径雷达数字高程模型（IFSAR-DEM）识别、量化和描述岩溶洼地。这种半自动岩溶洼地/天坑探测方法采用水流模拟法,并结合（1）流域划分;（2）下沉填充法提取洼地特征;（3）下沉深度测量及分类;（4）使用2013年至2014年谷歌高光谱卫星图像和数字地形模型对探测到的岩溶洼地进行验证。该方法已在薄荷省旁劳市进行的评估中进行了预测试。使用国家测绘资源信息局（菲律宾）1991年的1:50 000比例尺地形图进行的初步封闭洼地分析,发现旁劳岛有15个天坑。利用5米高分辨率IFSAR-DEM,共探测到820个天坑,其中424个根据详细的地面实况进行了描绘,以验证了岩溶洼地的存在。地表实况包含天坑大小、形状和深度等基本形态测量分析以消除误报数据。阈值设定为沉降深度大于1米,孔径大于10米,从而最大程度精确区分实际的天坑。这种基于GIS的工具有助于生成高分辨率岩溶塌陷易发区图,继而指导当地规划者、工程师及决策者进行开发规划和土地利用。   相似文献   

Effect of silicon on activity coefficients of Bi,Cd, Sn,and Ag in liquid Fe‐Si,and implications for differentiation and core formation     

K. Righter  K. Pando  D. K. Ross  M. Righter  T. J. Lapen 《Meteoritics & planetary science》2019,54(6):1379-1394

The depletion of volatile siderophile elements (VSE) Sn, Ag, Bi, Cd, and P in mantles of differentiated planetary bodies can be attributed to volatile‐depleted precursor materials (building blocks), fractionation during core formation, fractionation into and retention in sulfide minerals, and/or volatile loss associated with magmatism. Quantitative models to constrain the fractionation due to core formation have not been possible due to the lack of activity and partitioning data. Interaction parameters in Fe‐Si liquids have been measured at 1 GPa, 1600 °C and increase in the order Cd (~6), Ag (~10), Sn (~28), Bi (~46), and P (~58). These large and positive values contrast with smaller and negative values in Fe‐S liquids indicating that any chalcophile behavior exhibited by these elements will be erased by dissolution of a small amount of Si in the metallic liquid. A newly updated activity model is applied to Earth, Mars, and Vesta. Five elements (P, Zn, Sn, Cd, and In) in Earth's primitive upper mantle can largely be explained by metal‐silicate equilibrium at high PT conditions where the core‐forming metal is a Fe‐Ni‐S‐Si‐C metallic liquid, but two other—Ag and Bi—become overabundant during core formation and require a removal mechanism such as late sulfide segregation. All of the VSE in the mantle of Mars are consistent with core formation in a volatile element depleted body, and do not require any additional processes. Only P and Ag in Vesta's mantle are consistent with combined core formation and volatile‐depleted precursors, whereas the rest require accretion of chondritic or volatile‐bearing material after core formation. The concentrations of Zn, Ag, and Cd modeled for Vesta's core are similar to the concentration range measured in magmatic iron meteorites indicating that these volatile elements were already depleted in Vesta's precursor materials.  相似文献   

A conceptual framework for studying collective reactions to events in location-based social media     

Alexander Dunkel  Gennady Andrienko  Natalia Andrienko  Dirk Burghardt  Eva Hauthal  Ross Purves 《International journal of geographical information science》2019,33(4):780-804

Events are a core concept of spatial information, but location-based social media (LBSM) provide information on reactions to events. Individuals have varied degrees of agency in initiating, reacting to or modifying the course of events, and reactions include observations of occurrence, expressions containing sentiment or emotions, or a call to action. Key characteristics of reactions include referent events and information about who reacted, when, where and how. Collective reactions are composed of multiple individual reactions sharing common referents. They can be characterized according to the following dimensions: spatial, temporal, social, thematic and interlinkage. We present a conceptual framework, which allows characterization and comparison of collective reactions. For a thematically well-defined class of event such as storms, we can explore differences and similarities in collective attribution of meaning across space and time. Other events may have very complex spatio-temporal signatures (e.g. political processes such as Brexit or elections), which can be decomposed into series of individual events (e.g. a temporal window around the result of a vote). The purpose of our framework is to explore ways in which collective reactions to events in LBSM can be described and underpin the development of methods for analysing and understanding collective reactions to events.  相似文献