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21.
Benoît Thibodeau Moritz F. Lehmann Jacqueline Kowarzyk Alfonso Mucci Yves Gélinas Denis Gilbert Roxane Maranger Mohammad Alkhatib 《Estuarine, Coastal and Shelf Science》2010
Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L−1), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L−1, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m−2 d−1 in the hypoxic western LSLE to 100 μmol m−2 d−1 in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m−2 d−1, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 106 t N, yielding an almost balanced N budget for the SL marine system. 相似文献
22.
The trapped fluid phase in upper mantle xenoliths from Victoria,Australia: implications for mantle metasomatism 总被引：5，自引：0，他引：5
T. Andersen Suzanne Y. O'Reilly W. L. Griffin 《Contributions to Mineralogy and Petrology》1984,88(1-2):72-85
Mantle-derived xenoliths of spinel lherzolite, spinel pyroxenite, garnet pyroxenite and wehrlite from Bullenmerri and Gnotuk maars, southwestern Victoria, Australia contain up to 3 vol.% of fluids trapped at high pressures. The fluid-filled cavities range in size from fluid inclusions (1–100 m) up to vugs 11/2 cm across, lined with euhedral high-pressure phases. The larger cavities form an integral part of the mosaic microstructure. Microthermometry and Raman laser microprobe analysis show that the fluids are dominantly CO2. Small isolated inclusions may have densities 1.19 g/cm3, but most inclusions show microstructural evidence of partial decrepitation during eruption, and these have lower fluid densities. Mass-spectrometric analysis of gases released by crushing or heating shows the presence of He, N2, Ar, H2S, COs and SO2 in small quantities; these may explain the small freezing-point depressions observed in some inclusions. Petrographic, SEM and microprobe studies show that the trapped fluids have reacted with the cavity walls (in clinopyroxene grains) to produce secondary amphiboles and carbonates. The trapped CO2 thus represents only a small residual proportion of an original volatile phase, which has undergone at least two stages of modification — first by equilibration with spinel lherzolite to form amphibole (±mica±apatite), then by limited reaction with the walls of the fluid inclusions. The inferred original fluid was a CO2-H2O mixture, with significant contents of (at least) Cl and sulfur species. Generation of this fluid phase in the garnet-peridotite stability field, followed by its migration to the spinel peridotite stability field, would provide an efficient mechanism for metasomatic enrichment of the upper mantle in LIL elements. This migration could involve either a volatile flux or transport in small volumes of silicate melt that crystallize in the spinel peridotite field. These observations suggest that some portions of the subcontinental upper mantle contain large reservoirs of free fluid CO2, which may be liberated during episodes of rifting or magmatism, to induce granulite-facies metamorphism of the lower crust. 相似文献
23.
The dynamic response of offshore wind turbines is affected by the properties of the foundation and the subsoil. The aim of this paper is to evaluate the dynamic soil–structure interaction of suction caissons for offshore wind turbines. The investigations include evaluation of the vertical and coupled sliding–rocking vibrations, influence of the foundation geometry and examination on the properties of the surrounding soil. The soil is simplified as a homogenous linear viscoelastic material and the dynamic stiffness of the suction caisson is expressed in terms of dimensionless frequency‐dependent coefficients corresponding to different degrees of freedom. The dynamic stiffness coefficients for the skirted foundation are evaluated using a three‐dimensional coupled boundary element/finite element model. Comparisons with known analytical and numerical solutions indicate that the static and dynamic behaviours of the foundation are predicted accurately using the applied model. The analysis has been carried out for different combinations of the skirt length, Poisson's ratio of the subsoil and the ratio of the soil stiffness to the skirt stiffness. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
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